49 research outputs found
Electrical transition of (3,3) carbon nanotube on patterned hydrogen terminated Si(001)-2 x 1 driven by electric field
Structure, energetics, and electrical properties of (3,3) carbon nanotube(CNT) supported on patterned hydrogen terminated Si(001): 2 × 1 surface are studied using density functional theory. Our investigation reveals that an otherwise metallic (3,3) CNT when supported becomes semiconducting with a band gap of ≈0.5 eV due to its strong interaction with the surface. During adsorption, Si-C bonds form at the interface and charges transfer from Si surface to CNT. The Si-C bonds at the interface are partially covalent and partially ionic in nature. Under the application of an external electric field, the bandgap of the supported CNT reduces to zero, hence rendering the system metallic
Structural studies of phosphorus induced dimers on Si(001)
Renewed focus on the P-Si system due to its potential application in quantum
computing and self-directed growth of molecular wires, has led us to study
structural changes induced by P upon placement on Si(001)-. Using
first-principles density functional theory (DFT) based pseudopotential method,
we have performed calculations for P-Si(001) system, starting from an isolated
P atom on the surface, and systematically increasing the coverage up to a full
monolayer. An isolated P atom can favorably be placed on an {\bf M} site
between two atoms of adjacent Si dimers belonging to the same Si dimer row. But
being incorporated in the surface is even more energetically beneficial due to
the participation of the {\bf M} site as a receptor for the ejected Si. Our
calculations show that up to 1/8 monolayer coverage, hetero-dimer structure
resulting from replacement of surface Si atoms with P is energetically
favorable. Recently observed zig-zag features in STM are found to be consistent
with this replacement process. As coverage increases, the hetero-dimers give
way to P-P ortho-dimers on the Si dimer rows. This behavior is similar to that
of Si-Si d-dimers but are to be contrasted with the Al-Al dimers, which are
found between adjacent Si dimers rows and in a para-dimer arrangement. Unlike
Al-Si system P-Si does not show any para to ortho transition. For both systems,
the surface reconstruction is lifted at about one monolayer coverage. These
calculations help us in understanding the experimental data obtained using
scanning tunneling microscope.Comment: To appear in PR
Stationary localized states due to nonlinear impurities described by the modified discrete nonlinear Schr\"odinger equation
The modified discrete nonlinear Schr\"odinger equation is used to study the
formation of stationary localized states in a one-dimensional lattice with a
single impurity and an asymmetric dimer impurity. A periodically modulated and
a perfectly nonlinear chain is also considered. Phase diagrams of localized
states for all systems are presented. From the mean square displacement
calculation, it is found that all states are not localized even though the
system comprises random nonlinear site energies. Stability of the states is
discussed.Comment: Six pages including five figure
New way to achieve chaotic synchronization in spatially extended systems
We study the spatio-temporal behavior of simple coupled map lattices with
periodic boundary conditions. The local dynamics is governed by two maps,
namely, the sine circle map and the logistic map respectively. It is found that
even though the spatial behavior is irregular for the regularly coupled
(nearest neighbor coupling) system, the spatially synchronized (chaotic
synchronization) as well as periodic solution may be obtained by the
introduction of three long range couplings at the cost of three nearest
neighbor couplings.Comment: 5 pages (revtex), 7 figures (eps, included