Universal behavior of quantum Green's functions

We consider a general one-particle Hamiltonian H = - \Delta_r + u(r) defined in a d-dimensional domain. The object of interest is the time-independent Green function G_z(r,r') = . Recently, in one dimension (1D), the Green's function problem was solved explicitly in inverse form, with diagonal elements of Green's function as prescribed variables. The first aim of this paper is to extract from the 1D inverse solution such information about Green's function which cannot be deduced directly from its definition. Among others, this information involves universal, i.e. u(r)-independent, behavior of Green's function close to the domain boundary. The second aim is to extend the inverse formalism to higher dimensions, especially to 3D, and to derive the universal form of Green's function for various shapes of the confining domain boundary.Comment: 46 pages, the shortened version submitted to J. Math. Phy

The violation of the Hund's rule in semiconductor artificial atoms

The unrestricted Pople-Nesbet approach for real atoms is adapted to quantum dots, the man-made artificial atoms, under applied magnetic field. Gaussian basis sets are used instead of the exact single-particle orbitals in the construction of the appropriated Slater determinants. Both system chemical potential and charging energy are calculated, as also the expected values for total and z-component in spin states. We have verified the validity of the energy shell structure as well as the Hund's rule state population at zero magnetic field. Above given fields, we have observed a violation of the Hund's rule by the suppression of triplets and quartets states at the 1p energy shell, taken as an example. We also compare our present results with those obtained using the LS-coupling scheme for low electronic occupations. We have focused our attention to ground-state properties for GaAs quantum dots populated up to forty electrons.Comment: 5 pages, 2 figures, submitted to Semic. Sci. Techno