Designing Difunctional Promoters for Hypergolic Ignitions of Green Bipropellants Combining Ionic Liquids with H₂O₂

The emergence of tetrahydroborate (BH4–)/cyanoborohydride (BH3CN–) anion-based ionic liquid fuels in combination with high test peroxide (>90%H2O2, HTP) oxidizers has accelerated the greening of bipropellants. However, most BH4– and BH3CN– anion-based ionic liquids are sensitive to water, making it difficult to store them. Here, novel difunctional promoters are designed for hypergolic ignition of BH4–/BH3CN– anion-free ionic liquids with 90%H2O2. The transition metal in anions of promoters is expected to catalyze the exothermic decomposition of H2O2, and the substituted borohydride in cations of promoters acts as the ignition source. These novel difunctional promoters show good solubility in commercially available 1-allyl-3-methylimidazolium dicyanamide and 1-butyl-3-methylimidazolium dicyanamide ionic liquid fuels, and the composite fuels exhibit high density, acceptable viscosity, and high thermostability. The addition of difunctional promoters ensures the smooth hypergolic ignition of BH4–/BH3CN– anion-free ionic liquid fuels with a minimum ignition delay time of 34.0 ms, and no apparent microexplosion and secondary combustion are observed during the ignition process. With the increase in the amount of the promoter, density specific impulses of the composite fuels improve gradually. This work provides a platform strategy for designing promoters by synergy of cations and anions and makes efforts to seek green bipropellants

Fabrication of Swellable Organic–Inorganic Hybrid Polymers for CO₂‑Assisted Hydration of Propylene Epoxide

Swelling is a very common phenomenon in organic substances. However, the swelling behaviors of inorganic substances had rarely been reported. In this study, a new type of swellable organic–inorganic hybrid polymer (PIL@CHT) was designed and successfully synthesized through free-radical copolymerization of polymerizable phosphonium ionic liquid monomer and vinyl-functionalized hydrotalcite (CHT). The swelling behaviors of PIL@CHT in various solvents with a wide range of Hansen solubility parameters (δT) were investigated, and PIL@CHT exhibited excellent swellable capacity in the solvents with δT > 24.4 MPa1/2. The swollen state of the hybrid PIL@CHT in water presented a network structure with a diameter of approximately 8–12 μm, and CHT particles were well dispersed to the channel of PIL. PIL@CHT was applied to catalyze the CO2-assisted hydration of propylene oxide (PO), in which a cascade reaction including the cycloaddition of CO2 and PO and the subsequent hydrolysis of propylene carbonate (PC) occurred. PIL@CHT, combining the active sites of PIL and CHT, synergistically catalyzed this cascade reaction and achieved a high yield (93.0%) and selectivity (98.2%) of 1,2-propanediol (1,2-MPG) under a low H2O/PO ratio of 1.5/1. Moreover, the catalyst could be recycled seven times without any significant loss of catalytic activities and had good substrate generality

Swelling Poly(ionic liquid)s: Synthesis and Application as Quasi-Homogeneous Catalysts in the Reaction of Ethylene Carbonate with Aniline

Homogeneous catalysts generally show higher catalytic activities, while heterogeneous catalysts are more easily separated from products. To combine the advantages of heterogeneous and homogeneous catalysts has been of great interest for many years. Here, we report a kind of facilely prepared cross-linked poly­(ionic liquid)­s (PILs) with swelling property to increase catalytic activities of heterogeneous catalysts. The swelling ability of PILs was greatly affected by cross-linking density and chain length of substituents on imidazolium, and the unique swelling property prompted the nonporous PILs to contact with substrates sufficiently, enhancing their catalytic activities similar to homogeneous ionic liquid monomers