Detection And Characterization of Forest Harvesting In Piedmont Through Sentinel-2 Imagery: A Methodological Proposal

This study evaluated the effectiveness of Sentinel-2 (S2) as a tool for early detection and estimation of forest harvesting in the Piemonte Region, which can be used by the regional forest administration. The priority was the detection, at the regional scale, of annual forest cover changes with the following goals: i) mapping of irregular (in respect of the regional Forestry Regulation) forest cuts; ii) quantification of the intensity of the silvicultural interventions. Results are expected to support forest police controls.The proposed procedure is based on a supervised classification approach based on Random Forest algorithm. Accuracy of harvested areas detection proved to be high (overall accuracy 98%). Characterization of the occurred forest cuts was obtained computingthe local coefficient of variationof the normalized difference vegetation index (NDVI) after harvesting, that showed to be a good predictor of forest harvesting intensity

Computational Speciation Models: A Tool for the Interpretation of Spectroelectrochemistry for Catalytic Layers under Operative Conditions

none7In this study,the first coupled FEXRAV and chemical speciation modelling study of the Pd deactivation is presented. Due to the high brilliance of synchrotron light, FEXRAV can investigat edeeply buried surfaces. More specifically, we directly analyzed the evolution of the Pd/C catalytic layer during a voltammetric cycle, through a specifically designed electrochemical cell. Still, we observed a complex interfacial chemistry of Pd, which impairs a straightforward interpretation of FEXRAV data. Exploiting thermodynamic chemical speciation modelling we were able to overcome this issue. The study leads to three main results: 1) the confirmation of the relationship between the change of the Pd/Pd(II) ratio and the change of the Fluorescence intensity 2) the investigation of the deactivation mechanism 3)the identification of the relevant species leading to the electrodissolution of Pd under operative conditions. This study opens new perspectives for the application of the chemical speciation modelling to the study of the deactivation mechanism of Pd in Pd/C catalytic layers under operative conditions in different electrolytes.mixedMontegrossi, G.; GIACCHERINI, ANDREA; BERRETTI, ENRICO; DI BENEDETTO, FRANCESCO; INNOCENTI, MASSIMO; D'Acapito, F.; LAVACCHI, ALESSANDROMontegrossi, G.; Giaccherini, Andrea; Berretti, Enrico; DI BENEDETTO, Francesco; Innocenti, Massimo; D'Acapito, F.; Lavacchi, Alessandr

Aluminizing via Ionic liquid electrodeposition and pack cementation: A comparative study with inconel 738 and a CoNiCrAlY

A novel aluminizing process based upon room temperature Al-electrodeposition from Ionic Liquids followed by diffusion heat treatment was applied on bare- and CoNiCrAlY-coated Inconel 738 (IN738). The aluminized samples were tested by isothermal oxidation at 1000 °C in air. The microstructural and chemical evolution of the samples were determined as function of oxidation time and compared with the currently applied coatings obtained via pack cementation. The newly proposed method is suitable for the CoNiCrAlY coating, but not for the bare IN738. In the latter, the formed Al-enriched layer is much thinner and the anticorrosion properties resulted in being reduced. This is probably due to the presence of precipitates, which slow down the aluminum inward diffusion impairing the formation of a well-developed interdiffusion zone (IDZ). Traces of the electrolyte, embedded during the Al-electrodeposition process, can be seen as the origin of these precipitates