1 research outputs found
Green Synthesis of Multifunctionalized, Nitrogen-Doped, Highly Fluorescent Carbon Dots from Waste Expanded Polystyrene and Its Application in the Fluorimetric Detection of Au<sup>3+</sup> Ions in Aqueous Media
Synthesis of highly
luminescent carbon dots (CDs) from waste materials
gains much attention in the current scenario. We have converted waste
expanded polystyrene (EPS), a nonbiodegradable environmental pollutant,
into multifunctionalized fluorescent CDs. This can be a good scaling
up approach for the large-scale synthesis of nitrogen-doped CDs with
a high photoluminescence (PL) quantum yield (QY) of ∼20%. The
as prepared CDs exhibit excellent water solubility and a longer PL
lifetime (in nanoseconds). They also possess excellent photostability,
low cytotoxicity, and stable luminescence QY in different solution
environments. Selective and sensitive detection of Au<sup>3+</sup> ions is demonstrated using these CDs as fluorescence probes, and
a LOD of 53 nM is achieved. A detailed investigation revealed that
the observed PL quenching is due to “coordination-induced aggregation
caused PL quenching” mechanism