18 research outputs found
Concentration dependence of the low-shear viscosity of polyelectrolyte micro-networks: From hard spheres to soft microgels
The low-shear viscosity of polyelectrolyte microgels is studied as a function of concentration,
crosslink density and ionic strength. The variation of the viscosity with volume fraction is
very similar to that found in hard-sphere colloidal suspensions. In salt-free dispersions,
osmotic effects are responsible for the de-swelling of microgels at high polymer
concentration. This "softeningâ effect modifies the viscosity near the overlap concentration