287 research outputs found
Three-Dimensional Elastic Compatibility: Twinning in Martensites
We show how the St.Venant compatibility relations for strain in three
dimensions lead to twinning for the cubic to tetragonal transition in
martensitic materials within a Ginzburg-Landau model in terms of the six
components of the symmetric strain tensor. The compatibility constraints
generate an anisotropic long-range interaction in the order parameter
(deviatoric strain) components. In contrast to two dimensions, the free energy
is characterized by a "landscape" of competing metastable states. We find a
variety of textures, which result from the elastic frustration due to the
effects of compatibility. Our results are also applicable to structural phase
transitions in improper ferroelastics such as ferroelectrics and
magnetoelastics, where strain acts as a secondary order parameter
Trapped ion mobility spectrometry and PASEF enable in-depth lipidomics from minimal sample amounts
A comprehensive characterization of the lipidome from limited starting material remains very challenging. Here we report a high-sensitivity lipidomics workflow based on nanoflow liquid chromatography and trapped ion mobility spectrometry (TIMS). Taking advantage of parallel accumulation-serial fragmentation (PASEF), we fragment on average 15 precursors in each of 100 ms TIMS scans, while maintaining the full mobility resolution of co-eluting isomers. The acquisition speed of over 100 Hz allows us to obtain MS/MS spectra of the vast majority of isotope patterns. Analyzing 1 mu L of human plasma, PASEF increases the number of identified lipids more than three times over standard TIMS-MS/MS, achieving attomole sensitivity. Building on high intra- and inter-laboratory precision and accuracy of TIMS collisional cross sections (CCS), we compile 1856 lipid CCS values from plasma, liver and cancer cells. Our study establishes PASEF in lipid analysis and paves the way for sensitive, ion mobility-enhanced lipidomics in four dimensions
Droplet Fluctuations in the Morphology and Kinetics of Martensites
We derive a coarse grained, free-energy functional which describes droplet
configurations arising on nucleation of a product crystal within a parent. This
involves a new `slow' vacancy mode that lives at the parent-product interface.
A mode-coupling theory suggests that a {\it slow} quench from the parent phase
produces an equilibrium product, while a {\it fast} quench produces a
metastable martensite. In two dimensions, the martensite nuclei grow as
`lens-shaped' strips having alternating twin domains, with well-defined front
velocities. Several empirically known structural and kinetic relations drop out
naturally from our theory.Comment: 4 pages, REVTEX, and 3 .eps figures, compressed and uuencoded,
Submitted to Phys. Rev. Let
Antiferromagnetic domain walls in lightly doped layered cuprates
Recent ESR data shows rotation of the antiferromagnetic (AF) easy axis in
lightly doped layered cuprates upon lowering the temperature. We account for
the ESR data and show that it has significant implications on spin and charge
ordering according to the following scenario: In the high temperature phase AF
domain walls coincide with (110) twin boundaries of an orthorhombic phase. A
magnetic field leads to annihilation of neighboring domain walls resulting in
antiphase boundaries. The latter are spin carriers, form ferromagnetic lines
and may become charged in the doped system. However, hole ordering at low
temperatures favors the (100) orientation, inducing a pi/4 rotation in the AF
easy axis. The latter phase has twin boundaries and AF domain walls in (100)
planes.Comment: 4 pages, 3 figures (1 eps). v2: no change in content, Tex shadow
problem cleare
Catastrophic Fermi surface reconstruction in the shape-memory alloy AuZn
AuZn undergoes a shape-memory transition at 67 K. The de Haas van Alphen
effect persists to 100 K enabling the observation of a change in the quantum
oscillation spectrum indicative of a catastrophic Fermi surface reconstruction
at the transition. Coexistence of both Fermi surfaces at low temperatures is
suggestive of an intrinsic phase separation in the bulk of the material. In
addition, a Dingle analysis reveals a sharp change in the scattering mechanism
at a threshold cyclotron radius, which we suggest to be related to the
underlying microstructure that drives the shape-memory effect.Comment: 4 pages, 4 figure
Twin wall of cubic-tetragonal ferroelastics
We derive solutions for the twin wall linking two tetragonal variants of the
cubic-tetragonal ferroelastic transformation, including for the first time the
dilatational and shear energies and strains. Our solutions satisfy the
compatibility relations exactly and are obtained at all temperatures. They
require four non-vanishing strains except at the Barsch-Krumhansl temperature
TBK (where only the two deviatoric strains are needed). Between the critical
temperature and TBK, material in the wall region is dilated, while below TBK it
is compressed. In agreement with experiment and more general theory, the twin
wall lies in a cubic 110-type plane. We obtain the wall energy numerically as a
function of temperature and we derive a simple estimate which agrees well with
these values.Comment: 4 pages (revtex), 3 figure
Fermi Surface as a Driver for the Shape-Memory Effect in AuZn
Martensites are materials that undergo diffusionless, solid-state
transitions. The martensitic transition yields properties that depend on the
history of the material and may allow it to recover its previous shape after
plastic deformation. This is known as the shape-memory effect (SME). We have
succeeded in identifying the primary electronic mechanism responsible for the
martensitic transition in the shape-memory alloy AuZn by using Fermi-surface
measurements (de Haas-van Alphen oscillations) and band-structure calculations.
This strongly suggests that electronic band structure is an important
consideration in the design of future SME alloys
Intermediate states at structural phase transition: Model with a one-component order parameter coupled to strains
We study a Ginzburg-Landau model of structural phase transition in two
dimensions, in which a single order parameter is coupled to the tetragonal and
dilational strains. Such elastic coupling terms in the free energy much affect
the phase transition behavior particularly near the tricriticality. A
characteristic feature is appearance of intermediate states, where the ordered
and disordered regions coexist on mesoscopic scales in nearly steady states in
a temperature window. The window width increases with increasing the strength
of the dilational coupling. It arises from freezing of phase ordering in
inhomogeneous strains. No impurity mechanism is involved. We present a simple
theory of the intermediate states to produce phase diagrams consistent with
simulation results.Comment: 16 pages, 14 figure
Disorder-Driven Pretransitional Tweed in Martensitic Transformations
Defying the conventional wisdom regarding first--order transitions, {\it
solid--solid displacive transformations} are often accompanied by pronounced
pretransitional phenomena. Generally, these phenomena are indicative of some
mesoscopic lattice deformation that ``anticipates'' the upcoming phase
transition. Among these precursive effects is the observation of the so-called
``tweed'' pattern in transmission electron microscopy in a wide variety of
materials. We have investigated the tweed deformation in a two dimensional
model system, and found that it arises because the compositional disorder
intrinsic to any alloy conspires with the natural geometric constraints of the
lattice to produce a frustrated, glassy phase. The predicted phase diagram and
glassy behavior have been verified by numerical simulations, and diffraction
patterns of simulated systems are found to compare well with experimental data.
Analytically comparing to alternative models of strain-disorder coupling, we
show that the present model best accounts for experimental observations.Comment: 43 pages in TeX, plus figures. Most figures supplied separately in
uuencoded format. Three other figures available via anonymous ftp
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