521 research outputs found
Magnetic ground state and 2D behavior in pseudo-Kagome layered system Cu3Bi(SeO3)2O2Br
Anisotropic magnetic properties of a layered kagome-like system
Cu3Bi(SeO3)2O2Br have been studied by bulk magnetization and magnetic
susceptibility measurements as well as powder and single-crystal neutron
diffraction. At T_N = 27.4 K the system develops an alternating
antiferromagnetic order of (ab) layers, which individually exhibit canted
ferrimagnetic moment arrangement, resulting from the competing ferro- and
antiferro-magnetic intralayer exchange interactions. A magnetic field B_C ~ 0.8
T applied along the c axis (perpendicular to the layers) triggers a
metamagnetic transition, when every second layer flips, i.e., resulting in a
ferrimagnetic structure. Significantly higher fields are required to rotate the
ferromagnetic component towards the b axis (~7 T) or towards the a axis (~15
T). The estimates of the exchange coupling constants and features indicative of
an XY character of this quasi-2D system are presented.Comment: 7 pages, 6 figures, final versio
Spin anisotropy effects in dimer single molecule magnets
We present a model of equal spin dimer single molecule magnets. The
spins within each dimer interact via the Heisenberg and the most general set of
four quadratic anisotropic spin interactions with respective strengths and
, and with the magnetic induction . We solve the model
exactly for , and for antiferromagnetic Heisenberg couplings
(), present curves at low for these cases. Low-
curves for and electron paramagnetic susceptibility
for are also provided. For weak anisotropy
interactions, we employ a perturbative treatment, and show that the Hartree and
extended Hartree approximations lead to reliable analytic results at low
and large for these quantities and for the inelastic neutron scattering
cross-section . Our results are discussed with
regard to existing experiments on Fe dimer
single molecule magnets, and suggest that one of them contains a substantial
amount of single-ion anisotropy, without any sizeable global spin anisotropy.
We urge further experiments of the above types on single crystals of Fe and
on some [Mn] dimers, in order to elucidate the precise values
of the various microscopic interactions.Comment: 30 pages, 25 figures, submitted to Phys. Rev.
Single-ion and exchange anisotropy effects and multiferroic behavior in high-symmetry tetramer single molecule magnets
We study single-ion and exchange anisotropy effects in equal-spin
tetramer single molecule magnets exhibiting , , ,
, , or ionic point group symmetry. We first write the
group-invariant quadratic single-ion and symmetric anisotropic exchange
Hamiltonians in the appropriate local coordinates. We then rewrite these local
Hamiltonians in the molecular or laboratory representation, along with the
Dzyaloshinskii-Moriay (DM) and isotropic Heisenberg, biquadratic, and
three-center quartic Hamiltonians. Using our exact, compact forms for the
single-ion spin matrix elements, we evaluate the eigenstate energies
analytically to first order in the microscopic anisotropy interactions,
corresponding to the strong exchange limit, and provide tables of simple
formulas for the energies of the lowest four eigenstate manifolds of
ferromagnetic (FM) and anitiferromagnetic (AFM) tetramers with arbitrary .
For AFM tetramers, we illustrate the first-order level-crossing inductions for
, and obtain a preliminary estimate of the microscopic
parameters in a Ni from a fit to magnetization data.
Accurate analytic expressions for the thermodynamics, electron paramagnetic
resonance absorption and inelastic neutron scattering cross-section are given,
allowing for a determination of three of the microscopic anisotropy
interactions from the second excited state manifold of FM tetramers. We also
predict that tetramers with symmetries and should exhibit both
DM interactions and multiferroic states, and illustrate our predictions for
.Comment: 30 pages, 14 figures, submitted to Phys. Rev.
Spin dynamics in the low-dimensional magnet TiOCl
We present detailed ESR investigations on single crystals of the
low-dimensional quantum magnet TiOCl. The anisotropy of the g-factor indicates
a stable orbital configuration below room temperature, and allows to estimate
the energy of the first excited state as 0.3(1) eV ruling out a possible
degeneracy of the orbital ground state. Moreover, we discuss the possible spin
relaxation mechanisms in TiOCl and analyze the angular and temperature
dependence of the linewidth up to 250 K in terms of anisotropic exchange
interactions. Towards higher temperatures an exponential increase of the
linewidth is observed, indicating an additional relaxation mechanism.Comment: 10 pages, 8 figures; accepted for publication in Phys. Rev.
Field-induced level crossings in spin clusters: Thermodynamics and magneto-elastic instability
Quantum spin clusters with dominant antiferromagnetic Heisenberg exchange
interactions typically exhibit a sequence of field-induced level crossings in
the ground state as function of magnetic field. For fields near a level
crossing, the cluster can be approximated by a two-level Hamiltonian at low
temperatures. Perturbations, such as magnetic anisotropy or spin-phonon
coupling, sensitively affect the behavior at the level-crossing points. The
general two-level Hamiltonian of the spin system is derived in first-order
perturbation theory, and the thermodynamic functions magnetization, magnetic
torque, and magnetic specific heat are calculated. Then a magneto-elastic
coupling is introduced and the effective two-level Hamilitonian for the
spin-lattice system derived in the adiabatic approximation of the phonons. At
the level crossings the system becomes unconditionally unstable against lattice
distortions due to the effects of magnetic anisotropy. The resultant
magneto-elastic instabilities at the level crossings are discussed, as well as
the magnetic behavior.Comment: 13 pages, 8 figures, REVTEX
Colorimetric response to anions by a "robust" copper(II) complex of a [9]aneN3 pendant arm derivative: CN- and I- selective sensing
The 1 : 1 complex [Cu(L)](BF4)2MeCN (1) of the tetradentate ligand 1-(2-quinolinylmethyl)-1,4,7-triazacyclononane (L) selectively changes its colour in the presence of CN in H2O and MeCN (without undergoing decomplexation from the macrocyclic ligand). The same complex in MeCN assumes different colours in the presence of CN or I
Aza- and Mixed Thia/Aza-Macrocyclic Receptors with Quinoline-Bearing Pendant Arms for Optical Discrimination of Zinc(II) or Cadmium(II) Ions
The synthesis and coordination properties of two fluorescent chemosensors, featuring [9]aneN3 (1,4,7-triazacyclononane; L1) and [12]aneNS3 (1-aza-4,7,10-trithiacyclododecane; L2) as receptor units, and a quinoline pendant arm with an amide group as a functional group spacer are described. The optical responses of L1 and L2 in the presence of several metal ions were analysed in MeCN/H2O (1 : 4 v/v) solutions. A selective chelation enhancement of fluorescence (CHEF) effect was observed in the presence of Zn2+ in the case of L1, and in the presence of Cd2+ in the case of L2, following the formation of a 1 : 1 and a 1 : 2 metal/ligand complex, respectively, which was also confirmed by potentiometric measurements. 1H and 13C NMR measurements in CD3CN/CDCl3 in combination with molecular mechanics calculations show that for both complexes of L1 and L2 with Zn2+ and Cd2+, respectively, the coordination of the carbonyl group from the pendant arm could be the origin of the observed optical selectivity
Tuning the magnetic ground state of a novel tetranuclear Nickel(II) molecular complex by high magnetic fields
Electron spin resonance and magnetization data in magnetic fields up to 55 T
of a novel multicenter paramagnetic molecular complex [L_2Ni_4(N_3)(O_2C
Ada)_4](Cl O_4) are reported. In this compound, four Ni centers each having a
spin S = 1 are coupled in a single molecule via bridging ligands (including a
\mu_4-azide) which provide paths for magnetic exchange. Analysis of the
frequency and temperature dependence of the ESR signals yields the relevant
parameters of the spin Hamiltonian, in particular the single ion anisotropy gap
and the g factor, which enables the calculation of the complex energy spectrum
of the spin states in a magnetic field. The experimental results give
compelling evidence for tuning the ground state of the molecule by magnetic
field from a nonmagnetic state at small fields to a magnetic one in strong
fields owing to the spin level crossing at a field of ~25 T.Comment: revised version, accepted for publication in Physical Review
A systematic analysis of bone marrow cells by flow cytometry defines a specific phenotypic profile beyond GPI deficiency in paroxysmal nocturnal hemoglobinuria.
Automatic Quantum Error Correction
Criteria are given by which dissipative evolution can transfer populations
and coherences between quantum subspaces, without a loss of coherence. This
results in a form of quantum error correction that is implemented by the joint
evolution of a system and a cold bath. It requires no external intervention
and, in principal, no ancilla. An example of a system that protects a qubit
against spin-flip errors is proposed. It consists of three spin 1/2 magnetic
particles and three modes of a resonator. The qubit is the triple quantum
coherence of the spins, and the photons act as ancilla.Comment: 16 pages 12 fig LaTex uses multicol, graphicx expanded version of
letter submitted to Phys Rev Let
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