Aging in Dense Colloids as Diffusion in the Logarithm of Time

The far-from-equilibrium dynamics of glassy systems share important phenomenological traits. A transition is generally observed from a time-homogeneous dynamical regime to an aging regime where physical changes occur intermittently and, on average, at a decreasing rate. It has been suggested that a global change of the independent time variable to its logarithm may render the aging dynamics homogeneous: for colloids, this entails diffusion but on a logarithmic time scale. Our novel analysis of experimental colloid data confirms that the mean square displacement grows linearly in time at low densities and shows that it grows linearly in the logarithm of time at high densities. Correspondingly, pairs of particles initially in close contact survive as pairs with a probability which decays exponentially in either time or its logarithm. The form of the Probability Density Function of the displacements shows that long-ranged spatial correlations are very long-lived in dense colloids. A phenomenological stochastic model is then introduced which relies on the growth and collapse of strongly correlated clusters ("dynamic heterogeneity"), and which reproduces the full spectrum of observed colloidal behaviors depending on the form assumed for the probability that a cluster collapses during a Monte Carlo update. In the limit where large clusters dominate, the collapse rate is ~1/t, implying a homogeneous, log-Poissonian process that qualitatively reproduces the experimental results for dense colloids. Finally an analytical toy-model is discussed to elucidate the strong dependence of the simulation results on the integrability (or lack thereof) of the cluster collapse probability function.Comment: 6 pages, extensively revised, final version; for related work, see http://www.physics.emory.edu/faculty/boettcher/ or http://www.fysik.sdu.dk/staff/staff-vip/pas-personal.htm

Record dynamics of evolving metastable systems: theory and applications

Record Dynamics (RD) deals with complex systems evolving through a sequence of metastable stages. These are macroscopically distinguishable and appear stationary, except for the sudden and rapid changes, called quakes, which induce the transitions from one stage to the next. This phenomenology is well known in physics as “physical aging”, but from the vantage point of RD, the evolution of a class of systems of physical, biological, and cultural origin is rooted in a hierarchically structured configuration space and can, therefore, be analyzed by similar statistical tools. This colloquium paper strives to present in a coherent fashion methods and ideas that have gradually evolved over time. To this end, it first describes the differences and similarities between RD and two widespread paradigms of complex dynamics, Self-Organized Criticality and Continuous Time Random Walks. It then outlines the Poissonian nature of records events in white noise time-series, and connects it to the statistics of quakes in metastable hierarchical systems, arguing that the relaxation effects of quakes can generally be described by power laws unrelated to criticality. Several different applications of RD have been developed over the years. Some of these are described, showing the basic RD hypothesis and how the log-time homogeneity of quake dynamics, can be empirically verified in a given context. The discussion summarizes the paper and briefly mentions applications not discussed in detail. Finally, the outlook points to possible improvements and to new areas of research where RD could be of use

How a spin-glass remembers. Memory and rejuvenation from intermittency data: an analysis of temperature shifts

The memory and rejuvenation aspects of intermittent heat transport are explored theoretically and by numerical simulation for Ising spin glasses with short-ranged interactions. The theoretical part develops a picture of non-equilibrium glassy dynamics recently introduced by the authors. Invoking the concept of marginal stability, this theory links irreversible `intermittent' events, or `quakes' to thermal fluctuations of record magnitude. The pivotal idea is that the largest energy barrier $b(t_w,T)$ surmounted prior to $t_w$ by thermal fluctuations at temperature $T$ determines the rate $r_q \propto 1/t_w$ of the intermittent events occurring near $t_w$. The idea leads to a rate of intermittent events after a negative temperature shift given by $r_q \propto 1/t_w^{eff}$, where the `effective age' $t_w^{eff} \geq t_w$ has an algebraic dependence on $t_w$, whose exponent contains the temperatures before and after the shift. The analytical expression is verified by numerical simulations. Marginal stability suggests that a positive temperature shift $T \to T'$ could erase the memory of the barrier $b(t_w,T)$. The simulations show that the barrier $b(t_w,T') \geq b(t_w,T)$ controls the intermittent dynamics, whose rate is hence $r_q \propto 1/t_w$. Additional `rejuvenation' effects are also identified in the intermittency data for shifts of both signs.Comment: Revised introduction and discussion. Final version to appear in Journal of Statistical Mechanics: Theory and Experimen

Comparing extremal and thermal explorations of energy landscapes

Using a non-thermal local search, called Extremal Optimization (EO), in conjunction with a recently developed scheme for classifying the valley structure of complex systems, we analyze a short-range spin glass. In comparison with earlier studies using a thermal algorithm with detailed balance, we determine which features of the landscape are algorithm dependent and which are inherently geometrical. Apparently a characteristic for any local search in complex energy landscapes, the time series of successive energy records found by EO is also characterized approximately by a Poisson statistic with logarithmic time arguments. Differences in the results provide additional insights into the performance of EO. In contrast with a thermal search, the extremal search visits dramatically higher energies while returning to more widely separated low-energy configurations. Two important properties of the energy landscape are independent of either algorithm: first, to find lower energy records, progressively higher energy barriers need to be overcome. Second, the Hamming distance between two consecutive low-energy records is linearly related to the height of the intervening barrier. Copyright EDP Sciences/Società Italiana di Fisica/Springer-Verlag 2005

Extremal fluctuations are essential for relaxation in complex energy landscapes

We determine the importance of extreme, record-sized events on the non-equilibrium relaxation ("aging") after a sudden quench into the glassy phase. Here, we directly measure the impact of extreme events on the evolving system in Monte Carlo simulations of Ising spin glasses and ferromagnets undergoing quenches into either a low or high-temperature phase. Our results show that, if we bar the attainment of new record-high energy fluctuations (by explicitly imposing a "lid" on the fluctuation spectrum), further relaxation in the low-temperature glassy phase is impeded markedly while in all other phases such a lid actually accelerates the relaxation process. Such rare record events, emerging naturally in the sequence of ordinary fluctuations of any relaxing system, thus prove to be key in activating the aging dynamics, as has been argued for systems like spin glasses, superconductors, gels, colloids, and granular piles. This dynamics of records succeeds in explaining the logarithmic decay of the free energy and the memory effects encoded in the scaling of two-time correlation functions of those aging systems. These findings are interpreted through the interplay of fluctuations and generic features of the hierarchical, complex energy landscape of glassy systems