Advanced memory effects in the aging of a polymer glass

A new kind of memory effect on low frequency dielectric measurements on plexiglass (PMMA) is described. These measurements show that cooling and heating the sample at constant rate give an hysteretic dependence on temperature of the dielectric constant $\epsilon$. A temporary stop of cooling produces a downward relaxation of $\epsilon$. Two main features are observed i) when cooling is resumed $\epsilon$ goes back to the values obtained without the cooling stop (i.e. the low temperature state is independent of the cooling history) ii) upon reheating $\epsilon$ keeps the memory of all the cooling stops({\it Advanced memory}). The dependence of this effect on frequency and on the cooling rate is analyzed. The memory deletion is studied too. Finally the results are compared with those of similar experiments done in spin glasses and with the famous experiments of Kovacs.Comment: to be published in the European Physical Journa

Electrical noise properties in aging materials

The electric thermal noise has been measured in two aging materials, a colloidal suspension (Laponite) and a polymer (polycarbonate), presenting very slow relaxation towards equilibrium. The measurements have been performed during the transition from a fluid-like to a solid-like state for the gel and after a quench for the polymer. For both materials we have observed that the electric noise is characterized by a strong intermittency, which induces a large violation of the Fluctuation Dissipation Theorem (FDT) during the aging time, and may persist for several hours at low frequency. The statistics of these intermittent signals and their dependance on the quench speed for the polymer or on sample concentration for the gel are studied. The results are in a qualitative agreement with recent models of aging, that predict an intermittent dynamics.Comment: SPIE Proceeding Journa

Coupling between aging and convective motion in a colloidal glass of Laponite

We study thermal convection in a colloidal glass of Laponite in formation. Low concentration preparation are submitted to destabilizing vertical temperature gradient, and present a gradual transition from a turbulent convective state to a steady conductive state as their viscosity increases. The time spent under convection is found to depend strongly on sample concentration, decreasing exponentially with mass fraction of colloidal particles. Moreover, at fixed concentration, it also depends slightly on the pattern selected by the Rayleigh B\'{e}nard instability: more rolls maintain the convection state longer. This behavior can be interpreted with recent theoretical approaches of soft glassy material rheology.Comment: Eur. Phys. J. B 55, 101-107 (2007) The original publication is available at http://www.springerlink.co

Thermal noise properties of two aging materials

In this lecture we review several aspects of the thermal noise properties in two aging materials: a polymer and a colloidal glass. The measurements have been performed after a quench for the polymer and during the transition from a fluid-like to a solid-like state for the gel. Two kind of noise has been measured: the electrical noise and the mechanical noise. For both materials we have observed that the electric noise is characterized by a strong intermittency, which induces a large violation of the Fluctuation Dissipation Theorem (FDT) during the aging time, and may persist for several hours at low frequency. The statistics of these intermittent signals and their dependance on the quench speed for the polymer or on sample concentration for the gel are studied. The results are in a qualitative agreement with recent models of aging, that predict an intermittent dynamics. For the mechanical noise the results are unclear. In the polymer the mechanical thermal noise is still intermittent whereas for the gel the violation of FDT, if it exists, is extremely small.Comment: to be published in the Proceedings of the XIX Sitges Conference on ''Jammming, Yielding and Irreversible Deformation in Condensed Matter'', M.-C.Miguel and M. Rubi eds.,Springer Verlag, Berli

Steady state fluctuation relations for systems driven by an external random force

We experimentally study the fluctuations of the work done by an external Gaussian random force on two different stochastic systems coupled to a thermal bath: a colloidal particle in an optical trap and an atomic force microscopy cantilever. We determine the corresponding probability density functions for different random forcing amplitudes ranging from a small fraction to several times the amplitude of the thermal noise. In both systems for sufficiently weak forcing amplitudes the work fluctuations satisfy the usual steady state fluctuation theorem. As the forcing amplitude drives the system far from equilibrium, deviations of the fluctuation theorem increase monotonically. The deviations can be recasted to a single master curve which only depends on the kind of stochastic external force.Comment: 6 pages, submitted to EP

Formes d'organisation de maraîchers organiques périurbains de São Paulo.

Le développement de l'agriculture organique au Brésil prend des formes multiples. Au travers de leur expérience de l'AO, dans une communauté proche de trois métropoles, de petits maraîchers d'Ibiúna (São Paulo) créent des entités collectives et expérimentent de nouvelles pratiques sociales. À partir d'entretiens et d'observations sur le terrain, nous montrons comment ces minifundios se sont, ou ont été, organisés pour développer l'AO dans un même territoire Nous identifions quatre formes sociales d'organisation, leurs dynamiques, leurs valeurs et leurs inter-relations. Nous discutons des éléments susceptibles de sécuriser leur reproduction sociale et de soutenir de nouvelles voies de développement

Off equilibrium fluctuations in a polymer glass

The fluctuation-dissipation relation (FDR) is measured on the dielectric properties a polymer glass (polycarbonate). It is observed that the fluctuation dissipation theorem is strongly violated for a quench from above to below the glass transition temperature. The amplitude and the persistence time of this violation are decreasing functions of frequency. Around $1Hz$ it may persist for several hours. The origin of this violation is a highly intermittent dynamics characterized by large fluctuations a strongly non-Gaussian statistics. The intermittent dynamics depends on the quenching rate and it disappears after slow quenches. The relevance of these results for recent models of aging are discussed.Comment: submitted to Physica

A dinâmica do desenvolvimento da agroecologia no Brasil e na América Latina.

Resumo: A agroecologia é fonte de inspiração para a construção de sistemas agroalimentares ecológicos, a partir de 2003, foi fortalecida através de políticas públicas. O objetivo do artigo é o de apresentar as características, os elementos históricos determinantes da dinâmica de desenvolvimento da agroecologia no Brasil e em alguns países da América Latina, bem como suas diferentes facetas e o estado atual de sua estruturação. A metodologia utilizada é fruto de uma revisão bibliográfica, análise compreensiva de natureza sociológica e agronômica de um conjunto de estudos de casos. A agroecologia é atualmente legitimada pelo movimento social, redes científicas e técnicas, num cenário de tensão permanente e, de coexistência com a agricultura denominada de convencional ou produtivista