Integration of thermochemical water splitting with CO₂ direct air capture

Renewable production of fuels and chemicals from direct air capture (DAC) of CO₂ is a highly desired goal. Here, we report the integration of the DAC of CO₂ with the thermochemical splitting of water to produce CO₂, H₂, O₂, and electricity. The produced CO₂ and H₂ can be converted to value-added chemicals via existing technologies. The integrated process uses thermal solar energy as the only energy input and has the potential to provide the dual benefits of combating anthropogenic climate change while creating renewable chemicals. A sodium–manganese–carbonate (Mn–Na–CO₂) thermochemical water-splitting cycle that simultaneously drives renewable H₂ production and DAC of CO₂ is demonstrated. An integrated reactor is designed and fabricated to conduct all steps of the thermochemical water-splitting cycle that produces close to stoichiometric amounts (∼90%) of H₂ and O₂ (illustrated with 6 consecutive cycles). The ability of the cycle to capture 75% of the ∼400 ppm CO₂ from air is demonstrated also. A technoeconomic analysis of the integrated process for the renewable production of H₂, O₂, and electricity, as well as DAC of CO₂ shows that the proposed scheme of solar-driven H₂ production from thermochemical water splitting coupled with CO₂ DAC may be economically viable under certain circumstances

Assessing the Spoofing Threat: Development of a Portable GPS Civilian Spoofer

A portable civilian GPS spoofer is implemented on a digital signal processor and used to characterize spoofing effects and develop defenses against civilian spoofing. This work is intended to equip GNSS users and receiver manufacturers with authentication methods that are effective against unsophisticated spoofing attacks. The work also serves to refine the civilian spoofing threat assessment by demonstrating the challenges involved in mounting a spoofing attack.Aerospace Engineering and Engineering Mechanic

Evaluating GPS Receiver Robustness to Ionospheric Scintillation

A method for testing GPS receivers for ionospheric scintillation robustness has been implemented using a GPS signal simulator and a statistical model that captures the characteristics of scintillation relevant to receiver performance. This technique will help GNSS equipment manufacturers and users prepare for the approaching solar maximum by enabling repeatable receiver performance tests under realistic scintillation conditions. Ionospheric scintillation can impair the performance of phase tracking loops in GNSS receivers by introducing deep amplitude fades and abrupt phase changes in a signal. A statistical model has been developed that accurately recreates these effects by shaping the complex spectrum rather than treating phase and amplitude individually. Generated scintillation histories have been incorporated into the output of a GPS signal simulator so that any compatible receiver can be evaluated without modification. Such a hardware-in-the-loop approach provides a controlled test environment and the ability to characterize receiver performance statistically by running many experiments. It expands the range of possible test conditions beyond those available during field testing. The method is simple to implement, and its value has been demonstrated by a variety of tests applied to four different receivers.Aerospace Engineering and Engineering Mechanic

Impact of age and race on outcomes of a program to prevent excess weight gain and disordered eating in adolescent girls

Interpersonal psychotherapy (IPT) prevents weight gain and reduces loss-of-control (LOC)-eating in adults. However, IPT was not superior to health-education (HE) for preventing excess weight gain and reducing LOC-eating over 1-year in adolescent girls at risk for excess weight gain and eating disorders. Limited data suggest that older and non-White youth may be especially responsive to IPT. In secondary analyses, we examined if age or race moderated weight and LOC-eating outcomes. The 113 participants (12–17 years; 56.6% White) from the original trial were re-contacted 3 years later for assessment. At baseline and follow-up visits through 3 years, we assessed BMI, adiposity by dual energy X-ray absorptiometry, and LOC-eating presence. In linear mixed models, baseline age moderated 3-year BMI outcome; older girls in IPT had the lowest 3-year BMI gain compared to younger girls in IPT and all girls in HE, p = 0.04. A similar pattern was observed for adiposity. Race moderated 3-year LOC-eating; non-White girls in IPT were most likely to abstain from LOC-eating at 3 years compared to all other girls, p = 0.04. This hypothesis-generating analysis suggests future studies should determine if IPT is especially efficacious at reducing LOC-eating in older, non-White adolescents

The Helsinki Convention's agricultural nutrient governance: how domestic institutions matter

National policy styles and path-dependencies are affecting the abilities of Baltic Sea countries to deliver on their commitments under the Helsinki Convention. This article synthesizes evidence and insights from studies relating to the provisions on agricultural nutrient management, a main source of marine pollution. We contend that governments that are strongly concentrated vertically, while fragmented horizontally, lack capacity including with respect to informal institutions that can leverage implementation. As a stocktaking of institutional impediments to sustainable development, our analysis has wider relevance for other international agreements with Baltic Sea countries involved

CASES: A Smart, Compact GPS Software Receiver for Space Weather Monitoring

A real-time software-defined GPS receiver for the L1 C/A and L2C codes has been developed as a low-cost space weather instrument for monitoring ionospheric scintillation and total electron content. The so-called CASES receiver implements several novel processing techniques not previously published that make it well suited for space weather monitoring: (A) a differencing technique for eliminating local clock effects, (B) an advanced triggering mechanism for determining the onset of scintillation, (C) data buffering to permit observation of the prelude to scintillation, and (D) data-bit prediction and wipe-off for robust tracking. The receiver has been tested in a variety of benign and adverse signal conditions (e.g., severe ionospheric scintillation, both real and simulated); the results are presented here. The custom hardware platform on which the software runs is compact while remaining flexible and extensible. The CASES platform consists of a digital signal processor, an ARM microcontroller, and a custom-built narrow-band dualfrequency front end. Because the receiver is softwaredefined, it can be remotely reprogrammed via the internet or another communications link.Aerospace Engineering and Engineering Mechanic

Influenza Vaccine Effectiveness against Hospitalisation with Confirmed Influenza in the 2010-11 Seasons: A Test-negative Observational Study

Immunisation programs are designed to reduce serious morbidity and mortality from influenza, but most evidence supporting the effectiveness of this intervention has focused on disease in the community or in primary care settings. We aimed to examine the effectiveness of influenza vaccination against hospitalisation with confirmed influenza. We compared influenza vaccination status in patients hospitalised with PCR-confirmed influenza with patients hospitalised with influenza-negative respiratory infections in an Australian sentinel surveillance system. Vaccine effectiveness was estimated from the odds ratio of vaccination in cases and controls. We performed both simple multivariate regression and a stratified analysis based on propensity score of vaccination. Vaccination status was ascertained in 333 of 598 patients with confirmed influenza and 785 of 1384 test-negative patients. Overall estimated crude vaccine effectiveness was 57% (41%, 68%). After adjusting for age, chronic comorbidities and pregnancy status, the estimated vaccine effectiveness was 37% (95% CI: 12%, 55%). In an analysis accounting for a propensity score for vaccination, the estimated vaccine effectiveness was 48.3% (95% CI: 30.0, 61.8%). Influenza vaccination was moderately protective against hospitalisation with influenza in the 2010 and 2011 seasons

Core outcome measures for palliative and end-of-life research after severe stroke: mixed-method Delphi study

Background and Purpose: Stroke is the second commonest cause of death worldwide and a leading cause of severe disability, yet there are no published trials of palliative care in stroke. To design and evaluate palliative care interventions for people with stroke, researchers need to know what measurable outcomes matter most to patients and families, stroke professionals, and other service providers. Methods: A multidisciplinary steering group of professionals and laypeople managed the study. We synthesized recommendations from respected United Kingdom and international consensus documents to generate a list of outcome domains and then performed a rapid scoping literature review to identify potential outcome measures for use in future trials of palliative care after stroke. We then completed a 3-round, online Delphi survey of professionals, and service users to build consensus about outcome domains and outcome measures. Finally, we held a stakeholder workshop to review and finalize this consensus. Results: We generated a list of 36 different outcome domains from 4 key policy documents. The rapid scoping review identified 43 potential outcome measures that were used to create a shortlist of 16 measures. The 36 outcome domains and 16 measures were presented to a Delphi panel of diverse healthcare professionals and lay service users. Of 48 panelists invited to take part, 28 completed all 3 rounds. Shared decision-making and quality of life were selected as the most important outcome domains for future trials of palliative care in stroke. Additional comments highlighted the need for outcomes to be feasible, measurable, and relevant beyond the initial, acute phase of stroke. The stakeholder workshop endorsed these results. Conclusions: Future trials of palliative care after stroke should include pragmatic outcome measures, applicable to the evolving patient and family experiences after stroke and be inclusive of shared decision-making and quality of life

Historical ecology with real numbers: past and present extent and biomass of an imperiled estuarine habitat

Historic baselines are important in developing our understanding of ecosystems in the face of rapid global change. While a number of studies have sought to determine changes in extent of exploited habitats over historic timescales, few have quantified such changes prior to late twentieth century baselines. Here, we present, to our knowledge, the first ever large-scale quantitative assessment of the extent and biomass of marine habitat-forming species over a 100-year time frame. We examined records of wild native oyster abundance in the United States from a historic, yet already exploited, baseline between 1878 and 1935 (predominantly 1885–1915), and a current baseline between 1968 and 2010 (predominantly 2000–2010). We quantified the extent of oyster grounds in 39 estuaries historically and 51 estuaries from recent times. Data from 24 estuaries allowed comparison of historic to present extent and biomass. We found evidence for a 64 per cent decline in the spatial extent of oyster habitat and an 88 per cent decline in oyster biomass over time. The difference between these two numbers illustrates that current areal extent measures may be masking significant loss of habitat through degradation