Ensemble Inequivalence in Mean-field Models of Magnetism

Mean-field models, while they can be cast into an {\it extensive} thermodynamic formalism, are inherently {\it non additive}. This is the basic feature which leads to {\it ensemble inequivalence} in these models. In this paper we study the global phase diagram of the infinite range Blume-Emery-Griffiths model both in the {\it canonical} and in the {\it microcanonical} ensembles. The microcanonical solution is obtained both by direct state counting and by the application of large deviation theory. The canonical phase diagram has first order and continuous transition lines separated by a tricritical point. We find that below the tricritical point, when the canonical transition is first order, the phase diagrams of the two ensembles disagree. In this region the microcanonical ensemble exhibits energy ranges with negative specific heat and temperature jumps at transition energies. These two features are discussed in a general context and the appropriate Maxwell constructions are introduced. Some preliminary extensions of these results to weakly decaying nonintegrable interactions are presented.Comment: Chapter of the forthcoming "Lecture Notes in Physics" volume: ``Dynamics and Thermodynamics of Systems with Long Range Interactions'', T. Dauxois, S. Ruffo, E. Arimondo, M. Wilkens Eds., Lecture Notes in Physics Vol. 602, Springer (2002). (see http://link.springer.de/series/lnpp/

Equilibrium and nonequilibrium properties of systems with long-range interactions

We briefly review some equilibrium and nonequilibrium properties of systems with long-range interactions. Such systems, which are characterized by a potential that weakly decays at large distances, have striking properties at equilibrium, like negative specific heat in the microcanonical ensemble, temperature jumps at first order phase transitions, broken ergodicity. Here, we mainly restrict our analysis to mean-field models, where particles globally interact with the same strength. We show that relaxation to equilibrium proceeds through quasi-stationary states whose duration increases with system size. We propose a theoretical explanation, based on Lynden-Bell's entropy, of this intriguing relaxation process. This allows to address problems related to nonequilibrium using an extension of standard equilibrium statistical mechanics. We discuss in some detail the example of the dynamics of the free electron laser, where the existence and features of quasi-stationary states is likely to be tested experimentally in the future. We conclude with some perspectives to study open problems and to find applications of these ideas to dipolar media.Comment: 8 pages, 14 figures, Procs. of STATPHYS23, to be published on EPJ

Large deviation techniques applied to systems with long-range interactions

We discuss a method to solve models with long-range interactions in the microcanonical and canonical ensemble. The method closely follows the one introduced by Ellis, Physica D 133, 106 (1999), which uses large deviation techniques. We show how it can be adapted to obtain the solution of a large class of simple models, which can show ensemble inequivalence. The model Hamiltonian can have both discrete (Ising, Potts) and continuous (HMF, Free Electron Laser) state variables. This latter extension gives access to the comparison with dynamics and to the study of non-equilibri um effects. We treat both infinite range and slowly decreasing interactions and, in particular, we present the solution of the alpha-Ising model in one-dimension with $0\leq\alpha<1$

Ensemble Inequivalence in the Spherical Spin Glass Model with Nonlinear Interactions

We investigate the ensemble inequivalence of the spherical spin glass model with nonlinear interactions of polynomial order $p$. This model is solved exactly for arbitrary $p$ and is shown to have first-order phase transitions between the paramagnetic and spin glass or ferromagnetic phases for $p \geq 5$. In the parameter region around the first-order transitions, the solutions give different results depending on the ensemble used for the analysis. In particular, we observe that the microcanonical specific heat can be negative and the phase may not be uniquely determined by the temperature.Comment: 15 pages, 10 figure

First and second order clustering transitions for a system with infinite-range attractive interaction

We consider a Hamiltonian system made of $N$ classical particles moving in two dimensions, coupled via an {\it infinite-range interaction} gauged by a parameter $A$. This system shows a low energy phase with most of the particles trapped in a unique cluster. At higher energy it exhibits a transition towards a homogenous phase. For sufficiently strong coupling $A$ an intermediate phase characterized by two clusters appears. Depending on the value of $A$ the observed transitions can be either second or first order in the canonical ensemble. In the latter case microcanonical results differ dramatically from canonical ones. However, a canonical analysis, extended to metastable and unstable states, is able to describe the microcanonical equilibrium phase. In particular, a microcanonical negative specific heat regime is observed in the proximity of the transition whenever it is canonically discontinuous. In this regime, {\it microcanonically stable} states are shown to correspond to {\it saddles} of the Helmholtz free energy, located inside the spinodal region.Comment: 4 pages, Latex - 3 EPS Figs - Submitted to Phys. Rev.

Inequivalence of ensembles in a system with long range interactions

We study the global phase diagram of the infinite range Blume-Emery-Griffiths model both in the canonical and in the microcanonical ensembles. The canonical phase diagram is known to exhibit first order and continuous transition lines separated by a tricritical point. We find that below the tricritical point, when the canonical transition is first order, the phase diagrams of the two ensembles disagree. In this region the microcanonical ensemble exhibits energy ranges with negative specific heat and temperature jumps at transition energies. These results can be extended to weakly decaying nonintegrable interactions.Comment: Revtex, 4 pages with 3 figures, submitted to Phys. Rev. Lett., e-mail [email protected]