1 research outputs found
Impact of Selected LiPF<sub>6</sub> Hydrolysis Products on the High Voltage Stability of Lithium-Ion Battery Cells
Diverse
LiPF<sub>6</sub> hydrolysis products evolve during lithium-ion battery
cell operation at elevated operation temperatures and high operation
voltages. However, their impact on the formation and stability of
the electrode/electrolyte interfaces is not yet investigated and understood.
In this work, literature-known hydrolysis products of LiPF<sub>6</sub> dimethyl fluorophosphate (DMFP) and diethyl fluorophosphate (DEFP)
were synthesized and characterized. The use of DMFP and DEFP as electrolyte
additive in 1 M LiPF<sub>6</sub> in EC:EMC (1:1, by wt) was investigated
in LiNi<sub>1/3</sub>Mn<sub>1/3</sub>Co<sub>1/3</sub>O<sub>2</sub>/Li half cells. When charged to a cutoff potential of 4.6 V vs Li/Li<sup>+</sup>, the additive containing cells showed improved cycling stability,
increased Coulombic efficiencies, and prolonged shelf life. Furthermore,
low amounts (1 wt % in this study) of the aforementioned additives
did not show any negative effect on the cycling stability of graphite/Li
half cells. DMFP and DEFP are susceptible to oxidation and contribute
to the formation of an effective cathode/electrolyte interphase as
confirmed by means of electrochemical stability window determination,
and X-ray photoelectron spectroscopy characterization of pristine
and cycled electrodes, and they are supported by computational calculations