4,954 research outputs found
J D Bernal: philosophy, politics and the science of science
This paper is an examination of the philosophical and political legacy of John Desmond Bernal. It addresses the evidence of an emerging consensus on Bernal based on the recent biography of Bernal by Andrew Brown and the reviews it has received. It takes issue with this view of Bernal, which tends to be admiring of his scientific contribution, bemused by his sexuality, condescending to his philosophy and hostile to his politics. This article is a critical defence of his philosophical and political position
The Jahn-Teller active fluoroperovskites : thermo- and magneto optical correlations as function of the -site
Chromium (II) fluoroperovskites are
strongly correlated Jahn-Teller active materials at low temperatures. In this
paper, we examine the role that the -site ion plays in this family of
fluoroperovskites using both experimental methods (XRD, optical absorption
spectroscopy and magnetic fields) and DFT simulations. Temperature-dependent
optical absorption experiments show that the spin-allowed transitions and
only merge completely for = Na at 2 K. Field-dependent optical
absorption measurements at 2 K show that the oscillating strength of the
spin-allowed transitions in increases with increasing
applied field. Direct magneto-structural correlations which suppress the
spin-flip transitions are observed for below its Ne\'el
temperature. In the spin-flip transitions vanish abruptly below
9 K revealing magneto-optical correlations not linked to crystal structure
changes. This suggests that as the long range ordering is reduced local JT
effects in the individual octahedra take control of the
observed behavior. Our results show clear deviation from the pattern found for
the isoelectronic system. The size of the -site cation
is shown to be central in dictating the physical properties and phase
transitions in , opening up the possibility of varying the
composition to create novel states of matter with tuneable properties
J D Bernal: philosophy, politics and the science of science
This paper is an examination of the philosophical and political legacy of John Desmond Bernal. It addresses the evidence of an emerging consensus on Bernal based on the recent biography of Bernal by Andrew Brown and the reviews it has received. It takes issue with this view of Bernal, which tends to be admiring of his scientific contribution, bemused by his sexuality, condescending to his philosophy and hostile to his politics. This article is a critical defence of his philosophical and political position
Dimensional analysis and Rutherford Scattering
Dimensional analysis, and in particular the Buckingham theorem is
widely used in fluid mechanics. In this article we obtain an expression for the
impact parameter from Buckingham's theorem and we compare our result with
Rutherford's original discovery found in the early twentieth century
Weak distinction and the optimal definition of causal continuity
Causal continuity is usually defined by imposing the conditions (i)
distinction and (ii) reflectivity. It is proved here that a new causality
property which stays between weak distinction and causality, called feeble
distinction, can actually replace distinction in the definition of causal
continuity. An intermediate proof shows that feeble distinction and future
(past) reflectivity implies past (resp. future) distinction. Some new
characterizations of weak distinction and reflectivity are given.Comment: 9 pages, 2 figures. v2: improved and expanded version. v3: a few
misprints have been corrected and a reference has been update
Structure of plastically compacting granular packings
The developing structure in systems of compacting ductile grains were studied
experimentally in two and three dimensions. In both dimensions, the peaks of
the radial distribution function were reduced, broadened, and shifted compared
with those observed in hard disk- and sphere systems. The geometrical
three--grain configurations contributing to the second peak in the radial
distribution function showed few but interesting differences between the
initial and final stages of the two dimensional compaction. The evolution of
the average coordination number as function of packing fraction is compared
with other experimental and numerical results from the literature. We conclude
that compaction history is important for the evolution of the structure of
compacting granular systems.Comment: 12 pages, 12 figure
Dynamical Arrest in Attractive Colloids: The Effect of Long-Range Repulsion
We study gelation in suspensions of model colloidal particles with
short-ranged attractive and long-ranged repulsive interactions by means of
three-dimensional fluorescence confocal microscopy. At low packing fractions,
particles form stable equilibrium clusters. Upon increasing the packing
fraction the clusters grow in size and become increasingly anisotropic until
finally associating into a fully connected network at gelation. We find a
surprising order in the gel structure. Analysis of spatial and orientational
correlations reveals that the gel is composed of dense chains of particles
constructed from face-sharing tetrahedral clusters. Our findings imply that
dynamical arrest occurs via cluster growth and association.Comment: Final version: Phys. Rev. Lett. 94, 208301 (2005
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