Buprestidae, Cerambycidae, and Scolytidae Associated with Successive Stages of \u3ci\u3eAgrilus Bilineatus\u3c/i\u3e (Coleoptera: Buprestidae) Infestation of Oaks in Wisconsin

The species of Buprestidae, Cerambycidae, and Scolytidae found in association with Agrilus bilineatus (Weber) in declining oaks, Quercus spp., in Wisconsin, were Chrysobothris femorata (Olivier) and Dicerca sp. (Buprestidae); Amniscus macula (Say),Cyrtaphorus verrucosus (Olivier), Euderces picipes (Fabricius), Graphisurus fasciatus (DeGeer), Neodytus acuminatus (Fabricius), Sarosesthes fulminans (Fabricius), and Xylotrechus colonus (Fabricius) (Cerambycidae); and Monarthrum fasciatum (Say), Monarthrum mali (Fitch), Pseudopityophthorus minutissimus (Zimmerman), and Xylaterinus politus (Say) (Scolytidae). In general, weakened oaks were first attacked by A. bilineatus. and at times that same year by C. femorata. G. fasdalus, and P. minutissimus. Infestation by M.fasciatum, M. mali, and X. politus began the season following first attack by A. bilineatus. With the exception of A. bilineatus, the above mentioned Buprestidae and Cerambycidae appeared to preferentially infest dead wood, often those portions that had died the previous season

Quantum computation via translation-invariant operations on a chain of qubits

A scheme of universal quantum computation on a chain of qubits is described that does not require local control. All the required operations, an Ising-type interaction and spatially uniform simultaneous one-qubit gates, are translation-invariant.Comment: Comment after Eq. (2) inserted, journal versio

BCFA: Bespoke Control Flow Analysis for CFA at Scale

Many data-driven software engineering tasks such as discovering programming patterns, mining API specifications, etc., perform source code analysis over control flow graphs (CFGs) at scale. Analyzing millions of CFGs can be expensive and performance of the analysis heavily depends on the underlying CFG traversal strategy. State-of-the-art analysis frameworks use a fixed traversal strategy. We argue that a single traversal strategy does not fit all kinds of analyses and CFGs and propose bespoke control flow analysis (BCFA). Given a control flow analysis (CFA) and a large number of CFGs, BCFA selects the most efficient traversal strategy for each CFG. BCFA extracts a set of properties of the CFA by analyzing the code of the CFA and combines it with properties of the CFG, such as branching factor and cyclicity, for selecting the optimal traversal strategy. We have implemented BCFA in Boa, and evaluated BCFA using a set of representative static analyses that mainly involve traversing CFGs and two large datasets containing 287 thousand and 162 million CFGs. Our results show that BCFA can speedup the large scale analyses by 1%-28%. Further, BCFA has low overheads; less than 0.2%, and low misprediction rate; less than 0.01%.Comment: 12 page

Rovibrational Resonance Effects In Collision-Induced Electronic Energy Transfer: I2(E,v=0-2)+CF4

Collisions of I-2 in the E(0(g)(+)) electronic state with CF4 molecules induce electronic energy transfer to the nearby D, beta, and D-\u27 ion-pair states. Simulations of dispersed fluorescence spectra reveal collision-induced electronic energy transfer rate constants and final vibrational state distributions within each final electronic state. In comparison with earlier reports on I-2(upsilon(E)=0-2) collisions with He or Ar atoms, we find markedly different dynamics when I-2, excited to the same rovibronic states, collides with CF4. Final vibrational state distributions agree with the associated Franck-Condon factors with the initially prepared state to a greater degree than those found with He or Ar collision partners and suggest that internal degrees of freedom in the CF4 molecule represent a substantial means for accepting the accompanying loss of I-2 vibronic energy. Comparison of the E -\u3e D transfer of I-2 excited to the J=23 and J=55 levels of the upsilon(E)=0 state reveals the onset of specific, nonstatistical dynamics as the available energy is increased above the threshold for excitation of the low frequency nu(2) bending mode of CF4. (c) 2006 American Institute of Physics

Thermally Stable, Latent Olefin Metathesis Catalysts

Highly thermally stable N-aryl, N-alkyl N-heterocyclic carbene (NHC) ruthenium catalysts were designed and synthesized for latent olefin metathesis. These catalysts showed excellent latent behavior toward metathesis reactions, whereby the complexes were inactive at ambient temperature and initiated at elevated temperatures, a challenging property to achieve with second-generation catalysts. A sterically hindered N-tert-butyl substituent on the NHC ligand of the ruthenium complex was found to induce latent behavior toward cross-metathesis reactions, and exchange of the chloride ligands for iodide ligands was necessary to attain latent behavior during ring-opening metathesis polymerization (ROMP). Iodide-based catalysts showed no reactivity toward ROMP of norbornene-derived monomers at 25 °C and upon heating to 85 °C gave complete conversion of monomer to polymer in less than 2 h. All of the complexes were very stable to air, moisture, and elevated temperatures up to at least 90 °C and exhibited a long catalyst lifetime in solution at elevated temperatures