18,555 research outputs found
Curved Graphene Nanoribbons: Structure and Dynamics of Carbon Nanobelts
Carbon nanoribbons (CNRs) are graphene (planar) structures with large aspect
ratio. Carbon nanobelts (CNBs) are small graphene nanoribbons rolled up into
spiral-like structures, i. e., carbon nanoscrolls (CNSs) with large aspect
ratio. In this work we investigated the energetics and dynamical aspects of
CNBs formed from rolling up CNRs. We have carried out molecular dynamics
simulations using reactive empirical bond-order potentials. Our results show
that similarly to CNSs, CNBs formation is dominated by two major energy
contribution, the increase in the elastic energy due to the bending of the
initial planar configuration (decreasing structural stability) and the
energetic gain due to van der Waals interactions of the overlapping surface of
the rolled layers (increasing structural stability). Beyond a critical diameter
value these scrolled structures can be even more stable (in terms of energy)
than their equivalent planar configurations. In contrast to CNSs that require
energy assisted processes (sonication, chemical reactions, etc.) to be formed,
CNBs can be spontaneously formed from low temperature driven processes. Long
CNBs (length of 30.0 nm) tend to exhibit self-folded racket-like
conformations with formation dynamics very similar to the one observed for long
carbon nanotubes. Shorter CNBs will be more likely to form perfect scrolled
structures. Possible synthetic routes to fabricate CNBs from graphene membranes
are also addressed
Enhancing the Mass Sensitivity of Graphene Nanoresonators Via Nonlinear Oscillations: The Effective Strain Mechanism
We perform classical molecular dynamics simulations to investigate the
enhancement of the mass sensitivity and resonant frequency of graphene
nanomechanical resonators that is achieved by driving them into the nonlinear
oscillation regime. The mass sensitivity as measured by the resonant frequency
shift is found to triple if the actuation energy is about 2.5 times the initial
kinetic energy of the nanoresonator. The mechanism underlying the enhanced mass
sensitivity is found to be the effective strain that is induced in the
nanoresonator due to the nonlinear oscillations, where we obtain an analytic
relationship between the induced effective strain and the actuation energy that
is applied to the graphene nanoresonator. An important implication of this work
is that there is no need for experimentalists to apply tensile strain to the
resonators before actuation in order to enhance the mass sensitivity. Instead,
enhanced mass sensitivity can be obtained by the far simpler technique of
actuating nonlinear oscillations of an existing graphene nanoresonator.Comment: published versio
Damped finite-time-singularity driven by noise
We consider the combined influence of linear damping and noise on a dynamical
finite-time-singularity model for a single degree of freedom. We find that the
noise effectively resolves the finite-time-singularity and replaces it by a
first-passage-time or absorbing state distribution with a peak at the
singularity and a long time tail. The damping introduces a characteristic
cross-over time. In the early time regime the probability distribution and
first-passage-time distribution show a power law behavior with scaling exponent
depending on the ratio of the non linear coupling strength to the noise
strength. In the late time regime the behavior is controlled by the damping.
The study might be of relevance in the context of hydrodynamics on a nanometer
scale, in material physics, and in biophysics.Comment: 9 pages, 4 eps-figures, revtex4 fil
Raman modes of the deformed single-wall carbon nanotubes
With the empirical bond polarizability model, the nonresonant Raman spectra
of the chiral and achiral single-wall carbon nanotubes (SWCNTs) under uniaxial
and torsional strains have been systematically studied by \textit{ab initio}
method. It is found that both the frequencies and the intensities of the
low-frequency Raman active modes almost do not change in the deformed
nanotubes, while their high-frequency part shifts obviously. Especially, the
high-frequency part shifts linearly with the uniaxial tensile strain, and two
kinds of different shift slopes are found for any kind of SWCNTs. More
interestingly, new Raman peaks are found in the nonresonant Raman spectra under
torsional strain, which are explained by a) the symmetry breaking and b) the
effect of bond rotation and the anisotropy of the polarizability induced by
bond stretching
The Two Fluid Drop Snap-off Problem: Experiments and Theory
We address the dynamics of a drop with viscosity breaking up
inside another fluid of viscosity . For , a scaling theory
predicts the time evolution of the drop shape near the point of snap-off which
is in excellent agreement with experiment and previous simulations of Lister
and Stone. We also investigate the dependence of the shape and
breaking rate.Comment: 4 pages, 3 figure
Nanoscale Weibull Statistics
In this paper a modification of the classical Weibull Statistics is developed
for nanoscale applications. It is called Nanoscale Weibull Statistics. A
comparison between Nanoscale and classical Weibull Statistics applied to
experimental results on fracture strength of carbon nanotubes clearly shows the
effectiveness of the proposed modification. A Weibull's modulus around 3 is,
for the first time, deduced for nanotubes. The approach can treat (also) a
small number of structural defects, as required for nearly defect free
structures (e.g., nanotubes) as well as a quantized crack propagation (e.g., as
a consequence of the discrete nature of matter), allowing to remove the
paradoxes caused by the presence of stress-intensifications
Simply connected projective manifolds in characteristic have no nontrivial stratified bundles
We show that simply connected projective manifolds in characteristic
have no nontrivial stratified bundles. This gives a positive answer to a
conjecture by D. Gieseker. The proof uses Hrushovski's theorem on periodic
points.Comment: 16 pages. Revised version contains a more general theorem on torsion
points on moduli, together with an illustration in rank 2 due to M. Raynaud.
Reference added. Last version has some typos corrected. Appears in
Invent.math
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