Physicochemical, structural, and adsorption characteristics of DMSPS-co-DVB nanopolymers

The aim of this work is the synthesis and characterization of the series of S,S′-thiodi-4,1-phenylene bis(thio-methacrylate)-co-divinylbenzene (DMSPS-co-DVB) nanomaterials. The series of new nanopolymers including three mixed systems with different ratios of DMSPS and DVB components, DMSPS-co-DVB = 1:1, DMSPS-co-DVB = 1:2, and DMSPS-co-DVB = 1:3, was synthesized in the polymerization reaction. The research task is to investigate the influence of the reaction mixture composition on morphological, textural, and structural properties of final nanosystems including size, shape, and agglomeration effect. The advanced biphasic nanomaterials enriched with thiol groups were successfully synthesized as potential sorbents for binding organic substances, heavy metals, or biomolecules. To determine the impact of the DMSPS monomer on the final properties of DMSPS-co-DVB nanocomposites, several techniques were applied to reveal the nano-dimensional structure (SAXS), texture (low-temperature nitrogen sorption), general morphology (SEM), acid–base properties (potentiometric titration), and surface chemistry and phase bonding effectiveness (FTIR/ATR spectroscopy). Finally, kinetic studies of aniline sorption on polymeric materials were performed

Actual challenges, opportunities, and perspectives of composite materials

The development of technology is associated with a strong need for changes in the design and manufacture of new types of materials. Monolithic materials such as ceramics or metals have become insufficient for the needs of the modern market. The combination of several types of materials in one system turned out to be the right solution. Composite materials as multi-phase materials show improved properties compared with individual structural elements and can give the opportunity to design systems with enhanced specific characteristics.The presented work provides a review of actual literature dedicated to composite materials. In this work, the basic terminology, the division of composite systems, the most commonly used methods for composites preparation as well as physicochemical characteristics and potential applications of these types of matter were presented

Physicochemical and Adsorption Characteristics of Divinylbenzene-co-Triethoxyvinylsilane Microspheres as Materials for the Removal of Organic Compounds

In this work, organic-inorganic materials with spherical shape consisting of divinylbenzene (DVB) and triethoxyvinylsilane (TEVS) were synthesized and investigated by different complementary techniques. The obtained microspheres may be applied as sorbent systems for the purification of organic compounds from water. The hybrid microspheres combine the properties of the constituents depending on the morphologies and interfacial bonding. In this work, the influence of the molar ratio composition of crosslinked monomer (DVB) and silane coupling agent (TEVS) (DVB:TEVS molar ratios: 1:2, 1:1 and 2:1) on the morphology and quality of organic-inorganic materials have been examined. The materials were analysed using small angle X-ray scattering (SAXS) analysis, low-temperature nitrogen sorption, scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) to provide information on their structural and surface properties. Moreover, thermal analysis was performed to characterize the thermal stability of the studied materials and the adsorbent-adsorbate interactions, while adsorption kinetic studies proved the utility of the synthesized adsorbents for water and wastewater treatment

Physicochemical and Sorption Characteristics of Carbon Biochars Based on Lignin and Industrial Waste Magnetic Iron Dust

Magnetosensitive biochars were prepared with mechanochemical ball-milling of lignin and blast furnace dust with further pyrolysis at 800 °C under an inert gas atmosphere. The physicochemical and sorption characteristics of the materials were analyzed using several techniques: low-temperature nitrogen adsorption–desorption, X-ray powder diffraction, Raman spectroscopy, elemental analysis, potentiometric titration, and thermal analysis. All the synthesized biocarbons were characterized by their specific surface areas (SBET) in the range of 290–330 m2/g and microporous structures with certain contribution of mesopores in the total porosity. Equilibrium adsorption studies revealed the potential applicability of the materials in water remediation from hazardous organic substances modelled with methylene blue (MB) dye. Generally, this study illustrates the effective conversion of sustainable waste into a functional carbon material

Development, Synthesis and Characterization of Tannin/Bentonite-Derived Biochar for Water and Wastewater Treatment from Methylene Blue

Novel hybrid carbon–mineral materials were synthesized by the mechanochemical activation of a mixture of tannin and bentonite in a ball mill with further pyrolysis in an argon atmosphere at 800 °C. The influence of the initial mixture ingredients content on the structural, textural, and thermal characteristics of biochars has been described using X-ray diffraction, Raman and Fourier-transform infrared spectroscopy, nitrogen adsorption–desorption, and scanning electron microscopy. The influence of bentonite clay on the carbon phase characteristics due to the formation of more heat-resistant and structured nanocarbon particles in biochars has been proven. The adsorption effectiveness of the materials towards methylene blue was studied. The adsorption data were analyzed applying Langmuir and Freundlich isotherms with high determination coefficients (R2) in the range of 0.983–0.999 (Langmuir) and 0.783–0.957 (Freundlich). The maximum adsorption amount of MB was 5.78 mg/g. The adsorption efficiency of biochars with respect to phenol was also examined. It was shown that the hybrid biochars show differentiated selectivity to the adsorption of organic compounds. It was concluded that the physicochemical properties of the surface of biochars play an important role in the adsorption effectiveness, making them a good candidate for water and wastewater remediation processes

Development, Synthesis and Characterization of Tannin/Bentonite-Derived Biochar for Water and Wastewater Treatment from Methylene Blue

Novel hybrid carbon–mineral materials were synthesized by the mechanochemical activation of a mixture of tannin and bentonite in a ball mill with further pyrolysis in an argon atmosphere at 800 °C. The influence of the initial mixture ingredients content on the structural, textural, and thermal characteristics of biochars has been described using X-ray diffraction, Raman and Fourier-transform infrared spectroscopy, nitrogen adsorption–desorption, and scanning electron microscopy. The influence of bentonite clay on the carbon phase characteristics due to the formation of more heat-resistant and structured nanocarbon particles in biochars has been proven. The adsorption effectiveness of the materials towards methylene blue was studied. The adsorption data were analyzed applying Langmuir and Freundlich isotherms with high determination coefficients (R2) in the range of 0.983–0.999 (Langmuir) and 0.783–0.957 (Freundlich). The maximum adsorption amount of MB was 5.78 mg/g. The adsorption efficiency of biochars with respect to phenol was also examined. It was shown that the hybrid biochars show differentiated selectivity to the adsorption of organic compounds. It was concluded that the physicochemical properties of the surface of biochars play an important role in the adsorption effectiveness, making them a good candidate for water and wastewater remediation processes