1 research outputs found
Synthesis and characterization of ternary carboxylato complexes of cobalt(II) with Schiff bases
2006-2010Some novel mixed-ligand, ternary carboxylato
complexes of cobalt(II) with Schiff bases (HSB) having general formula [Co(OOCR)(SB)]
(where R = C11H23, C13H27,
C15H31
or C17H35) have been synthesized by the substitution reactions
of anhydrous cobalt(II) acetate. The isolated products have been characterized by
elemental analyses, molar conductance and magnetic moment measurements and spectral
(infrared, electronic and FAB mass) data. Models and coordination hypotheses for
the complexes have been proposed and a peculiar structural characterization has
been discussed on the basis of physicochemical studies. A sharp structural change
has been noticed