Study of the microstructure of the grade 91 steel after more than 100.000h of creep exposure at 600°C

International audienceThis paper presents results on the evolution of microstructure (both matrix and precipitates) of an ASME Grade 91 steel that has been creep tested for 113,431 h at 600 °C under a load of 80 MPa. The microstructure was investigated using transmission electron microscopy (TEM) and revealed chromium rich M23C6 carbides, MX-type precipitates, Laves phases and modified Z-phases. Only a small amount of modified Z-phase was found. In order to quantify coarsening of precipitates and growth of new phases during creep, the size distributions of the identified precipitates were determined by analysis of TEM images. In addition to this, the size distribution of Laves phases was determined by image analysis of scanning electron micrographs. Substructure modifications and creep damage were investigated on cross sections of the creep specimen using Electron Backscatter Diffraction and Scanning Electron Microscopy

Evolution of dislocation density, size of subgrains and MX-type precipitates in a P91 steel during creep and during thermal ageing at 600 °C for more than 100,000 h

International audienceThere are rather few quantitative data on the microstructure of the 9–12%Cr heat resistant steels after long-term creep. This paper presents results of the quantitative measurement of the size of MX precipitates, subgrain size and dislocation density in a P91 steel that had been creep tested for 113,431 h at 600 °C. The same measurements were conducted in the same P91 steel in the as received conditions. Transmission electron microscopy investigations were conducted using thin foils and revealed a decrease in dislocation density and an increase in subgrain size after creep exposure. MX carbonitrides are very stable during thermal and creep exposure of P91 steel at 600 °C up to 113,431 h. Electron backscatter diffraction (EBSD) investigations also revealed a significant change in the substructure of the steel after creep exposure

Long term aging effect on the creep strength of the T92 steel

International audienceCreep strength loss of T92 steel after long-term creep exposure at 600°C and 650°C is partially due to a thermal aging of the steel during the first part of the test. In order to quantify the effect of long-term aging on the creep strength loss, creep tests were conducted at 600 and 650°C on T92 steel thermally aged for 10,000h at the same temperature and on as-received T92 steel. Laves phases precipitates were found after thermal aging at 600°C and 650°C with an average equivalent diameter of about 200nm and of about 350nm, respectively. No significant change in hardness and in the matrix substructure as revealed by electron backscatter diffraction occurred during aging. For stresses higher than 170MPa at 600°C and higher than 110MPa at 650°C the time to rupture is four times lower in the aged steels compared to the as-received steel, this is correlated to a secondary creep rate four times higher for the aged specimens compared to that of the as-received steel. Creep tests conducted at 650°C under lower stresses revealed a creep lifetime only twice lower after aging

Instability of the rhodium magnetic moment as origin of the metamagnetic phase transition in alpha-FeRh

Based on ab initio total energy calculations we show that two magnetic states of rhodium atoms together with competing ferromagnetic and antiferromagnetic exchange interactions are responsible for a temperature induced metamagnetic phase transition, which experimentally is observed for stoichiometric alpha-FeRh. A first-principle spin-based model allows to reproduce this first-order metamagnetic transition by means of Monte Carlo simulations. Further inclusion of spacial variation of exchange parameters leads to a realistic description of the experimental magneto-volume effects in alpha-FeRh.Comment: 10 pages, 13 figures, accepted for publication in Phys. Rev.

Impact of age norms and stereotypes on managers' hiring decisions of retirees

Purpose -Our study investigates the role of managers in the re-employment of early retirees and asks what the effect is of managers’ age norms and stereotypes on managers’ employment decisions. Design/methodology/approach- A combination of a factorial study and a survey was conducted. First, information on the age norms and stereotypes was collected. Secondly, profiles of hypothetical retired job applicants were presented to the employers, who were asked to make a specific hiring decision. The information collected during both studies was combined in the analysis and multilevel models were estimated. Findings -The results indicate that higher age norms result in a higher propensity to hire an early retiree. Stereotypes, by contrast, do not influence managers’ decisions. Early retirees’ chances for re-employment are also related to their own circumstances (physical appearance and relevant experience) and organisational forces, as they are hired when organisations face labour force shortages. Research limitation / implications – with the use of vignettes study we deal with hypothetical hiring situation. Originality value- Although the effect of age norms and age stereotypes has been often suggested, not much empirical evidence was presented to support this notion. Our study estimates the effect of age norms and stereotypes on hiring decision. key words: bridge employment; early retirees; age norms; age stereotypes; multilevel models.

FEASIBILITY OF CROSS-FLOW MICROFILTRATIONFOR COMBINED SEWER OVERFLOWS

Combined sewer overflows contribute high levels of suspended solids, pathogenic microorganisms, oxygen-demanding compounds and other pollutants into the receiving stream [US EPA, 2001]. The level of pollution coupled with regulatory pressure is challenging communities to find feasible treatment alternatives. Microfiltration may be a preferred treatment alternative. The feasibility of cross-flow microfiltration for the treatment of a dilute primary sewage effluent simulating combined sewer overflow wastewater was investigated. Ceramic membranes of various pores sizes (0.05 - 5.0 um) were tested at the bench and field scale to understand the impact of operating conditions on the permeate water quality and flux rate. A 0.2 um membrane operated with a 1.8 m/s cross flow velocity, a transmembrane pressure less than 2.1 bar and a backpulse frequency of 60 seconds were selected as the preferred operating conditions. The 0.2 um membrane consistently met water quality objectives for fecal coliforms, E Coli, enterococci, BOD5 and SS. The steady state flux rates are impacted by the feed suspended solids concentration and temperature, and an understanding of these parameters is critical to commercial scale design