4,517 research outputs found
Multi-step exploitation of raw arundo donax L. For the selective synthesis of second-generation sugars by chemical and biological route
Lignocellulosic biomass represents one of the most important feedstocks for future biorefineries, being a precursor of valuable bio-products, obtainable through both chemical and biological conversion routes. Lignocellulosic biomass has a complex matrix, which requires the careful development of multi-step approaches for its complete exploitation to value-added compounds. Based on this perspective, the present work focuses on the valorization of hemicellulose and cellulose fractionsof giant reed (Arundo donax L.) to give second-generation sugars, minimizing the formation of reaction by-products. The conversion of hemicellulose to xylose was undertaken in the presence of the heterogeneous acid catalyst Amberlyst-70 under microwave irradiation. The effect of the main reaction parameters, such as temperature, reaction time, catalyst, and biomass loadings on sugars yield was studied, developing a high gravity approach. Under the optimised reaction conditions (17 wt% Arundo donax L. loading, 160 °C, Amberlyst-70/Arundo donax L. weight ratio 0.2 wt/wt), the xylose yield was 96.3 mol%. In the second step, the cellulose-rich solid residue was exploited through the chemical or enzymatic route, obtaining glucose yields of32.5 and56.2 mol%, respectively. This work proves the efficiency of this innovative combination of chemical and biological catalytic approaches, for the selective conversion of hemicellulose and cellulose fractions of Arundo donax L. to versatile platform products
Biorthogonal quantum mechanics
The Hermiticity condition in quantum mechanics required for the characterization of (a) physical observables and (b) generators of unitary motions can be relaxed into a wider class of operators whose eigenvalues are real and whose eigenstates are complete. In this case, the orthogonality of eigenstates is replaced by the notion of biorthogonality that defines the relation between the Hilbert space of states and its dual space. The resulting quantum theory, which might appropriately be called 'biorthogonal quantum mechanics', is developed here in some detail in the case for which the Hilbert-space dimensionality is finite. Specifically, characterizations of probability assignment rules, observable properties, pure and mixed states, spin particles, measurements, combined systems and entanglements, perturbations, and dynamical aspects of the theory are developed. The paper concludes with a brief discussion on infinite-dimensional systems. © 2014 IOP Publishing Ltd
Prescriptions for the scaling variable of the nucleon structure function in nuclei
We tested several choices of the in-medium value of the Bjorken scaling
variable assuming the nucleon structure function in nucleus to be the same as
that of free nucleon. The results unambiguously show that it is different.Comment: 11 pages, 3 figures, 1 tabl
The CMS RPC gas gain monitoring system: an overview and preliminary results
The status of the CMS RPC Gas Gain Monitoring (GGM) system developed at the
Frascati Laboratory of INFN (Istituto Nazionale di Fisica Nucleare) is reported
on. The GGM system is a cosmic ray telescope based on small RPC detectors
operated with the same gas mixture used by the CMS RPC system. The GGM gain and
efficiency are continuously monitored on-line, thus providing a fast and
accurate determination of any shift in working point conditions. The
construction details and the first result of GGM commissioning are described.Comment: 8 pages, 9 figures, uses lnfprepCMS.sty, presented by L. Benussi at
RPC07, Mumbai, INDIA 200
VHMPID: a new detector for the ALICE experiment at LHC
This article presents the basic idea of VHMPID, an upgrade detector for the
ALICE experiment at LHC, CERN. The main goal of this detector is to extend the
particle identification capabilities of ALICE to give more insight into the
evolution of the hot and dense matter created in Pb-Pb collisions. Starting
from the physics motivations and working principles the challenges and current
status of development is detailed.Comment: 4 pages, 6 figures. To be published in EPJ Web of Conference
Active-Sterile neutrino oscillations and BBN+CMBR constraints
We show how active-sterile neutrino oscillations in the early Universe can
play an interesting role in explaining the current observations of CMBR
anisotropies and light element abundances. We describe different possible
phenomenological scenarios in the interpretation of present data and how
active-sterile neutrino oscillations can provide a viable theoretical
framework.Comment: Some changes, to appear in Phys. Rev.
Mechanism of CDW-SDW Transition in One Dimension
The phase transition between charge- and spin-density-wave (CDW, SDW) phases
is studied in the one-dimensional extended Hubbard model at half-filling. We
discuss whether the transition can be described by the Gaussian and the
spin-gap transitions under charge-spin separation, or by a direct CDW-SDW
transition. We determine these phase boundaries by level crossings of
excitation spectra which are identified according to discrete symmetries of
wave functions. We conclude that the Gaussian and the spin-gap transitions take
place separately from weak- to intermediate-coupling region. This means that
the third phase exists between the CDW and the SDW states. Our results are also
consistent with those of the strong-coupling perturbative expansion and of the
direct evaluation of order parameters.Comment: 5 pages(REVTeX), 5 figures(EPS), 1 table, also available from
http://wwwsoc.nacsis.ac.jp/jps/jpsj/1999/p68a/p68a42/p68a42h/p68a42h.htm
Update on neutrino mixing in the early Universe
From the current cosmological observations of CMB and nuclear abundances we
show, with an analytic procedure, that the total effective number of extra
neutrino species . We also describe the possible
signatures of non standard effects that could be revealed in future CMB
observations. This cosmological information is then applied to neutrino mixing
models. Taking into account the recent results from the SNO and SuperKamiokande
experiments, disfavouring pure active to sterile neutrino oscillations, we show
that all 4 neutrino mixing models, both of 2+2 and 3+1 type, lead to a full
thermalization of the sterile neutrino flavor. Moreover such a sterile neutrino
production excludes the possibility of an electron neutrino asymmetry
generation and we conclude that , in
disagreement with the cosmological bound. This result is valid under the
assumption that the initial neutrino asymmetries are small. We suggest the
existence of a second sterile neutrino flavor, with mixing properties such to
generate a large electron neutrino asymmetry, as a possible way out.Comment: 29 pages, 3 figures; to appear on Phys.Rev.D; added discussion (at
page 19) and references; typos correcte
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