A study on the emissions of alternative aviation fuels

Currently, the aviation sector is seeking for alternatives to kerosene from crude oil, as part of the efforts combating climate change by reducing greenhouse gas (GHG) emissions, in particular carbon dioxide (CO2), and ensuring security of supply at affordable prices. Several synthetic jet fuels have been developed including sustainable biokerosene, a low-carbon fuel. Over the last years, the technical feasibility as well as the compatibility of alternative jet fuels with today's planes has been proven However, when burning a jet fuel, the exhaust gases are a mixture of many species, going beyond CO2 and water (H2O) emissions, with nitrogen oxides (NOx), carbon monoxide (CO), unburned hydrocarbons (UHC) including aromatic species and further precursors of particles and soot among them. These emissions have an impact on the local air quality as well as on the climate (particles, soot, contrails). Therefore, a detailed knowledge and understanding of the emission patterns when burning synthetic aviation fuels are inevitable. In the present paper, these issues are addressed by studying numerically the combustion of four synthetic jet fuels (Fischer–Tropsch fuels). For reference, two types of crude-oil-based kerosene (Jet A-1 and Jet A) are considered, too. Plug flow calculations were performed by using a detailed chemical-kinetic model validated previously. The composition of the multicomponent jet fuels was imaged by using the surrogate approach. Calculations were done for relevant temperatures, pressures, residence times, and fuel equivalence ratios φ. Results are discussed for NOx, CO as well as for benzene and acetylene as major soot precursors. According to the predictions, the NOx and CO emissions are within about ±10% for all fuels considered, within the parameter range studied: T = 1800 K, T = 2200 K; 0.25 ≤ φ ≤ 1.8; p = 40 bar; t = 3 ms. The aromatics free GtL (gas to liquid) fuel displayed higher NOx values compared to Jet A-1/A. In addition, synthetic fuels show slightly lower (better) CO emission data than Jet A-1/A. The antagonist role of CO and NOx is apparent. Major differences were predicted for benzene emissions, depending strongly on the aromatics content in the specific fuel, with lower levels predicted for the synthetic aviation fuels. Acetylene levels show a similar, but less pronounced, effect.</jats:p

The Importance of Detailed Chemical Mechanisms in Gas Turbine Combustion Simulations

This paper – in memory of Jürgen Warnatz – summarizes selected recent papers of the Chemical Kinetics Group at the German Aerospace Center in Stuttgart. It shows the need for detailed chemical reaction mechanisms to understand practical combustion systems. A comprehensive description of combustion processes based on detailed mechanisms is especially important in the design of new gas turbine combustion chambers and in the optimization of existing ones to improve efficiency and to reduce pollutant emissions, with fuel-flexibility and load-flexibility ever becoming more important. Different aspects of combustion processes where detailed reaction mechanisms provide useful insights will be covered in this paper: Fuels (alternative jet fuels, biomass based fuels), pollutants (soot), diagnostics (chemiluminescence), and thermochemistry. Furthermore, the underlying thermodynamics inevitably connected with detailed reaction schemes will be addressed. Exemplified results will be presented clearly demonstrating the predictive capabilities of detailed reaction mechanisms to be explored in computational fluid dynamic simulations to further optimize technical combustion systems