The Influence of K4[Fe(CN)6] Aerosol on the Flame Speed of Methane-air Flame

AbstractThe influence of 1% aerosol of the water solution of potassium ferrocyanide K4[Fe(CN)6] on the flame speed of stoichoimetric methane- air flame, stabilized over the Mache-Hebra burner, has been studied experimentally and by computer simulation. The flame speed was measured at atmospheric pressure and the temperature 93°C. Addition of the aerosol of the water solution of potassium ferrocyanide results in significantly greater reduction of the flame speed of stoichiometric methane-air flame, compared to aerosol addition without the salt. Modeling the flame speed with the mechanism GRI-Mech 3.0 shows this effect to be caused by the presence of potassium atoms in the composition of this salt. The results obtained account for effectiveness of applying fine aerosol of the water solution of K4[Fe(CN)6] in extinguishing fires

Hybrid Microporous Polymeric Materials with Outstanding Permeability and Increased Gas Transport Stability: PTMSP Aging Prevention by Sorption of the Polymerization Catalyst on HCPS

The influence of hyper-crosslinked polystyrene (HCPS) MacronetTM MN200 on the gas transport properties and aging of the highly permeable glassy polymer poly(1-trimethylsilyl-1-propyne) (PTMSP) was studied and analyzed in detail. The gas transport characteristics of dense PTMSP membranes containing 0–10.0 wt % HCPS were studied. It was shown that the introduction of a small amount of HCPS into the PTMSP matrix led to a 50–60% increase of the permeability coefficients of the material for light gases (N2, O2, CO2) and slowed down the deterioration of polymer transport properties over time. The lowest reduction in gas permeability coefficients (50–57%) was found for PTMSP containing HCPS 5.0 wt % after annealing at 100 °C for 300 h. It was found that HCPS sorbed residues of tantalum-based polymerization catalyst from PTMSP. In order to investigate the influence of catalysts on transport and physical properties of PTMSP, we purified the latter from the polymerization catalyst by addition of 5 wt % HCPS into polymer/chloroform solution. It was shown that sorption on HCPS allowed for almost complete removal of tantalum compounds from PTMSP. The membrane made of PTMSP purified by HCPS demonstrated more stable transport characteristics compared to the membrane made of the initial polymer. HCPS has a complex effect on the aging process of PTMSP. The introduction of HCPS into the polymer matrix not only slowed down the physical aging of PTMSP, but also reduced chemical aging due to removal of active reagents

Mathematical modeling of the reaction system of dicyclopentadiene polymerization

Based on the mathematical model of dicyclopentadiene polymerization the authors have proposed the mathematical model of the polymerization reactor. The reactor for producing polydicyclopentadiene was designed. It is operated in adiabatic and isothermal temperature conditions. The maximum permissible monomer concentration in toluene solution was determined. It was shown that the polymerization products in different reactors have the same molecular mass and different molecular weight distribution

High Efficiency Membranes Based on PTMSP and Hyper-Crosslinked Polystyrene for Toxic Volatile Compounds Removal from Wastewater

For the first time, membranes based on poly(1-trimethylsilyl-1-propyne) (PTMSP) with 5–50 wt% loading of hyper-crosslinked polystyrene sorbent particles (HCPS) were obtained; the membranes were investigated for the problem of effective removal of volatile organic compounds from aqueous solutions using vacuum pervaporation. The industrial HCPS sorbent Purolite Macronet™ MN200 was chosen due to its high sorption capacity for organic solvents. It has been found that the membranes are asymmetric when HCPS content is higher than 30 wt%; scanning electron microscopy of the cross-sections the membranes demonstrate that they have a clearly defined thin layer, consisting mainly of PTMSP, and a thick porous layer, consisting mainly of HCPS. The transport and separation characteristics of PTMSP membranes with different HCPS loading were studied during the pervaporation separation of binary and multicomponent mixtures of water with benzene, toluene and xylene. It was shown that the addition of HCPS up to 30 wt% not only increases the permeate fluxes by 4–7 times, but at the same time leads to 1.5–2 fold increase in the separation factor. It was possible to obtain separation factors exceeding 1000 for all studied mixtures at high permeate fluxes (0.5–1 kg/m2∙h) in pervaporation separation of binary solutions

He-enriched STAREVOL models for globular cluster multiple populations. Self-consistent isochrones from ZAMS to the TP-AGB phase

International audienceA common property of globular clusters (GC) is to host multiple populations characterized by peculiar chemical abundances. Recent photometric studies suggest that the He content could vary between the populations of a GC by up to $\Delta$He $\sim$ 0.13, in mass fraction. The initial He content impacts the evolution of low-mass stars by ultimately modifying their lifetimes, luminosity, temperatures, and, more generally, the morphology of post-RGB evolutionary tracks in the Hertzsprung-Russell diagram. We present new physically accurate isochrones with different initial He-enrichments and metallicities, with a focus on the methods implemented to deal with the post-RGB phases. The isochrones are based on tracks computed with the stellar evolution code STAREVOL for different metallicities (Z = 0.0002, 0.0009, 0.002, and 0.008) and with different He-enrichment (from 0.25 to 0.6 in mass fraction). We describe the effect of He-enrichment on the morphology of the isochrones and test these by comparing the predicted number counts of HB and AGB stars with those of selected GCs. Comparing the number ratios, we find that our new theoretical ones agree with the observed values within $1\sigma$ in most cases. The work presented here sets the ground for future studies on stellar populations in globular clusters, in which the abundances of light elements in He-enhanced models will rely on different assumptions for the causes of this enrichment. The developed methodology permits the computation of isochrones from new stellar tracks with non-canonical stellar processes. The checked number counts ensure that, at least in this reference set, the contribution of the luminous late stages of stellar evolution to the integrated light of a GC is represented adequately