Selective oxidation of methane to ethane and ethylene over various oxide catalysts

Preliminary results are reported for the oxidative coupling of methane to give ethane/ethylene mixtures over a series of different catalyst formulations; the temperature range studied is 650–850°C. A comparison is made of the behaviour of lead/alumina and lithium/magnesia materials. It is found that the former samples give ethane and ethylene plus a predominance of CO2 whereas the latter give ethane and ethylene plus a mixture of CO, CO2 and H2; at higher temperatures, the lead materials give also H2 and CO. The lithium-containing materials are much more stable than the lead-containing ones; the latter lose lead, probably by volatilisation of the metal. A number of other oxide materials have also been examined and have been found to be less effective, having lower activities and selectivities than the lead- and lithium-containing systems

Synchrotron emission from secondary leptons in microquasar jets

We present a model to estimate the synchrotron radio emission generated in microquasar (MQ) jets due to secondary pairs created via decay of charged pions produced in proton-proton collisions between stellar wind ions and jet relativistic protons. Signatures of electrons/positrons are obtained from consistent particle energy distributions that take into account energy losses due to synchrotron and inverse Compton (IC) processes, as well as adiabatic expansion. The space parameter for the model is explored and the corresponding spectral energy distributions (SEDs) are presented. We conclude that secondary leptonic emission represents a significant though hardly dominant contribution to the total radio emission in MQs, with observational consequences that can be used to test some still unknown processes occurring in these objects as well as the nature of the matter outflowing in their jets

External Operators and Anomalous Dimensions in Soft-Collinear Effective Theory

It has recently been argued that soft-collinear effective theory for processes involving both soft and collinear partons contains a new soft-collinear mode, which can communicate between the soft and collinear sectors of the theory. The formalism incorporating the corresponding fields into the effective Lagrangian is extended to include external current and four-quark operators relevant to weak interactions. An explicit calculation of the anomalous dimensions of these operators reveals that soft-collinear modes are needed for correctly describing the ultraviolet behavior of the effective theory.Comment: 15 pages, 2 figure

B->gamma e nu Transitions from QCD Sum Rules

B->gamma e nu transitions have recently been studied in the framework of QCD factorization. The attractiveness of this channel for such an analysis lies in the fact that, at least in the heavy quark limit, the only hadron involved is the B meson itself, so one expects a very simple description of the form factor in terms of a convolution of the B meson distribution amplitude with a perturbative kernel. This description, however, does not include contributions suppressed by powers of the b quark mass. In this letter, we calculate corrections to the factorized expression which are induced by the ``soft'' hadronic component of the photon. We demonstrate that the power-suppression of these terms is numerically not effective for physical values of the $b$ quark mass and that they increase the form factor by about 30% at zero momentum transfer. We also derive a sum rule for lambda_B, the first negative moment of the B meson distribution amplitude, and find lambda_B = 0.6 GeV (to leading order in QCD).Comment: 13 pages, 5 figure

Rare radiative exclusive B decays in soft-collinear effective theory

We consider rare radiative B decays such as B -> K^* gamma or B -> rho gamma in soft-collinear effective theory, and show that the decay amplitudes are factorized to all orders in alpha_s and at leading order in Lambda/m_b.By employing two-step matching, we classify the operators for radiative B decays in powers of a small parameter lambda(~ \sqrt{Lambda/m_b}) and obtain the relevant operators to order lambda in SCET_I. These operators are constructed with or without spectator quarks including the four-quark operators contributing to annihilation and W-exchange channels. And we employ SCET_II where the small parameter becomes of order Lambda/m_b, and evolve the operators in order to compute the decay amplitudes for rare radiative decays in soft-collinear effective theory. We show explictly that the contributions from the annihilation channels and the W-exchange channels vanish at leading order in SCET. We present the factorized result for the decay amplitudes in rare radiative B decays at leading order in SCET, and at next-to-leading order in alpha_s.Comment: v2: 31 pages, 11 figures. An appendix is added about the quark mass effects on radiative B decay

Sudakov Resummation for Subleading SCET Currents and Heavy-to-Light Form Factors

The hard-scattering contributions to heavy-to-light form factors at large recoil are studied systematically in soft-collinear effective theory (SCET). Large logarithms arising from multiple energy scales are resummed by matching QCD onto SCET in two stages via an intermediate effective theory. Anomalous dimensions in the intermediate theory are computed, and their form is shown to be constrained by conformal symmetry. Renormalization-group evolution equations are solved to give a complete leading-order analysis of the hard-scattering contributions, in which all single and double logarithms are resummed. In two cases, spin-symmetry relations for the soft-overlap contributions to form factors are shown not to be broken at any order in perturbation theory by hard-scattering corrections. One-loop matching calculations in the two effective theories are performed in sample cases, for which the relative importance of renormalization-group evolution and matching corrections is investigated. The asymptotic behavior of Sudakov logarithms appearing in the coefficient functions of the soft-overlap and hard-scattering contributions to form factors is analyzed.Comment: 50 pages, 10 figures; minor corrections, version to appear in JHE

Alignment of galaxy spins in the vicinity of voids

We provide limits on the alignment of galaxy orientations with the direction to the void center for galaxies lying near the edges of voids. We locate spherical voids in volume limited samples of galaxies from the Sloan Digital Sky Survey using the HB inspired void finder and investigate the orientation of (color selected) spiral galaxies that are nearly edge-on or face-on. In contrast with previous literature, we find no statistical evidence for departure from random orientations. Expressed in terms of the parameter c, introduced by Lee & Pen to describe the strength of such an alignment, we find that c<0.11(0.13) at 95% (99.7%) confidence limit within a context of a toy model that assumes a perfectly spherical voids with sharp boundaries.Comment: 8 pages, 4 figures; v2 discussion expanded, references fixed, matches version accepted by JCA

The B-Meson Distribution Amplitude in QCD

The B-meson distribution amplitude is calculated using QCD sum rules. In particular we obtain an estimate for the integral relevant to exclusive B-decays \lambda_B = 460 \pm 110 MeV at the scale 1 GeV. A simple QCD-motivated parametrization of the distribution amplitude is suggested.Comment: 17 pages, 8 figures, Latex styl