Revealing the Ligand Effect on Copper(I) Disproportionation via Operando IR Spectra

The ligand effect on Cu^I disproportionation is investigated through operando IR. It is found that the Cu^I complexes formed from the reaction of CuI with β-diketone enolate, β-keto ester enolate, and β-keto amide enolate could disproportionate to Cu^II and Cu⁰ species, respectively. The distinct disproportionation rates of Cu^I complexes chelated by different β-dicarbonyl ligands provide a useful insight into the nature of copper catalytic reactions, which will be helpful for designing ligands and understanding the mechanism of Cu-catalyzed coupling reactions

Bias between Index Test and Ampicor v1.5 as a comparator (data extracted from references [19], [24], [25], [29], [37], [38], [40], [41], [43], [45], [46], [48], [52], [55]). *No volume specified.

<p>Bias between Index Test and Ampicor v1.5 as a comparator (data extracted from references <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Braun1" target="_blank">[19]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Damond1" target="_blank">[24]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Do1" target="_blank">[25]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Gueudin1" target="_blank">[29]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Poveda1" target="_blank">[37]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Pyne1" target="_blank">[38]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Schutten1" target="_blank">[40]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Scott1" target="_blank">[41]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Sivapalasingam1" target="_blank">[43]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Sloma1" target="_blank">[45]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Ssebugenyi1" target="_blank">[46]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Swanson1" target="_blank">[48]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Weissman1" target="_blank">[52]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Young1" target="_blank">[55]</a>). *No volume specified.</p

Operating characteristics of Point of Care (POC) technologies for CD4+ T-cell enumeration.

<p>Operating characteristics of Point of Care (POC) technologies for CD4+ T-cell enumeration.</p

A. Bias compared to FASCount as the reference technology. B. Bias compared to FASCalibur as the reference technology.

<p>A. Bias compared to FASCount as the reference technology. B. Bias compared to FASCalibur as the reference technology.</p

Operating characteristics of dedicated single platform CD4+ T-cell enumeration systems.

<p>PCA = personal cell analysis, SSC = side scatter.</p><p>Operating characteristics of dedicated single platform CD4+ T-cell enumeration systems.</p

PRISMA flow diagram of study selection.

<p>EQA: external quality assurance, FC: flow cytometry.</p

Intra- and inter-assay variation for the Versant kPCR (plasma) according to log copy number/mL of sample (data extracted from references [39], [50]).

<p>Intra- and inter-assay variation for the Versant kPCR (plasma) according to log copy number/mL of sample (data extracted from references <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Ruelle1" target="_blank">[39]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Troppan1" target="_blank">[50]</a>).</p

Bias data between index test and WHO International Standard [50].

<p>Bias data between index test and WHO International Standard <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Troppan1" target="_blank">[50]</a>.</p

Intra- and inter-assay variation for the Abbott RealTime HIV-1(plasma) according to log copy number/mL of sample (data extracted from references [19], [20], [23], [38], [40], [45]).

<p>Intra- and inter-assay variation for the Abbott RealTime HIV-1(plasma) according to log copy number/mL of sample (data extracted from references <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Braun1" target="_blank">[19]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Choi1" target="_blank">[20]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Crump1" target="_blank">[23]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Pyne1" target="_blank">[38]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Schutten1" target="_blank">[40]</a>, <a href="http://www.plosone.org/article/info:doi/10.1371/journal.pone.0085869#pone.0085869-Sloma1" target="_blank">[45]</a>).</p

HIV VL Search Algorithm.

<p>HIV VL Search Algorithm.</p