Carbon monoxide formation during aerobic biostabilization of the organic fraction of municipal solid waste: the influence of technical parameters in a full-scale treatment system

The present study sought to investigate the formation of carbon monoxide (CO) during aerobic biostabilization (AB) of the organic fraction of municipal solid waste (OFMSW) in forced aerated piles. Understanding the factors influencing CO formation may be important not only for safety, but also for environmental and technical reasons. The objective of the study was to determine the effect of the technical parameters of the piles on the concentration of CO in the process gas during AB of the OFMSW in a full-scale waste treatment system: rate of waste aeration (from 3365 to 12,744 m3∙Mg−1), waste mass loads in the pile (from 391 to 702 Mg), thermal conditions, application of sidewalls as an element of pile bioreactor construction, concentration of O2 and CO2 in the waste piles and the duration of the process from 6 to 9 weeks. The temperature and concentration of O2, CO2, CO, CH4 were measured in each pile at weekly intervals. All six reactors provide stable thermal and aerobic conditions, but the presence of CO was observed, ranging from a few to over 2000 ppm, which demonstrated that ensuring optimum conditions for the process is not sufficient for CO to be eliminated. A moderate, non-linear rise in CO concentration was observed along with a rise in the temperature inside the reactors. Concentrations of CO were not highly correlated with those of O2 or CO2. An increase in waste mass loads increased the CO concentration in waste piles, while application of sidewalls decreased CO concentration. Increasing aeration rate had an influence on CO production, and the highest CO concentrations were noted under air flow rate 5.3 m3·Mg−1·h−1

Aerobic biostabilization of the organic fraction of municipal solid waste-monitoring hot and cold spots in the reactor as a novel tool for process optimization

The process of aerobic biostabilization (AB) has been adopted for treatment of the organic fraction of municipal solid waste (OFMSW). However, thermal gradients and some side effects in the bioreactors present difficulties in optimization of AB. Forced aeration is more effective than natural ventilation of waste piles, but “hot and cold spots” exist due to inhomogeneous distribution of air and heat. This study identified the occurrence of hot and cold spots during the OFMSW biostabilization process at full technical scale. It was shown that the number of hot and cold spots depended on the size of the pile and aeration rate. When the mass of stabilized waste was significantly lower and the aeration rate was two-fold higher the number of anaerobic hot spots decreased, while cold spots increased. In addition, the results indicated that pile construction with sidewalls decreased the number of hot spots. However, channelizing the airflow under similar conditions increased the number of cold spots. Knowledge of the spatial and temporal distribution of process gases can enable optimization and adoption of the OFMSW flow aeration regime. Temperature monitoring within the waste pile enables the operator to eliminate undesirable “hot spots” by modifying the aeration regime and hence improve the overall treatment efficiency

Oxygen transfer capacity as a measure of water aeration by floating reed plants: initial laboratory studies

Reed-Phragmites australis (Cav.) Trin. ex Steud, an aquatic plant, commonly used in constructed wetlands for wastewater treatment, supplies oxygen into the subsurface environment. Reed may be used as a ‘green machine’ in the form of a floating vegetation cover with many applications: wastewater lagoons, manure lagoons or sewage sludge lagoons. An important measure of the performance of the plant system is the oxygen transfer capacity (OTC). Accurate prediction of the OTC in relation to reed biomass would be crucial in modelling its influence on organic matter degradation and ammonia–nitrogen oxygenation in such lagoons. Laboratory experiments aiming to determine OTC and its dependence on reed biomass were carried out. Eight plants with a total dry mass ranging from approximately 3 to 7 g were tested. Mean OTC was determined per plant: 0.18 ± 0.21 (g O2·m−3·h−1·plant−1), with respect to leaves-and-stem dry mass (dlsm): 44.91 ± 35.21 (g O2·m−3·h−1·g dlsm−1), and to total dry mass (dtm): 33.25 ± 27.97 (g O2·m−3·h−1·g dtm−1). In relation to the relatively small root dry mass (drm), the OTC value was 136.02 ± 147.19 (g O2·m−3·h−1·g drm−1). Measured OTC values varied widely between the individual plants (variation coefficient 115%), in accordance with their differing size. Oxygenation performance was greatest in the reed plants with larger above ground dry mass (>4 g dlsm), but no influence of the root dry mass on the OTC rate was found

Willows and reeds for bioremediation of landfill leachate: redox potential in the root zone

Constructed wetlands can be used for bioremediation of landfill leachate (LL) making it safe to discharge into the environment. Wetland plants (reed and willow), contribute to pollutant removal, particularly of organic and nitrogen loads. Root exudates stimulate microbial activity and elevate oxygen levels in the rhizosphere which promotes nitrification. This study investigated the effects of reed and willow on bioremediation of LL in comparison with an unplanted control by measuring redox potential levels in the rhizosphere of microcosm systems in a greenhouse. Redox potential in the reed rhizosphere was consistently the highest, with the willow rhizosphere consistently the lowest. Redox potential fluctuated in the willow rhizosphere during daylight hours, with large decreases in the morning. Levels of NH4+ decreased dramatically in the first day of the experiment and remained at similar low levels in all tanks. Removal of ammonia took place in the control tank with peaks in NO2- and NO3-, but levels of NO3- remained high. Removal of ammonia was also observed in the reed tank with a peak in NO2-, but there was no peak in NO3-, as well as in the willow tank, but there were no peaks in NO2- or NO3-. Final levels of totalnitrogen, nitrate and chemical oxygen demand where considerably lower in the reed and willow tank than the unplanted control

Phytotoxicity of landfill leachate on willow- Salix amygdalina L.

Because of low investment and operational costs, interest is increasing in the use of willow plants in landfill leachate disposal. Toxic effects of leachate on the plants should be avoided in the initial period of growth and phytotoxicological testing may be helpful to select appropriate leachate dose rates. The aim of this study was to determine the phytotoxicity of landfill leachate on young willow (Salix amygdalina L.) cuttings, as a criterion for dose rate selection in the early phase of growth. Over a test period of 6 weeks plants were exposed to six concentrations of landfill leachate solutions (0%; 6.25%; 12.5%; 25%; 50% and 100%), under two different regimes. In regime A willow plants were cultivated in leachate solution from the beginning, whereas in regime B they were grown initially in clean water for 4 weeks, after which the water was exchanged for leachate solutions. The lowest effective concentration causing toxic effects (LOEC) was calculated (p < 0.05). In regime A LOEC was between 5.44% and 6.50% of leachate concentration, but slightly higher in regime B (5.32–6.59%). Willow plants were able to survive in landfill leachate solutions with electrical conductivity (EC) values up to 5.0 mS/cm in regime A, whereas in regime B plants were killed when EC exceeded 3.0 mS/cm. This indicates an ability of willow plants to tolerate higher strengths of landfill leachate if they are cultivated in such concentrations from the beginning

The influence of evapotranspiration on wastewater constructed wetland treatment efficiency

Owing to low investment and maintenance costs, there has been a growing interest in applying plants in wastewater treatment. Plants commonly used in constructed wetlands (CW) include: cattail, reed, rush, yellow flag, manna grass, and willow. In a CW, application of plants brings several benefits: creating aerobic conditions in the otherwise anaerobic rhizosphere, providing carbon compounds into the rhizosphere, uptaking pollutants (e.g. nutrients and heavy metals) from treated wastewater; improving the hydraulic conditions of wastewater flow through CW beds, and also increasing the available surface for growth of microbial biofilms. Hydrophytes also have great transpiration potential. Numerous studies have shown the importance of evapotranspiration during hot periods in natural wetlands and also in constructed wetlands. Evapotranspiration affects treatment efficiency in CWs: it increases the concentration of dissolved compounds due to decreasing water volume. Therefore, having regard to the mode of operating (VSSW or HSSW), temperature and influent characteristics (e.g. HLR and wastewater influent loads), the removal efficiency calculated as a comparison between initial and final concentration is lower, than expected from mass balance. Given results from systems in colder (Poland) and warmer (Portugal) climate conditions shows that the difference in methodology of removal efficiency calculation is significant, even if the CWs are operating in different modes. Usually, in the literature removal efficiency is expressed on the basis of concentrations, mostly due to lack of flow rate monitoring. Unfortunately, this may seriously underestimate treatment performance of CWs. This study suggests the need for routine monitoring of flow rate, or evaluation of potential evapotranspiration, to estimate removal efficiency of a CW based on mass balance.info:eu-repo/semantics/publishedVersio

The influence of evapotranspiration on vertical flow subsurface constructed wetland performance

This paper presents an example of the importance of evapotranspiration in constructed wetlands, with vertical subsurface flow, comparing different methods of treatment efficiency calculations and discussing the influence of evapotranspiration on removal rates. The application of reed, marked by high transpiration ability, is a cheap and effective method of landfill leachate disposal. A 2-year study examined the effectiveness of leachate treatment in constructed wetlands with reed. Two kinds of vertical subsurface flow systems: first with sand, and second with combined two layers of sewage sludge and sand has been tested. 1, 3, and 5 mmd(-1) hydraulic loading rates of landfill leachate have been applied. Daily evapotranspiration was in the range from 0.98 to 2.99 mmd(-1) in the first year of research and from 2.56 to 4.61 mmd(-1) in the second year. The influence of evapotranspiration rate on chemical oxygen demand (COD) removal rate was examined. Two methods of removal efficiency calculation have been used: first based on inlet and outlet COD concentrations, second on mass balance determination. Research showed that the removal efficiency calculated as a comparison between initial and final concentration is significantly lower, than expected from mass balance, especially, when higher hydraulic loading rates were applied

Oxygen transfer capacity of willow (Salix viminalis L.)

Willow Salix viminalis L. supplies oxygen into the subsurface environment. Laboratory experiments determined the willow Oxygen Transfer Capacity and its dependence on total leaf area and root wet mass. It was shown, that oxygen is released by roots under light conditions, and the rate of oxygen supplymay be greater than the rate of consumption due to respiration of roots. The mean OTC level was 195.7 [gO2.m−3.h−1.kgrwm−1]. Nonlinear relationship between OTC and both total leaf area and root wet mass was found, and confirmed by high determination coefficient (R2) values: 0.912 and 0.936