7 research outputs found
Geometric/microstructural imperfection sensitivity in the vibration characteristics of geometrically non-uniform functionally graded plates with mixed boundary conditions
Photoredox-Induced Three-Component Oxy-, Amino-, and Carbotrifluoromethylation of Enecarbamates
Synthesis, Characterization, Free-radical Scavenging Capacity and Antioxidant Activity of Novel Series of Hydrazone, 1,3,4-oxadiazole and 1,2,4- triazole Derived from 3,5-dimethyl-1H-pyrazole
2.5 Radical–Polar Crossover Reactions
International audienceAbstract Radical–polar crossover reactions, that is, single-electron redox events allowing for the interconversion between radical and ionic intermediates, make it possible to connect radical and polar processes in the same synthetic transformation. Such a combination is the basis of much original synthetic methodology, which is particularly useful in the context of domino, tandem, or multicomponent reactions. This chapter comprehensively covers the field of radical–polar crossover reactions, with a primary emphasis on transformations wherein both the radical and polar processes provide synthetic elaboration