1,988 research outputs found
Reconstruction and thermal stability of the cubic SiC(001) surfaces
The (001) surfaces of cubic SiC were investigated with ab-initio molecular
dynamics simulations. We show that C-terminated surfaces can have different
c(2x2) and p(2x1) reconstructions, depending on preparation conditions and
thermal treatment, and we suggest experimental probes to identify the various
reconstructed geometries. Furthermore we show that Si-terminated surfaces
exhibit a p(2x1) reconstruction at T=0, whereas above room temperature they
oscillate between a dimer row and an ideal geometry below 500 K, and sample
several patterns including a c(4x2) above 500 K.Comment: 12 pages, RevTeX, figures 1 and 2 available in gif form at
http://irrmawww.epfl.ch/fg/sic/fig1.gif and
http://irrmawww.epfl.ch/fg/sic/fig2.gi
Beyond persons: extending the personal / subpersonal distinction to non-rational animals and artificial agents
The distinction between personal level explanations and subpersonal ones has been subject to much debate in philosophy. We understand it as one between explanations that focus on an agent’s interaction with its environment, and explanations that focus on the physical or computational enabling conditions of such an interaction. The distinction, understood this way, is necessary for a complete account of any agent, rational or not, biological or artificial. In particular, we review some recent research in Artificial Life that pretends to do completely without the distinction, while using agent-centered concepts all the way. It is argued that the rejection of agent level explanations in favour of mechanistic ones is due to an unmotivated need to choose among representationalism and eliminativism. The dilemma is a false one if the possibility of a radical form of externalism is considered
Bombyx mori silk/titania/gold hybrid materials for photocatalytic water splitting: combining renewable raw materials with clean fuels
The synthesis, structure, and photocatalytic water splitting performance of two new titania (TiO2)/gold(Au)/Bombyx mori silk hybrid materials are reported. All materials are monoliths with diameters of up to ca. 4.5 cm. The materials are macroscopically homogeneous and porous with surface areas between 170 and 210 m2/g. The diameter of the TiO2 nanoparticles (NPs) – mainly anatase with a minor fraction of brookite – and the Au NPs are on the order of 5 and 7–18 nm, respectively. Addition of poly(ethylene oxide) to the reaction mixture enables pore size tuning, thus providing access to different materials with different photocatalytic activities. Water splitting experiments using a sunlight simulator and a Xe lamp show that the new hybrid materials are effective water splitting catalysts and produce up to 30 mmol of hydrogen per 24 h. Overall the article demonstrates that the combination of a renewable and robust scaffold such as B. mori silk with a photoactive material provides a promising approach to new monolithic photocatalysts that can easily be recycled and show great potential for application in lightweight devices for green fuel production
Evidence of random magnetic anisotropy in ferrihydrite nanoparticles based on analysis of statistical distributions
We show that the magnetic anisotropy energy of antiferromagnetic ferrihydrite
depends on the square root of the nanoparticles volume, using a method based on
the analysis of statistical distributions. The size distribution was obtained
by transmission electron microscopy, and the anisotropy energy distributions
were obtained from ac magnetic susceptibility and magnetic relaxation. The
square root dependence corresponds to random local anisotropy, whose average is
given by its variance, and can be understood in terms of the recently proposed
single phase homogeneous structure of ferrihydrite.Comment: 6 pages, 2 figure
Seleção genômica ampla para os componentes da eficiência no uso de fósforo em milho.
O objetivo deste trabalho foi verificar a eficácia do método da seleção genomica ampla (GWS) no melhoramentode milho para os componentes da eficiência no uso de fósforo (EUP). Para isto, foram avaliadas 41 combinações hÃbridas de milho, em alta e baixa disponibilidade de P, em casa de vegetação pertencente ao Departamento de Fitotecnia da Universidade Federal de Viçosa, em outubro de 2010. As plantas foram coletadas no estádio V6. Foram estimados os dois componentes da EUP, que são as eficiências de absorção e de utilização de N. Os dados obtidos foram submetidos a análises estatÃsticas via metodologia REML/BLUP. Na genotipagem da população de estimação, foram utilizados 80 marcadores microssatélites (SSR). A predição dos valores genéticos genômicos dos hÃbridos foi obtida via RR-BLUP/GWS. Para os caracteres em que a GWS apresentou altos valores de acurácia seletiva, ela foi comparada com a seleção recorrente intrapopulacional. Com o uso da GWS houve um aumento significativo na acurácia seletiva, nos ganhos estimados por unidade de tempo
Quenching through Dirac and semi-Dirac points in optical Lattices: Kibble-Zurek scaling for anisotropic Quantum-Critical systems
We propose that Kibble-Zurek scaling can be studied in optical lattices by
creating geometries that support, Dirac, Semi-Dirac and Quadratic Band
Crossings. On a Honeycomb lattice with fermions, as a staggered on-site
potential is varied through zero, the system crosses the gapless Dirac points,
and we show that the density of defects created scales as , where
is the inverse rate of change of the potential, in agreement with the
Kibble-Zurek relation. We generalize the result for a passage through a
semi-Dirac point in dimensions, in which spectrum is linear in parallel
directions and quadratic in rest of the perpendicular directions. We
find that the defect density is given by where
and are the dynamical exponents and the correlation
length exponents along the parallel and perpendicular directions, respectively.
The scaling relations are also generalized to the case of non-linear quenching
Structure, thermal properties, conductivity and electrochemical stability of di-urethanesil hybrids doped with LiCF3SO3
Variable chain length di-urethane cross-linked poly(oxyethylene) (POE)/siloxane hybrid networks were prepared by application of a sol-gel strategy. These materials, designated as di-urethanesils (represented as d-Ut(Y’), where Y’ indicates the average molecular weight of the polymer segment), were doped with lithium triflate (LiCF3SO3). The two host hybrid matrices used, d-Ut(300) and d-Ut(600), incorporate POE chains with approximately 6 and 13 (OCH2CH2) repeat units, respectively. All the samples studied, with compositions ∞ > n ≥ 1 (where n is the molar ratio of (OCH2CH2) repeat units per Li+),, are entirely amorphous. The di-urethanesils are thermally stable up to at least 200 ºC. At room temperature the conductivity maxima of the d-Ut(300)- and d-Ut(600)-based di-urethanesil families are located at n = 1 (approximately 2.0x10-6 and 7.4x10-5 Scm-1, respectively). At about 100 ºC, both these samples also exhibit the highest conductivity of the two electrolyte systems (approximately 1.6x10-4 and 1.0x10-3 Scm-1, respectively). The d-Ut(600)-based xerogel with n = 1 displays excellent redox stability.Fundação para a Ciência e a Tecnologia (FCT
Short chain U(600) di-urea cross-linked poly(oxyethylene)/siloxane ormolytes doped with lanthanum triflate salt
Promising La3+-doped electrolytes based on a hybrid poly(oxyethylene)/siliceous host matrix, U(600), have been produced. The organic and inorganic components of the hybrid structure are covalently bonded through urea linkages. The low molecular weight of the polyether segments of U(600) is thought to be responsible for the total amorphous character and high conductivity at room temperature (1.1×10−4 S cm−1) of these ormolytes.Fundação para a Ciência e a Tecnologia (FCT
Seleção genômica ampla para os componentes da eficiência no uso de nitrogênio em milho.
O objetivo deste trabalho foi verificar a eficácia do método da seleção genômica ampla (GWS) no melhoramento demilho para os componentes da eficiência no uso de nitrogênio (EUN). Para isto, foram avaliadas 41 combinações hÃbridas de milho, em alta e baixa disponibilidade de N, em casa de vegetação pertencente ao Departamento de Fitotecnia da Universidade Federal de Viçosa, em outubro de 2010. As plantas foram coletadasno estádio V6. Foram estimados os dois componentes da EUN, que são as eficiências na absorção e na utilização de N. Os dados obtidos foram submetidos a análises estatÃsticas via metodologia REML/BLUP. Na genotipagem da população de estimação, foram utilizados 80 marcadores microssatélites (SSR). A predição dos valores genéticos genômicos dos hÃbridos foi obtida via RR-BLUP/GWS. Para os caracteres em que a GWS apresentou altos valores de acurácia seletiva, ela foi comparada com a seleção recorrente intrapopulacional. Com o uso daGWS houve um aumento significativo na acurácia seletiva e nos ganhos estimados por unidade de tempo para os componentes da eficiência no uso de nitrogênio em milho em alto e baixo nitrogênio
Decoherence-protected quantum gates for a hybrid solid-state spin register
Protecting the dynamics of coupled quantum systems from decoherence by the
environment is a key challenge for solid-state quantum information processing.
An idle qubit can be efficiently insulated from the outside world via dynamical
decoupling, as has recently been demonstrated for individual solid-state
qubits. However, protection of qubit coherence during a multi-qubit gate poses
a non-trivial problem: in general the decoupling disrupts the inter-qubit
dynamics, and hence conflicts with gate operation. This problem is particularly
salient for hybrid systems, wherein different types of qubits evolve and
decohere at vastly different rates. Here we present the integration of
dynamical decoupling into quantum gates for a paradigmatic hybrid system, the
electron-nuclear spin register. Our design harnesses the internal resonance in
the coupled-spin system to resolve the conflict between gate operation and
decoupling. We experimentally demonstrate these gates on a two-qubit register
in diamond operating at room temperature. Quantum tomography reveals that the
qubits involved in the gate operation are protected as accurately as idle
qubits. We further illustrate the power of our design by executing Grover's
quantum search algorithm, achieving fidelities above 90% even though the
execution time exceeds the electron spin dephasing time by two orders of
magnitude. Our results directly enable decoherence-protected interface gates
between different types of promising solid-state qubits. Ultimately, quantum
gates with integrated decoupling may enable reaching the accuracy threshold for
fault-tolerant quantum information processing with solid-state devices.Comment: This is original submitted version of the paper. The revised and
finalized version is in print, and is subjected to the embargo and other
editorial restrictions of the Nature journa
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