The influence of Si and V on the kinetics of phase transformation and microstructure of rapidly solidified Al-Fe-Zr alloys

The influence of Si and V on the precipitation kinetics of the rapidly solidified (RS) Al-Fe-Zr alloys is presented. Precipitation kinetics and microstructural development of RS Al-Fe-Zr alloys with Si or V addition have been investigated by the combination of four point electrical resistance measurement, optical microscopy, transmition electron microscopy (TEM) and scanning electron microscopy (SEM). For verification of the electrical resistivity measurement results differential scanning calorimetry (DSC) and differential thermal analysis (DTA) was also applied. Rapidly solidified samples, in the form of thin ribbons, were prepared with the single roll melt spun technique. For determination of the distinctive temperatures at which microstructural transformations occur in-situ electrical resistivity measurement during heating of the ribbons with various constant heating rates has been used. It was found that microstructure decomposition depends on heating rate and shifts to higher temperatures with increasing heating rate. After heating above the distinctive transition temperatures, heating was stopped and microstructure of the samples examined by electron microscopy

Fracture of drilling head pipe connection due to quenching of heat affected zone (HAZ)

The drilling head pipe connection is made of quenched and tempered steel 34CrNiMo6. The steel characteristic is high hardenability. Due to unsuitable and untested welding technology the heat affected zone (HAZ) cooling rate after welding surpassed the upper critical cooling rate. During horizontal drilling of the rock, the resulting brittle martensite could not bear the dynamic loads which led to a brittle fracture of the pipe connection

Tests of a proximity focusing RICH with aerogel as radiator

Using aerogel as radiator and multianode PMTs for photon detection, a proximity focusing Cherenkov ring imaging detector has been constructed and tested in the KEK $\pi$2 beam. The aim is to experimentally study the basic parameters such as resolution of the single photon Cherenkov angle and number of detected photons per ring. The resolution obtained is well approximated by estimates of contributions from pixel size and emission point uncertainty. The number of detected photons per Cherenkov ring is in good agreement with estimates based on aerogel and detector characteristics. The values obtained turn out to be rather low, mainly due to Rayleigh scattering and to the relatively large dead space between the photocathodes. A light collection system or a higher fraction of the photomultiplier active area, together with better quality aerogels are expected to improve the situation. The reduction of Cherenkov yield, for charged particle impact in the vicinity of the aerogel tile side wall, has also been measured.Comment: 4 pages, 8 figure

Sequent Calculus in the Topos of Trees

Nakano's "later" modality, inspired by G\"{o}del-L\"{o}b provability logic, has been applied in type systems and program logics to capture guarded recursion. Birkedal et al modelled this modality via the internal logic of the topos of trees. We show that the semantics of the propositional fragment of this logic can be given by linear converse-well-founded intuitionistic Kripke frames, so this logic is a marriage of the intuitionistic modal logic KM and the intermediate logic LC. We therefore call this logic $\mathrm{KM}_{\mathrm{lin}}$. We give a sound and cut-free complete sequent calculus for $\mathrm{KM}_{\mathrm{lin}}$ via a strategy that decomposes implication into its static and irreflexive components. Our calculus provides deterministic and terminating backward proof-search, yields decidability of the logic and the coNP-completeness of its validity problem. Our calculus and decision procedure can be restricted to drop linearity and hence capture KM.Comment: Extended version, with full proof details, of a paper accepted to FoSSaCS 2015 (this version edited to fix some minor typos

Development of banded microstructure in 34CrNiMo6 steel

In this paper the development of a banded microstructure in hot-rolled 34CrNiMo6 steel which consisted of bainitic and martensitic bands is explained. The chemical compositions of the bands were measured with energy dispersive x-ray spectroscopy (EDS), which showed that the martensitic bands contained more alloying elements (Mn, Cr, Mo, Si) than bainitic bands. By using Oberhoffer reagent, the segregations of phosphorus were also revealed. These phosphorus segregations coincided with the positive segregations of the alloying elements. The continuous cooling transformation (CCT) diagrams of steel were calculated. They confirmed the formation of martensite in positive segregations and the formation of bainite in negative segregations

Structural and thermodynamic analysis of whiskers on the surface of grey cast iron

The paper focuses, first, on the characterization of the whiskers on the surface of grey cast iron and second, it gives an explanation of whiskers growth based on thermodynamic calculations. The whiskers were observed on the surface of hot plates for the electric stove after black-oxide-coating (blackening) performed the furnace at 650°C in order to produce a protective layer mainly of magnetite (Fe3O4). However, the whiskers caused brown spots on dark grey surface and thus, the surface was aesthetically damaged. The investigations confirmed that whiskers are of hematite (Fe2O3); however, the thermodynamic calculations present that hematite may be formed as a result of the oxidation of magnetite if the partial pressure of oxygen is increased during the blackening

Quantitation of Formoterol, Salbutamol, and Salbutamol-4′-O-Sulfate in Human Urine and Serum via UHPLC-MS/MS

The adrenergic beta-2 agonists formoterol and salbutamol are used for the treatment of asthma and COPD but are also misused in sports competitions. Therefore, they are included in WADA regulations. Both drugs are mainly excreted in urine after administration via inhalation. A four-armed, double-blind cross-over clinical trial was conducted involving endurance-trained participants (12 females and 12 males). Inhalation dosages of 36 μg formoterol, 1200 μg salbutamol, a combination of both, or a placebo were administered before exercise. Serum and urine were collected after exercise and 3 and 24 h after administration. Here, we show the successful quantitation of formoterol, salbutamol, and its phase II metabolite salbutamol-4′-O-sulfate in all urine and serum samples using ultra-high performance liquid chromatography–tandem mass spectrometry. In the serum analysis, results of up to 14.2 pg/mL formoterol, 10.0 ng/mL salbutamol, and 21.4 ng/mL salbutamol-4′-O-sulfate (calculated as salbutamol equivalent) were found. In urine, maximum concentrations (after deglucuronidation) were 17.2 ng/mL formoterol, 948.5 ng/mL salbutamol, and 2738.5 ng/mL salbutamol-4′-O-sulfate. Sex-specific differences in serum concentrations as well as in urinary excretion were observed. The results pronounce the importance of the implementation and elucidation of phase II metabolites to quantitation methods in antidoping

Averages of b-hadron Properties at the End of 2005

This article reports world averages for measurements on b-hadron properties obtained by the Heavy Flavor Averaging Group (HFAG) using the available results as of at the end of 2005. In the averaging, the input parameters used in the various analyses are adjusted (rescaled) to common values, and all known correlations are taken into account. The averages include lifetimes, neutral meson mixing parameters, parameters of semileptonic decays, branching fractions of B meson decays to final states with open charm, charmonium and no charm, and measurements related to CP asymmetries