Infrared aircraft measurements of stratospheric composition over Antarctica during September 1987

The JPL Mark IV interferometer recorded high resolution, infared solar spectra from the NASA DC-8 aircraft during flights over Antarctica in September 1987. The atmospheric absorption features in these spectra were analyzed to determine the overburdens of O3, NO, NO2, HNO3, ClONO2, HCl, HF, CH4, N2O, CO, H2O and CFC-12. The spectra were obtained at latitudes which ranged between 64 degrees S and 86 degrees S, allowing the composition in the interior of the polar vortex to be compared with that at the edge. The latitude dependence observed for NO, HO2, HNO3, ClONO2, HCl and HF are summerized. The values at 30 deg S were observed on the ferry flight from New Zealand to Hawaii. The dashed lines connecting the two were interpolated across the region for which there are no measurements. The chemically perturbed region is seen to consist of a collar of high HNO3 and ClONO2 surrounding a core in which the overburdens of these and of HCl and NO2 are very low. Clear increases in the overburdens of HF and HNO3 were observed during the course of September in the vortex core. HCl and NO2 exhibited smaller, less significant increases. The overburdens of the tropospheric source gases, N2O, CH4, CF2Cl2, and H2O were observed to much smaller over Antarctica than at mid-latitudes. This, together with the fact that HF over Antarctica was more that double its mid-latitude value, suggests that downwelling has occurred

H2O and δD profiles remotely-sensed from ground in different spectral infrared regions

We present ground-based FTIR (Fourier Transform Infrared) water vapour analyses performed in four different spectral regions: 790–880, 1090–1330, 2650–3180, and 4560–4710 cm−1. All four regions allow the retrieval of lower, middle, and upper tropospheric water vapour amounts with a vertical resolution of about 3, 6, and 10 km, respectively. In addition the analyses at 1090–1330 and 2650–3180 cm−1 allow the retrieval of lower and middle/upper tropospheric δD values with vertical resolutions of 3 and 10 km, respectively. A theoretical and empirical error assessment – taking coincident Vaisala RS92 radiosonde measurements as a reference – suggests that the H2O data retrieved at high wavenumbers are slightly more precise than those retrieved at low wavenumbers. We deduce an H2O profile precision and accuracy of generally better than 20% except for the low wavenumber retrieval at 790–880 cm−1, where the assessed upper precision limit of middle/upper tropospheric H2O is 35%. The scatter between the H2O profiles produced by the four different retrievals is generally below 20% and the bias below 10%, except for the boundary layer, where it can reach 24%. These values well confirm the theoretical and empirical error assessment and are rather small compared to the huge tropospheric H2O variability of about one order of magnitude thereby demonstrating the large consistency between the different H2O profile retrievals. By comparing the two δD profile versions we deduce a precision of about 8 and 17‰ for the lower and middle/upper troposphere, respectively. However, at the same time we observe a systematic difference between the two retrievals of up to 40‰ in the middle/upper troposphere which is a large value compared to the typical tropospheric δD variability of only 80‰.M. Schneider has been supported by the Deutsche Forschungsgemeinschaft via the project RISOTO (Geschaftszeichen SCHN 1126/1-1 and 1-2)

Optical-Path-Difference Linear Mechanism for the Panchromatic Fourier Transform Spectrometer

A document discusses a mechanism that uses flex-pivots in a parallelogram arrangement to provide frictionless motion with an unlimited lifetime. A voicecoil actuator drives the parallelogram over the required 5-cm travel. An optical position sensor provides feedback for a servo loop that keeps the velocity within 1 percent of expected value. Residual tip/tilt error is compensated for by a piezo actuator that drives the interferometer mirror. This mechanism builds on previous work that targeted ground-based measurements. The main novelty aspects include cryogenic and vacuum operation, high reliability for spaceflight, compactness of the design, optical layout compatible with the needs of an imaging FTS (i.e. wide overall field-of-view), and mirror optical coatings to cover very broad wavelength range (i.e., 0.26 to 15 m)

Infrared measurements of atmospheric CH_3CN

For the first time CH_3CN has been measured in the Earth's atmosphere by means of infrared remote sensing. Vertical profiles of volume mixing ratio were retrieved from 12 solar occultation measurements by the balloon-borne JPL MkIV interferometer between 1993 and 2004. Profile retrieval is possible in an altitude range between 12 and 30 km with a precision of ∼20 ppt in the Arctic and ∼30 ppt at mid-latitudes. The retrieved CH_3CN profiles show mixing ratios of 100–150 ppt a few kilometers above the tropopause that decrease to values below 40 ppt at altitudes between 22 and 30 km. The CH_3CN mixing ratios show a reasonably compact correlation with the stratospheric tracers CH_3Cl and CH_4. The CH_3CN altitude profiles and tracer correlations are well reproduced by a 2-dimensional model, suggesting that CH_3CN is long-lived in the lower stratosphere and that previously-proposed ion-molecule reactions do not play a major role as loss processes of CH_3CN

On the stratospheric chemistry of hydrogen cyanide

HCN profiles measured by solar occultation spectrometry during 10 balloon flights of the JPL MkIV instrument are presented. The HCN profiles reveal a compact correlation with stratospheric tracers. Calculations with a 2D-model using established rate coefficients for the reactions of HCN with OH and O(^1D) severely underestimate the measured HCN in the middle and upper stratosphere. The use of newly available rate coefficients for these reactions gives reasonable agreement of measured and modeled HCN. An HCN yield of ∼30% from the reaction of CH_3CN with OH is consistent with the measurements