1,738 research outputs found
Ferreting out the Fluffy Bunnies: Entanglement constrained by Generalized superselection rules
Entanglement is a resource central to quantum information (QI). In
particular, entanglement shared between two distant parties allows them to do
certain tasks that would otherwise be impossible. In this context, we study the
effect on the available entanglement of physical restrictions on the local
operations that can be performed by the two parties. We enforce these physical
restrictions by generalized superselection rules (SSRs), which we define to be
associated with a given group of physical transformations. Specifically the
generalized SSR is that the local operations must be covariant with respect to
that group. Then we operationally define the entanglement constrained by a SSR,
and show that it may be far below that expected on the basis of a naive (or
``fluffy bunny'') calculation. We consider two examples. The first is a
particle number SSR. Using this we show that for a two-mode BEC (with Alice
owning mode and Bob mode ), the useful entanglement shared by Alice and
Bob is identically zero. The second, a SSR associated with the symmetric group,
is applicable to ensemble QI processing such as in liquid-NMR. We prove that
even for an ensemble comprising many pairs of qubits, with each pair described
by a pure Bell state, the entanglement per pair constrained by this SSR goes to
zero for a large ensemble.Comment: 8 pages, proceedings paper for an invited talk at 16th International
Conference on Laser Spectroscopy (2003
Dynamic structure elucidation of chemical reactivity by laser pulses and X-ray probes
Visualising chemical reactions by X-ray methods is a tantalising prospect. New light sources provide the prospect for studying atomic, electronic and energy transfers accompanying chemical change by X-ray spectroscopy and inelastic scattering. Here we assess how this adventure can illuminate inorganic and catalytic chemistry. In particular X-ray inelastic scattering provides a means of exploiting X-ray free electron lasers, as a parallel to laser Raman spectroscopy
Letter. On the activation of [CrCl3{R-SN(H)S-R}] catalysts for selective trimerization of ethene: a freeze-quench Cr K-edge XAFS study
Homogeneous chromium catalysts for the selective conversion of ethene to hex-1-ene are formed from Cr(III) reagents, amino-thioether ligands of the type HN(CH2CH2SR)2, and aluminum reagents. In this study the early activation steps are investigated by EPR, UV-visible and Cr K-edge XAFS spectroscopy; rapid stopped-flow mixing and a freeze-quench allows good quality EXAFS analysis of a species formed in ~ 1 second of reaction. This is shown to involve reduction to Cr(II) and deprotonation of a NH group of the auxiliary ligand. This 4-coordinate metal-center may act as precursor for the coordination of ethene and subsequent selective oligomerization
AN EVALUATION OF THE PRIA GRAZING FEE FORMULA
The federal grazing fee is currently set using the Public Rangeland Improvement Act (PRIA) fee formula established in 1978 and modified in 1986. The formula is adjusted annually using indices of private land grazing lease rates (Forage Value Index, FVI), prices received for beef cattle (Beef Cattle Price Index, BCPI), and costs of beef production (Prices Paid Index, PPI). The FVI tracks price movement in the private forage market and was the only index originally proposed to be included in the fee formula. Public land ranchers and an Interdepartmental Grazing Fee Technical Committee assigned to study grazing fee alternatives in the 1960s questioned the ability of the FVI to account for short-term demand, supply, and price equilibrium, and, for this reason, the BCPI and PPI were added to the fee formula. Over 30 years of data are now available to evaluate whether adding the BCPI and PPI did, in fact, help explain short-term market fluctuations. This analysis shows, as earlier studies did, that, if tracking the private forage market is the primary objective, then the fee formula should have included only the FVI. Including the BCPI and, especially, the PPI has caused calculated grazing fees to fall further and further behind private land lease rates. Had the 3.84/AUM instead of $1.35/AUM in 2000. It is time to consider the feasibility of a competitive bid system for public lands, or, at the very least, adopt a new fee formula that generates more equitable grazing fees.Land Economics/Use,
Predictive coupled-cluster isomer orderings for some SiC () clusters; A pragmatic comparison between DFT and complete basis limit coupled-cluster benchmarks
The accurate determination of the preferred
isomer is important to guide experimental efforts directed towards synthesizing
SiC nano-wires and related polymer structures which are anticipated to be
highly efficient exciton materials for opto-electronic devices. In order to
definitively identify preferred isomeric structures for silicon carbon
nano-clusters, highly accurate geometries, energies and harmonic zero point
energies have been computed using coupled-cluster theory with systematic
extrapolation to the complete basis limit for set of silicon carbon clusters
ranging in size from SiC to . It is found that
post-MBPT(2) correlation energy plays a significant role in obtaining converged
relative isomer energies, suggesting that predictions using low rung density
functional methods will not have adequate accuracy. Utilizing the best
composite coupled-cluster energy that is still computationally feasible,
entailing a 3-4 SCF and CCSD extrapolation with triple- (T) correlation,
the {\it closo} isomer is identified to be the
preferred isomer in support of previous calculations [J. Chem. Phys. 2015, 142,
034303]. Additionally we have investigated more pragmatic approaches to
obtaining accurate silicon carbide isomer energies, including the use of frozen
natural orbital coupled-cluster theory and several rungs of standard and
double-hybrid density functional theory. Frozen natural orbitals as a way to
compute post MBPT(2) correlation energy is found to be an excellent balance
between efficiency and accuracy
The Solar Neighborhood XIII: Parallax Results from the CTIOPI 0.9-m Program -- Stars with mu >= 1"/year (MOTION Sample)
We present the first set of definitive trigonometric parallaxes and proper
motions from the Cerro Tololo Inter-American Observatory Parallax Investigation
(CTIOPI). Full astrometric reductions for the program are discussed, including
methods of reference stars selection, differential color refraction
corrections, and conversion of relative to absolute parallax. Using data
acquired at the 0.9-m at CTIO, full astrometric solutions and
photometry are presented for 36 red and white dwarf stellar systems with proper
motions faster than 1\farcs0/yr. Of these, thirty three systems have the first
ever trigonometric parallaxes, which comprise 41% of MOTION systems (those with
proper motions greater than 1\farcs0/yr) south of 0 that have no
parallaxes. Four of the systems are new members of the RECONS 10 pc sample for
which the first accurate trigonometric parallaxes are published here: DENIS
J1048-3956 (4.04 0.03 pc), GJ 1128 (LHS 271, 6.53 0.10 pc), GJ 1068
(LHS 22, 6.97 0.09 pc), and GJ 1123 (LHS 263, 9.02 0.16 pc). In
addition, two red subdwarf-white dwarf pairs, LHS 193AB and LHS 300AB, are
identified. The white dwarf secondaries fall in a previously uncharted region
of the HR diagram.Comment: 40 pages, 7 figures, accepted to The Astronomical Journal (scheduled
for April 2005 issue), Re-submit, Table 2 running off the bottom of the page
has been fixe
High-throughput Agrobacterium-mediated barley transformation
<p>Abstract</p> <p>Background</p> <p>Plant transformation is an invaluable tool for basic plant research, as well as a useful technique for the direct improvement of commercial crops. Barley (<it>Hordeum vulgare</it>) is the fourth most abundant cereal crop in the world. It also provides a useful model for the study of wheat, which has a larger and more complex genome. Most existing barley transformation methodologies are either complex or have low (<10%) transformation efficiencies.</p> <p>Results</p> <p>A robust, simple and reproducible barley transformation protocol has been developed that yields average transformation efficiencies of 25%. This protocol is based on the infection of immature barley embryos with <it>Agrobacterium </it>strain AGL1, carrying vectors from the pBract series that contain the <it>hpt </it>gene (conferring hygromycin resistance) as a selectable marker. Results of large scale experiments utilising the <it>luc </it>(firefly luciferase) gene as a reporter are described. The method presented here has been used to produce hundreds of independent, transgenic plant lines and we show that a large proportion of these lines contain single copies of the <it>luc </it>gene.</p> <p>Conclusion</p> <p>This protocol demonstrates significant improvements in both efficiency and ease of use over existing barley transformation methods. This opens up opportunities for the development of functional genomics resources in barley.</p
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