Ötzi the Iceman. Examining new evidence from the famous copper age mummy

The Iceman mummy, nicknamed Ötzi, was discovered in 1991 amidst sheets of melting ice on the Tisenjoch pass of the Similaun glacier in the Tyrolean Alps. He was found on the border between Italy and Austria, at an altitude of 3,200 m above sea level. He is a well-preserved male human corpse, dark in color, and dates to the early Copper Age, indicating he is more than 5,000 years old (ca. 3,250 yrs. cal BCE). His belongings, scattered around the body, included a bow and quiver with arrows, a complete copper-bladed axe, a flint dagger with a wicker sheath, two birch wood vessels clad with maple leaves, remnants of a backpack, a leather pouch with small objects, fur and leather garments, shoes, and other minor artifacts. When scientists realized the antiquity of the find, the media response was overwhelming and Ötzi captivated audiences far and wide

Study of the wettability behavior of stainless steel surfaces after ultrafast laser texturing

The interest in superhydrophobic surfaces has grown exponentially over recent decades. Since the lotus leaf dual hierarchical structure was discovered, researchers have investigated the foundations of this behavior and many methods have been developed to obtain superhydrophobic surfaces. In this paper the possibility to use ultrafast laser treatments to obtain hydrophobic and superhydrophobic stainless surfaces was investigated on a AISI 316L stainless steel, ranging the total energy doses provided to the surfaces from 178 to 1143 J/cm2. As SEM-FEG images reveals, different surface microstructures can be obtained at the increasing values of energy dose. Independently on the specific values of laser treatment, all the obtained samples showed hydrophobic values of static contact angle. However, only particular surface microstructures allowed obtaining a self-cleaning surface characterized by low values of both contact angle hysteresis and roll-off angle. The obtained results led to define the effect of the laser parameters on the morphological, chemical and wetting surface properties allowing one to design new textures with the desired wetting properties, from “lotus effect” surfaces to “rose petal effect” surfaces

Synergic strategies to improve the PBF-LB/M processability of a cracking-sensitive alloy

The Powder Bed Fusion-Laser Beam\Metals (PBF-LB\M) is a promising additive manufacturing process that can be used to directly produce functional components with a complex shape for a wide variety of applications. However, the layer-by-layer scanning and high cooling rates result in a high thermal gra- dient and thus, in thermally induced stresses. The stresses developed during the additive process could lead to undesirable cracking and delamination phenomena that can seriously affect the performance of the final component. The alloy composition can exacerbate crack and delamination formation, however, the need to expand the portfolio of high-strength materials processable for PBF-LB\M makes the resolu- tion of these undesirable phenomena a primary challenge in the additive manufacturing field. This works aims to systematically investigate some strategies to make processable non-standard compositions. As no standard compositions, the promising pre-alloyed AlSi10Cu8Mg composition was chosen for the present work. Based on the results obtained from a condition of severe delamination, the synergetic use of appro- priate process parameters and support structures can lead to crack-free and fully dense specimens also when platform heating is not allowed. The developed approach could also be applied to adapt other cracking-sensitive alloys for PBF-LB\M production

Advantages of additive manufacturing for biomedical applications of polyhydroxyalkanoates

In recent years, biopolymers have been attracting the attention of researchers and special-ists from different fields, including biotechnology, material science, engineering, and medicine. The reason is the possibility of combining sustainability with scientific and technological progress. This is an extremely broad research topic, and a distinction has to be made among different classes and types of biopolymers. Polyhydroxyalkanoate (PHA) is a particular family of polyesters, synthetized by microorganisms under unbalanced growth conditions, making them both bio-based and biodegradable polymers with a thermoplastic behavior. Recently, PHAs were used more intensively in biomedical applications because of their tunable mechanical properties, cytocompatibility, adhesion for cells, and controllable biodegradability. Similarly, the 3D-printing technologies show increasing potential in this particular field of application, due to their advantages in tailor-made design, rapid prototyping, and manufacturing of complex structures. In this review, first, the synthesis and the production of PHAs are described, and different production techniques of medical implants are compared. Then, an overview is given on the most recent and relevant medical applications of PHA for drug delivery, vessel stenting, and tissue engineering. A special focus is reserved for the inno-vations brought by the introduction of additive manufacturing in this field, as compared to the traditional techniques. All of these advances are expected to have important scientific and commer-cial applications in the near future

Development of glass-stalks-unsaturated polyester hybrid composites

The aim of this study is to investigate the possibility to use agro-residues of the vinification process as a cheaper and eco-friendly fillers to prepare unsaturated polyester composites for interior design building sector. Experimental unsaturated polyester–based resin composite samples, reinforced with grape stalks, were prepared by a simple casting technique. The glass microspheres were added in the mixing to increase the mechanical and physical properties of the final materials. A silane coupling agent was used to increase the interface adhesion between resin and grape stalks. The samples were subjected to several tests. Unfilled samples were analyzed by Differential Scanning calorimetry (DSC). Prepared silanized and non-silanized composites were completely characterized in order to study the effect of stalk fibers concentration on the mechanical, chemical and physical properties. The results showed that mechanical and physical properties for silanized composites were superior to non-silanized composites. The presence of stalks, up to 50% wt. increased Young's Modulus preserving a satisfactory tensile strength and hardness in comparison with the neat resin properties. Then, the final results showed that grape stalks from winemaking can be satisfactory used as natural filler resource to produce composites for interior furniture

Novel 3D printable bio-based and biodegradable poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) microspheres for selective laser sintering applications

Selective laser sintering (SLS) has become the most popular additive manufacturing process due to its high accuracy, productive efficiency, and surface quality. However, currently there are still very few commercially available polymeric materials suitable for this technique. This research work focused on the fabrication and characterization of bio-based and biodegradable microspheres obtained by oil-in-water emulsion solvent evaporation, starting from a poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (PHBH) biopolymer matrix. First, the fabrication parameters were optimized to improve the morphological, thermal, and flowability properties of the synthetized microspheres. Once the best production conditions were established, the PHBH microspheres were further used to study their effective 3D printability on an SLS 3D printer using geometries varying from simple shapes to architectures with more complex internal patterns. The results of this research revealed that PHBH has promising applicability for the SLS technique. This study undertook the first step toward broadening the range of polymeric materials for this additive manufacturing technology. These findings will contribute to a greater and wider dissemination of the SLS technique in the future, as well as they will bring this manufacturing process closer to applications, such as the biomedical sector, where the use of biodegradable and biocompatible materials can add value to the final application

Measurement of the Charge Collection Efficiency after Heavy Non-Uniform Irradiation in BaBar Silicon Detectors

We have investigated the depletion voltage changes, the leakage current increase and the charge collection efficiency of a silicon microstrip detector identical to those used in the inner layers of the BaBar Silicon Vertex Tracker (SVT) after heavy non-uniform irradiation. A full SVT module with the front-end electronics connected has been irradiated with a 0.9 GeV electron beam up to a peak fluence of 3.5 x 10^14 e^-/cm^2, well beyond the level causing substrate type inversion. We irradiated one of the two sensors composing the module with a non-uniform profile with sigma=1.4 mm that simulates the conditions encountered in the BaBar experiment by the modules intersecting the horizontal machine plane. The position dependence of the charge collection properties and the depletion voltage have been investigated in detail using a 1060 nm LED and an innovative measuring technique based only on the digital output of the chip.Comment: 7 pages, 13 figures. Presented at the 2004 IEEE Nuclear Science Symposium, October 18-21, Rome, Italy. Accepted for publication by IEEE Transactions on Nuclear Scienc

Short range investigation of sub-micron zirconia particles

The Perturbed Angular Correlations technique was used to determine the configurations around Zirconium ions and their thermal behavior in non-aggregated sub-micron zirconia spherical particles. Three residues containing- Zr surroundings were determined for the non-crystalline starting particles, which were identified under the assumption of a certain chemical reactions sequence during synthesis. While the one made up mainly by hydroxyl groups was common to both samples, the two involving mainly organic residues were particle size dependent. Upon crystallization, both samples stabilized in the t'- and t- tetragonal forms and the Xc-cubic form but their amounts and temperatures of appearance were different. On heating, the structure of the smaller particles became gradually monoclinic achieving total degradation upon the subsequent cooling to RT.Instituto de Física La Plat

Short range investigation of sub-micron zirconia particles

The Perturbed Angular Correlations technique was used to determine the configurations around Zirconium ions and their thermal behavior in non-aggregated sub-micron zirconia spherical particles. Three residues containing- Zr surroundings were determined for the non-crystalline starting particles, which were identified under the assumption of a certain chemical reactions sequence during synthesis. While the one made up mainly by hydroxyl groups was common to both samples, the two involving mainly organic residues were particle size dependent. Upon crystallization, both samples stabilized in the t'- and t- tetragonal forms and the Xc-cubic form but their amounts and temperatures of appearance were different. On heating, the structure of the smaller particles became gradually monoclinic achieving total degradation upon the subsequent cooling to RT.Instituto de Física La Plat

The structure of ZrO2 phases and devetrification processes in a Ca-Zr-Si-O-based glass ceramic: a combined a-XRD and XAS study

The structure of Zr atomic environment in a CaO-ZrO2-SiO2 glass-ceramic has beenstudied combining x-ray absorption spectroscopy (XAS), X-ray diffraction (XRD) andanomalous-XRD (a-XRD) techniques as a function of thermal treatments. The analysisof XRD patterns demonstrates that the devitrification process, as a function ofthermal treatment, proceeds through the partial segregation of Zr-depleted phases(Wollastonite-like) and Zr-rich phases (Zr-oxides). The XAS and a-XRD measurementsat the Zr K edge have been exploited to get a closer insight on the atomicstructure around Zr ions. In the as quenched glass the Zr is 6-fold coordinated to Oxygenatoms in an amorphous environment rich of Ca and Si. Thermal treatment firstly(T=1000 - 1050 oC) determines the partial segregation of Zr in form of oxide whichcrystalline structure is that of tetragonal Zirconia (t-ZrO2). Raising the temperature(T=1100 oC) provokes the formation of ZrO2 crystallites in the monoclinic crystallographicphase (Baddeleyite: m-ZrO2). The analysis of XAS data demonstrates that aconsiderable amount of Zr still remains in an amorphous Calcium-Silicate phase