Theoretical Description of Pulsed RYDMR: Refocusing Zero-Quantum and Single Quantum Coherences

A theoretical description of pulsed reaction yield detected magnetic resonance (RYDMR) is proposed. In RYDMR, magnetic resonance spectra of radical pairs (RPs) are indirectly detected by monitoring their recombination yield. Such a detection method is significantly more sensitive than conventional electron paramagnetic resonance (EPR), but design of appropriate pulse sequences for RYDMR requires additional effort because of a different observable. In this work various schemes for generating spin-echo like signals and detecting them by RYDMR are treated. Specifically, we consider refocusing of zero-quantum coherences (ZQCs) and single-quantum coherences (SQCs) by selective as well as by non-selective pulses and formulate a general analytical approach to pulsed RYDMR, which makes an efficient use of the product operator formalism. We anticipate that these results are of importance for RYDMR studies of elusive paramagnetic particles, notably, in organic semiconductors

Higher triplet state of fullerene C70 revealed by electron spin relaxation

Spin-lattice relaxation timesT1 of photoexcited triplets 3C70 in glassy decalin were obtained from electron spin echo inversion recovery dependences. In the range 30–100 K, the temperature dependence of T1 was fitted by the Arrhenius law with an activation energy of 172 cm−1. This indicates that the dominant relaxation process of 3C70 is described by an Orbach-Aminov mechanism involving the higher triplet state t2 which lies 172 cm−1 above the lowest triplet state t1. Chemical modification of C70fullerene not only decreases the intrinsic triplet lifetime by about ten times but also increases T1 by several orders of magnitude. The reason for this is the presence of a low-lying excited triplet state in 3C70 and its absence in triplet C70 derivatives. The presence of the higher triplet state in C70 is in good agreement with the previous results from phosphorescence spectroscopy

Physical Vacuum Properties and Internal Space Dimension

The paper addresses matrix spaces, whose properties and dynamics are determined by Dirac matrices in Riemannian spaces of different dimension and signature. Among all Dirac matrix systems there are such ones, which nontrivial scalar, vector or other tensors cannot be made up from. These Dirac matrix systems are associated with the vacuum state of the matrix space. The simplest vacuum system realization can be ensured using the orthonormal basis in the internal matrix space. This vacuum system realization is not however unique. The case of 7-dimensional Riemannian space of signature 7(-) is considered in detail. In this case two basically different vacuum system realizations are possible: (1) with using the orthonormal basis; (2) with using the oblique-angled basis, whose base vectors coincide with the simple roots of algebra E_{8}. Considerations are presented, from which it follows that the least-dimension space bearing on physics is the Riemannian 11-dimensional space of signature 1(-)& 10(+). The considerations consist in the condition of maximum vacuum energy density and vacuum fluctuation energy density.Comment: 19 pages, 1figure. Submitted to General Relativity and Gravitatio

Environmentally Friendly Improvement of Plasmonic Nanostructure Functionality towards Magnetic Resonance Applications

Plasmonic nanostructures have attracted a broad research interest due to their application perspectives in various fields such as biosensing, catalysis, photovoltaics, and biomedicine. Their synthesis by pulsed laser ablation in pure water enables eliminating various side effects originating from chemical contamination. Another advantage of pulsed laser ablation in liquids (PLAL) is the possibility to controllably produce plasmonic nanoparticles (NPs) in combination with other plasmonic or magnetic materials, thus enhancing their functionality. However, the PLAL technique is still challenging in respect of merging metallic and semiconductor specific features in nanosized objects that could significantly broaden application areas of plasmonic nanostructures. In this work, we performed synthesis of hybrid AuSi NPs with novel modalities by ultrashort laser ablation of bulk gold in water containing silicon NPs. The Au/Si atomic ratio in the nanohybrids was finely varied from 0.5 to 3.5 when changing the initial Si NPs concentration in water from 70 µg/mL to 10 µg/mL, respectively, without requiring any complex chemical procedures. It has been found that the laser-fluence-insensitive silicon content depends on the mass of nanohybrids. A high concentration of paramagnetic defects (2.2·× 1018 spin/g) in polycrystalline plasmonic NPs has been achieved. Our findings can open further prospects for plasmonic nanostructures as contrast agents in optical and magnetic resonance imaging techniques, biosensing, and cancer theranostics

Rare processes and coherent phenomena in crystals

We study coherent enhancement of Coulomb excitation of high energy particles in crystals. We develop multiple scattering theory description of coherent excitation which consistently incorporates both the specific resonant properties of particle-crystal interactions and the final/initial state interaction effects typical of the diffractive scattering. Possible applications to observation of induced radiative neutrino transitions are discussed.Comment: 8 pages, LaTe

Lowering the Barriers to Medication Treatment for People with Opioid Use Disorder: Evidence for a Low-Threshold Approach

Overdose deaths have reached unprecedented levels in the U.S., despite effective medications to treat opioid use disorders (OUDs). Because the regulatory and administrative barriers to treatment are high, only about 11% of people with OUD receive effective medications, which include buprenorphine, methadone, and naltrexone. In response, clinicians and advocates have looked to a “low-threshold” approach that reduces the stigma surrounding effective medications and facilitates their use. This brief summarizes the barriers to treatment, the evidence on the low-threshold approach, and areas for future research. The evidence suggests that low-threshold approaches can increase access to treatment, with outcomes comparable to high-barrier, standard care. Policymakers, providers, and payers should lower the barriers to medication treatment through regulatory flexibility (including telehealth prescribing), and harm reduction strategies that de-emphasize abstinence and place a priority on initiating or re-initiating treatment whenever and wherever individuals are ready to do so

A nitroxide-containing cathode material for organic radical batteries studied with pulsed EPR spectroscopy

An electron spin echo in a nitroxide-containing polymer cathode film for organic radical batteries is observed for various states of charge at cryogenic temperatures. The EPR-detected state of charge (ESOC), as inferred from the number of paramagnetic centers in the film, is compared to the results of Coulomb counting based on galvanostatic charging. Spin concentration, longitudinal relaxation times T(1 )and phase memory times T-m strongly correlate with the ESOC. In the discharged film, the spin concentration reaches 5 +/- 3x10(20) cm(-3), causing a phase memory time T-m << 100 ns (shorter than the resonator ring-down time) that hinders the detection of the spin echo. In the charged film, the decreased spin concentration results in a longer T-m between 100 ns and 300 ns that enables spin-echo detection, yet limits the length of the microwave pulse sequence. The short, broad-band pulses cause instantaneous diffusion in the unoxidized domains across the oxidized film, affecting the relative peak intensities in the pulsed EPR spectrum. By simulating the spectral distortion caused by instantaneous diffusion, we obtain information on the local spin concentration, which complements the information on the 'bulk' spin concentration determined by electrochemistry and continuous-wave EPR spectroscopy

Elucidating the structural composition of a Fe-N-C catalyst by nuclear and electron resonance techniques

Fe–N–C catalysts are very promising materials for fuel cells and metal–air batteries. This work gives fundamental insights into the structural composition of an Fe–N–C catalyst and highlights the importance of an in‐depth characterization. By nuclear‐ and electron‐resonance techniques, we are able to show that even after mild pyrolysis and acid leaching, the catalyst contains considerable fractions of α‐iron and, surprisingly, iron oxide. Our work makes it questionable to what extent FeN4 sites can be present in Fe–N–C catalysts prepared by pyrolysis at 900 °C and above. The simulation of the iron partial density of phonon states enables the identification of three FeN4 species in our catalyst, one of them comprising a sixfold coordination with end‐on bonded oxygen as one of the axial ligands