The bifurcation phenomena in the resistive state of the narrow superconducting channels

We have investigated the properties of the resistive state of the narrow superconducting channel of the length L/\xi=10.88 on the basis of the time-dependent Ginzburg-Landau model. We have demonstrated that the bifurcation points of the time-dependent Ginzburg-Landau equations cause a number of singularities of the current-voltage characteristic of the channel. We have analytically estimated the averaged voltage and the period of the oscillating solution for the relatively small currents. We have also found the range of currents where the system possesses the chaotic behavior

Hydrogen transport in superionic system Rb3H(SeO4)2: a revised cooperative migration mechanism

We performed density functional studies of electronic properties and mechanisms of hydrogen transport in Rb3H(SeO4)2 crystal which represents technologically promising class M3H(XO4)2 of proton conductors (M=Rb,Cs, NH4; X=S,Se). The electronic structure calculations show a decisive role of lattice dynamics in the process of proton migration. In the obtained revised mechanism of proton transport, the strong displacements of the vertex oxygens play a key role in the establishing the continuous hydrogen transport and in the achieving low activation energies of proton conduction which is in contrast to the standard two-stage Grotthuss mechanism of proton transport. Consequently, any realistic model description of proton transport should inevitably involve the interactions with the sublattice of the XO4 groups.Comment: 11 pages, 11 figures, to appear in Physical Review

Simulation of Time-Resolved Vibronic Spectra and the possibility of analyzing molecules with similar apectral properties

The possibility of using time-resolved vibronic spectroscopy for spectral analysis of mixtures of chemical compounds with similar optical properties, when traditional methods are inefficient, is demonstrated by using the method of computer simulation. The analysis is carried out by the example of molecules of a series of polyenes (butadiene, hexatraene, octatetraene, decapentaene, and decatetraene), their various cis- and trans-rotational isomers, and phenyl-substituted polyenes. Ranges of relative concentrations of molecules similar in their spectral properties, where reliable interpretation of time-resolved spectra of mixtures and both qualitative and quantitative analyses are possible, are determined. The use of computer simulation methods for oprimizing full-scale experiments in femtosecond spectroscopy is shown to hold much promise

Extracts from Problems of Air Law, a collection of works of the Section of air law of the Aviakhim Society of the USSR and Aviakhim RSFSR

The difficulties of developing a body of international law to govern air travel is discussed. A summary of literature and agreements is presented as well as a brief history. Air space over the poles and the legality of methods of claiming territory in the polar regions is discussed