Volatiles as a link between planetary interiors and the environment

Thesis (Ph. D.)--Massachusetts Institute of Technology, Dept. of Earth, Atmospheric, and Planetary Sciences, 2013.Cataloged from PDF version of thesis.Includes bibliographical references (pages 163-179).Volatiles derived from planetary interiors influence magma evolution and environmental processes. Over appropriate timescales, Earth's mantle, crust, ocean, and atmosphere constitute coupled systems. The apparently synchronous Siberian Traps eruption and end-Permian mass extinction offer an ideal test case to study the interactions between magmatism and climate. In this thesis, I use experimental petrology, numerical modeling, geochemical measurements, and field observations to investigate the petrologic sources, eruptive transfer, and climatic effects of volatiles released during emplacement of the Siberian large igneous province. In an extreme variation on terrestrial volatile cycling, I also explore the erosional history of Titan as recorded in valley networks carved by rivers of liquid hydrocarbons.by Benjamin A. Black.Ph.D

Carbon release from Large Igneous Province magmas estimated from trace element-gas correlations

Large Igneous Provinces (LIPs) facilitate massive transfers of CO2 and other volatiles from the mantle to atmosphere, contributing to past global warming and environmental disruption. However, the scale and evolution of magmatic CO2 fluxes during these events remain uncertain due to the tendency of CO2 to degas deep in magmatic systems. Here we estimate LIP CO2 using an approach based on an observed correlation between gas CO2/S ratios and trace elements in volcanic rocks. We apply this method to a compilation of published geochemical data for tholeiitic LIP lavas and to a new major and trace element dataset for alkaline rocks from the Siberian Traps. Our results indicate that CO2/S and therefore CO2 in tholeiitic and alkaline magma suites from LIPs span 1–2 orders of magnitude, emphasizing that changing CO2 concentrations can combine with magma flux to drive strong variations in CO2 release through the evolution of LIP magmatism

Prospects for the cavity-assisted laser cooling of molecules

Cooling of molecules via free-space dissipative scattering of photons is thought not to be practicable due to the inherently large number of Raman loss channels available to molecules and the prohibitive expense of building multiple repumping laser systems. The use of an optical cavity to enhance coherent Rayleigh scattering into a decaying cavity mode has been suggested as a potential method to mitigate Raman loss, thereby enabling the laser cooling of molecules to ultracold temperatures. We discuss the possibility of cavity-assisted laser cooling particles without closed transitions, identify conditions necessary to achieve efficient cooling, and suggest solutions given experimental constraints. Specifically, it is shown that cooperativities much greater than unity are required for cooling without loss, and that this could be achieved via the superradiant scattering associated with intracavity self-localization of the molecules. Particular emphasis is given to the polar hydroxyl radical (OH), cold samples of which are readily obtained from Stark deceleration.Comment: 18 pages, 10 figure

Morphology of fluvial networks on Titan: Evidence for structural control

Although Titan’s surface shows clear evidence of erosional modification, such as fluvial incision, evidence for tectonism has been less apparent. On Earth, fluvial networks with strongly preferred orientations are often associated with structural features, such as faults or joints, that influence flow or erodibility. We delineated and classified the morphologies of fluvial drainages on Titan and discovered evidence of structural control. Fluvial networks were delineated both on synthetic aperture radar (SAR) images covering ∼40% of Titan from the Cassini Titan Radar Mapper up through T71 and on visible light images of the Huygens landing site collected by the Descent Imager/Spectral Radiometer (DISR). The delineated networks were assigned to one of three morphologic classes—dendritic, parallel or rectangular—using a quantitative terrestrial drainage pattern classification algorithm modified for use with Titan data. We validated our modified algorithm by applying it to synthetic fluvial networks produced by a landscape evolution model with no structural control of drainage orientations, and confirmed that only a small fraction of the networks are falsely identified as structurally controlled. As a second validation, we confirmed that our modified algorithm correctly classifies terrestrial networks that are classified in multiple previous works as rectangular. Application of this modified algorithm to our Titan networks results in a classification of rectangular for one-half of the SAR and DISR networks. A review of the geological context of the four terrestrial rectangular networks indicates that tensional stresses formed the structures controlling those terrestrial drainages. Based on the similar brittle response of rock and cryogenic ice to stress, we infer that structures formed under tension are the most likely cause of the rectangular Titan networks delineated here. The distribution of these rectangular networks suggests that tensional stresses on Titan may have been widespread.United States. National Aeronautics and Space Administration (NASA Cassini Data Analysis Program Grant NNX08BA81G

Global drainage patterns and the origins of topographic relief on Earth, Mars, and Titan

Rivers have eroded the topography of Mars, Titan, and Earth, creating diverse landscapes. However, the dominant processes that generated topography on Titan (and to some extent on early Mars) are not well known. We analyzed drainage patterns on all three bodies and found that large drainages, which record interactions between deformation and erosional modification, conform much better to long-wavelength topography on Titan and Mars than on Earth. We use a numerical landscape evolution model to demonstrate that short-wavelength deformation causes drainage directions to diverge from long-wavelength topography, as observed on Earth. We attribute the observed differences to ancient long-wavelength topography on Mars, recent or ongoing generation of long-wavelength relief on Titan, and the creation of short-wavelength relief by plate tectonics on Earth

Gut Microbiome: Profound Implications For Diet And Disease

The gut microbiome plays an important role in human health and influences the development of chronic diseases ranging from metabolic disease to gastrointestinal disorders and colorectal cancer. Of increasing prevalence in Western societies, these conditions carry a high burden of care. Dietary patterns and environmental factors have a profound effect on shaping gut microbiota in real time. Diverse populations of intestinal bacteria mediate their beneficial effects through the fermentation of dietary fiber to produce short-chain fatty acids, endogenous signals with important roles in lipid homeostasis and reducing inflammation. Recent progress shows that an individual’s starting microbial profile is a key determinant in predicting their response to intervention with live probiotics. The gut microbiota is complex and challenging to characterize. Enterotypes have been proposed using metrics such as alpha species diversity, the ratio of Firmicutes to Bacteroidetes phyla, and the relative abundance of beneficial genera (e.g., Bifidobacterium, Akkermansia) versus facultative anaerobes (E. coli), pro-inflammatory Ruminococcus, or nonbacterial microbes. Microbiota composition and relative populations of bacterial species are linked to physiologic health along different axes. We review the role of diet quality, carbohydrate intake, fermentable FODMAPs, and prebiotic fiber in maintaining healthy gut flora. The implications are discussed for various conditions including obesity, diabetes, irritable bowel syndrome, inflammatory bowel disease, depression, and cardiovascular disease

Fertility Intentions and Clinical Care Attendance Among Women Living with HIV in South Africa

Poor HIV care retention impedes optimal treatment outcomes in persons living with HIV. Women trying to become pregnant may be motivated by periconception horizontal and vertical transmission concerns and thus more likely to attend HIV care visits than women not trying to conceive. We estimated the effect of fertility intentions on HIV care attendance over 12 months among non-pregnant, HIV-positive women aged 18–35 years who were on or initiating antiretroviral therapy in Johannesburg, South Africa. The percentage of women attending an HIV care visit decreased from 93.4% in the first quarter to 82.8% in the fourth quarter. Fertility intentions were not strongly associated with care attendance in this cohort of reproductive-aged women; however, attendance declined over time irrespective of childbearing plans. These findings suggest a need for reinforced efforts to support care engagement and risk reduction, including safer conception practices for women wishing to conceive

Longitudinal patterns of unmet need for contraception among women living with HIV on antiretroviral therapy in South Africa

Objectives: Fertility intentions and contraceptive use are often not assessed in the context of clinical HIV care, representing a possible programming gap if women's family planning needs change over time. We aimed to identify longitudinal patterns of unmet need for contraception over a 12-month period among women living with HIV taking antiretroviral therapy (ART). Study design: 850 non-pregnant, HIV-positive women aged 18-35 on or initiating ART in Johannesburg, South Africa, were enrolled into a prospective cohort study in 2009-2010. Fertility intentions and contraceptive use were assessed during routine HIV care visits via an interviewer-administered questionnaire, and women were referred for on-site contraceptive counseling. We used group-based trajectory modeling to identify patterns of unmet need for contraception over 12 months, first in the entire population and then in a subset of recent ART initiators. Results: In the full population we identified four patterns of unmet need for contraception over one year. Half of the enrolled women were predicted to have a consistently high probability of unmet need, 22.9% a consistently low probability, 16.7% a decreasing probability, and 10.4% an increasing probability over time. Contraceptive method discontinuation and rapidly changing fertility intentions were the primary drivers of changing (increasing or decreasing) unmet need over follow-up. Results were similar in recent ART initiators. Conclusions: Half of women were estimated to have a high probability of unmet need that persisted over time, and more than a quarter were estimated to experience patterns of changing unmet need over 12 months. Family planning needs should be assessed more regularly in HIV-positive women to prevent unintended pregnancies and support safer conception among women trying to conceive