2 research outputs found
Rydberg trimers and excited dimers bound by internal quantum reflection
Quantum reflection is a pure wave phenomena that predicts reflection of a
particle at a changing potential for cases where complete transmission occurs
classically. For a chemical bond, we find that this effect can lead to
non-classical vibrational turning points and bound states at extremely large
interatomic distances. Only recently has the existence of such ultralong-range
Rydberg molecules been demonstrated experimentally. Here, we identify a broad
range of molecular lines, most of which are shown to originate from two
different novel sources: a single-photon associated triatomic molecule formed
by a Rydberg atom and two ground state atoms and a series of excited dimer
states that are bound by a so far unexplored mechanism based on internal
quantum reflection at a steep potential drop. The properties of the Rydberg
molecules identified in this work qualify them as prototypes for a new type of
chemistry at ultracold temperatures.Comment: 6 pages, 3 figures, 1 tabl
Formation and interactions of cold and ultracold molecules: new challenges for interdisciplinary physics
Progress on researches in the field of molecules at cold and ultracold
temperatures is reported in this review. It covers extensively the experimental
methods to produce, detect and characterize cold and ultracold molecules
including association of ultracold atoms, deceleration by external fields and
kinematic cooling. Confinement of molecules in different kinds of traps is also
discussed. The basic theoretical issues related to the knowledge of the
molecular structure, the atom-molecule and molecule-molecule mutual
interactions, and to their possible manipulation and control with external
fields, are reviewed. A short discussion on the broad area of applications
completes the review.Comment: to appear in Reports on Progress in Physic