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Thesis (M.B.A.)--Boston Universit

First-principle density-functional calculation of the Raman spectra of BEDT-TTF

We present a first-principles density-functional calculation for the Raman spectra of a neutral BEDT-TTF molecule. Our results are in excellent agreement with experimental results. We show that a planar structure is not a stable state of a neutral BEDT-TTF molecule. We consider three possible conformations and discuss their relation to disorder in these systems.Comment: 3 pages, 2 figures, submitted to the proceedings of ISCOM 200

Tilted guides with friction in web conveyance systems

One challenge in designing web conveyance systems is controlling the displacement and vibration of the webs by guides without introducing instabilities or higher frequency disturbances from flange impacts. A solution to this problem is to use an actively or passively tilted guide or roller to steer the web. In this paper, a model of tilted guides with friction is developed, and it is shown that tilted guides produce a change in the web’s displacement, slope, bending moment, and shear force. When the web is conceptually unwrapped from its path, the normal force between the web and a tilted guide has a component that acts in the direction of the web’s lateral displacement, resulting in an equivalent force and bending moment acting on the web. The model is validated by measurements, and is compared to a previously existing model of guide tilt. In the configurations studied, the displacement of the web near the guide is linearly dependent on the tilt angle and tension and it increases exponentially with the web’s span length. When the guide’s tilt is oriented towards the center of the web’s wrap around the guide, the equivalent bending moment is zero in the absence of friction, and there is good agreement between the model developed in this paper and the previously existing model. However, when the center of the web’s wrap is oriented 90° away from the guide’s tilt orientation, the equivalent force is zero in the absence of friction, and measurements demonstrate the necessity of the equivalent bending moment

Active noise compensation for multichannel magnetocardiography in an unshielded environment

A multichannel high-T/sub c/-SQUID-based heart scanner for unshielded environments is under development, Outside a magnetically shielded room, sensitive SQUID measurements are possible using gradiometers. However, it is difficult to realize large-baseline gradiometers in high-T/sub c/ materials, Therefore, the authors developed two active noise compensation techniques. In the Total Field Compensation technique, a Helmholtz type coil set is placed around the sensors. One magnetometer is used as a zero detector controlling the compensation current through the coil set. For Individual Flux Compensation, the reference signal is sent to the separate SQUIDs (or their flux transformer circuits) to compensate the local environmental noise fluxes, The latter technique was tested on low-T/sub c/ rf-SQUID magnetometers, each sensor set to a field resolution SQUID magnetometers, i.e. 0.1 pT/sub RMS///spl radic/Hz. The authors were able to suppress the environmental disturbances to such an extent that magnetocardiograms could be recorded in an ordinary environment. Here the two suppression techniques are described and experimental results are presente

On the origin of computational model sensitivity, error, and uncertainty in threaded fasteners

Predicting the mechanical response of components requires simplifications and idealizations that affect the fidelity of the results and introduce errors. Some errors correspond to the limited knowledge of intrinsic physical attributes while others are introduced by the modeling framework and mathematical approximations. This paper studies the dependence of the force-displacement response of threaded fasteners on modeling attributes such as geometry, material, and friction resistance using finite element simulations. A systematic comparison of View the MathML source1D,2.5D or 3D3D computational models demonstrates the influence of model properties and the limitations of the methodologies. Finally, the paper discusses the sources of model inputs and model form errors for threaded fasteners

Non-random dispersal in the butterfly Maniola jurtina: implications for metapopulation models

The dispersal patterns of animals are important in metapopulation ecology because they affect the dynamics and survival of populations. Theoretical models assume random dispersal but little is known in practice about the dispersal behaviour of individual animals or the strategy by which dispersers locate distant habitat patches. In the present study, we released individual meadow brown butterflies (Maniola jurtina) in a non-habitat and investigated their ability to return to a suitable habitat. The results provided three reasons for supposing that meadow brown butterflies do not seek habitat by means of random flight. First, when released within the range of their normal dispersal distances, the butterflies orientated towards suitable habitat at a higher rate than expected at random. Second, when released at larger distances from their habitat, they used a non-random, systematic, search strategy in which they flew in loops around the release point and returned periodically to it. Third, butterflies returned to a familiar habitat patch rather than a non-familiar one when given a choice. If dispersers actively orientate towards or search systematically for distant habitat, this may be problematic for existing metapopulation models, including models of the evolution of dispersal rates in metapopulations

Mechanics of cooling liquids by forced evaporation in bubbles

Injecting a non-dissolvable gas into a saturated liquid results in sub-cooling of the liquid due to forced evaporation into the bubble. Previous studies assumed the rate of evaporation of liquid into the bubble to be independent of the degree of sub-cooling. In our study we quantify the bubble growth by direct observation using high speed imaging and prove that this hypothesis is not true. A phenomenological model of the bubble growth as a function of the degree of sub-cooling is developed and we find excellent agreement between the measurements and theory. This bubble cooling process is employed in cooling a liquid. By identification of all heat flows, we can well describe the cool down curve using bubble cooling. Bubble cooling provides an alternative cooling method for liquids without the use of complicated cooling techniques