261 research outputs found
Diluted II-VI Oxide Semiconductors with Multiple Band Gaps
We report the realization of a new multi-band-gap semiconductor. The highly
mismatched alloy Zn1-yMnyOxTe1-x has been synthesized using the combination of
oxygen ion implantation and pulsed laser melting. Incorporation of small
quantities of isovalent oxygen leads to the formation of a narrow,
oxygen-derived band of extended states located within the band gap of the
Zn1-yMnyTe host. When only 1.3% of Te atoms is replaced with oxygen in a
Zn0.88Mn0.12Te crystal (with band gap of 2.32 eV) the resulting band structure
consists of two direct band gaps with interband transitions at ~1.77 eV and 2.7
eV. This remarkable modification of the band structure is well described by the
band anticrossing model in which the interactions between the oxygen-derived
band and the conduction band are considered. With multiple band gaps that fall
within the solar energy spectrum, Zn1-yMnyOxTe1-x is a material perfectly
satisfying the conditions for single-junction photovoltaics with the potential
for power conversion efficiencies surpassing 50%.Comment: 12 pages, 4 figure
Recommended from our members
Giant negative piezoresistance effect in copper-doped germanium
We have observed a stress-induced decrease of over ten orders of magnitude in the low-temperature electrical resistivity of copper- doped germanium single crystals. The application of large uniaxial stresses in a direction leas to a change in the copper ground- state wavefunction from the highly localized (1s){sup 3} to the much more extended (1s){sup 2}(2s){sup 1} configuration. We attribute the decrease in the resistivity to impurity band conduction by the 2s - holes of the high pressure configuration
Mutual passivation of group IV donors and nitrogen in diluted GaNâAsâËâ alloys
We demonstrate the mutual passivation phenomenon of Ge donors and isovalent N in highly mismatched alloy GaNâAsâËâdoped with Ge. Layers of this alloy were formed by the sequential implantation of Ge and N ions followed by pulsed laser melting and rapid thermal annealing. The mutual passivation effect results in the electrical deactivation of GeGa donors (Ge on Ga sites) and suppression of the NAs (N on As sites) induced band gap narrowing through the formation of GeGaâNAs nearest neighbor pairs. These results in combination with the analogous effect observed in Si-doped GaNâAsâËâ provide clear evidence of the general nature of the mutual passivation phenomenon in highly mismatched semiconductor alloys.This work was supported by the Director, Office of Science,
Office of Basic Energy Sciences, Division of Materials
Sciences and Engineering, U.S. Department of Energy, under
Contract No. DE-AC03-76SF00098. One of the authors
~M.A.S.! acknowledges support by an NSF graduate research
fellowship
Development of a Li2MoO4 scintillating bolometer for low background physics
We present the performance of a 33 g Li2MoO4 crystal working as a
scintillating bolometer. The crystal was tested for more than 400 h in a
dilution refrigerator installed in the underground laboratory of Laboratori
Nazionali del Gran Sasso (Italy). This compound shows promising features in the
frame of neutron detection, dark matter search (solar axions) and neutrinoless
double-beta decay physics. Low temperature scintillating properties were
investigated by means of different alpha, beta/gamma and neutron sources, and
for the first time the Light Yield for different types of interacting particle
is estimated. The detector shows great ability of tagging fast neutron
interactions and high intrinsic radiopurity levels (< 90 \muBq/kg for 238-U and
< 110 \muBq/kg for 232-Th).Comment: revised versio
First bolometric measurement of the two neutrino double beta decay of Mo with a ZnMoO crystals array
The large statistics collected during the operation of a ZnMoO array, for
a total exposure of 1.3 kg day of Mo, allowed the first
bolometric observation of the two neutrino double beta decay of Mo. The
observed spectrum of each crystal was reconstructed taking into account the
different background contributions due to environmental radioactivity and
internal contamination. The analysis of coincidences between the crystals
allowed the assignment of constraints to the intensity of the different
background sources, resulting in a reconstruction of the measured spectrum down
to an energy of 300 keV. The half-life extracted from the data is
T= [7.15 0.37 (stat) 0.66 (syst)] 10
y.Comment: 6 pages, 2 figure, Accepted for publication in Journal of Physics G:
Nuclear and Particle Physic
Metric tensor as the dynamical variable for variable cell-shape molecular dynamics
We propose a new variable cell-shape molecular dynamics algorithm where the
dynamical variables associated with the cell are the six independent dot
products between the vectors defining the cell instead of the nine cartesian
components of those vectors. Our choice of the metric tensor as the dynamical
variable automatically eliminates the cell orientation from the dynamics.
Furthermore, choosing for the cell kinetic energy a simple scalar that is
quadratic in the time derivatives of the metric tensor, makes the dynamics
invariant with respect to the choice of the simulation cell edges. Choosing the
densitary character of that scalar allows us to have a dynamics that obeys the
virial theorem. We derive the equations of motion for the two conditions of
constant external pressure and constant thermodynamic tension. We also show
that using the metric as variable is convenient for structural optimization
under those two conditions. We use simulations for Ar with Lennard-Jones
parameters and for Si with forces and stresses calculated from first-principles
of density functional theory to illustrate the applications of the method.Comment: 10 pages + 6 figures, Latex, to be published in Physical Review
Mn L3,2 X-ray Absorption Spectroscopy And Magnetic Circular Dichroism In Ferromagnetic (Ga,Mn)P
We have measured the X-ray absorption (XAS) and X-ray magnetic circular
dichroism (XMCD) at the Mn L3,2 edges in ferromagnetic Ga1-xMnxP films for
0.018<x<0.042. Large XMCD asymmetries at the L3 edge indicate significant
spin-polarization of the density of states at the Fermi energy. The spectral
shapes of the XAS and XMCD are nearly identical with those for Ga1-xMnxAs
indicating that the hybridization of Mn d states and anion p states is similar
in the two materials. Finally, compensation with sulfur donors not only lowers
the ferromagnetic Curie temperature but also reduces the spin polarization of
the hole states.Comment: 2 pages, 1 figure; To appear in the Proceedings of the 28th
International Conference on the Physics of Semiconductors (ICPS-28, Vienna,
Austria, July 24-28, 2006
Metal-insulator transition by isovalent anion substitution in Ga1-xMnxAs: Implications to ferromagnetism
We have investigated the effect of partial isovalent anion substitution in Ga1-xMnxAs on electrical transport and ferromagnetism. Substitution of only 2.4percent of As by P induces a metal-insulator transition at a constant Mn doping of x=0.046 while the replacement of 0.4 percent As with N results in the crossover from metal to insulator for x=0.037. This remarkable behavior is consistent with a scenario in which holes located within an impurity band are scattered by alloy disorder in the anion sublattice. The shorter mean free path of holes, which mediate ferromagnetism, reduces the Curie temperature TC from 113 K to 60 K (100 K to 65 K) upon the introduction of 3.1 percent P (1percent N) into the As sublattice
Compensation-dependent in-plane magnetization reversal processes in Ga1-xMnxP1-ySy
We report the effect of dilute alloying of the anion sublattice with S on the
in-plane uniaxial magnetic anisotropy and magnetization reversal process in
Ga1-xMnxP as measured by both ferromagnetic resonance (FMR) and superconducting
quantum interference device (SQUID) magnetometry. At T=5K, raising the S
concentration increases the uniaxial magnetic anisotropy between in-plane
directions while decreasing the magnitude of the (negative) cubic anisotropy
field. Simulation of the SQUID magnetometry indicates that the energy required
for the nucleation and growth of domain walls decreases with increasing y.
These combined effects have a marked influence on the shape of the
field-dependent magnetization curves; while the direction remains the easy axis
in the plane of the film, the field dependence of the magnetization develops
double hysteresis loops in the [011] direction as the S concentration increases
similar to those observed for perpendicular magnetization reversal in lightly
doped Ga1-xMnxAs. The incidence of double hysteresis loops is explained with a
simple model whereby magnetization reversal occurs by a combination of coherent
spin rotation and noncoherent spin switching, which is consistent with both FMR
and magnetometry experiments. The evolution of magnetic properties with S
concentration is attributed to compensation of Mn acceptors by S donors, which
results in a lowering of the concentration of holes that mediate
ferromagnetism.Comment: 37 pages, 9 figures, 3 table
- âŠ