Experimental Study of Transport Behavior of Swellable Microgel Particles in Superpermeable Channels for Conformance Control

Gel treatment is an effective way to attack excessive water production during oil development. The transport behavior of gel materials in reservoirs is of crucial importance to the effectiveness of gel treatments. The aim of this paper is investigating the transport behavior of swellable micrometer-sized preformed particle gels (PPGs, or microgels) through superpermeable (super-K) channels. Sandpacks with permeabilities ranging from 27 to 221 darcies were used to mimic the super-K channels. Multiple pressure sensors were applied along the sandpack models to monitor the propagation behavior of the microgels. The tested microgel particles could transport through the super-K channels, and a higher driving pressure gradient was required when the particle/pore size ratio was larger. The pressure gradient distribution along the super-K channels was relatively uniform when the particle/pore ratio was low (less than 1.3). However, the inlet section would show increasingly higher pressure gradients as the particle/pore ratio was increased, indicating increased difficulty in propagation. The propagation of the gel particles was significantly slower compared with the carrying fluid. The delayed propagation behavior was more pronounced when the particle/pore ratio was higher. The injection pressure was much less sensitive to the injection flow rate compared with a Newtonian fluid. The gel dispersion exhibited an apparent shear thinning (pseudoplastic) behavior when transporting through the porous channels. Breakage of the gel particles was observed especially at high superficial velocities. The particle breakage was partially responsible for the apparent shear thinning behavior. The breakage phenomenon was in favor of deep placement of the gel particles. The channel permeabilities were significantly reduced by the microgels, bringing sufficient resistance to subsequent waterflooding (more than 99.5%). At given matching size conditions, softer gels were more likely to establish in-depth placement and uniform water blocking capacity in the channels. The microgel particles exhibited salinity-responsive behavior to the post-brine flush. The gel particles could shrink and reswell according to the salinity of the injected water. Possibilities were discussed to use this salinity-responsive behavior. Also, the microgels exhibited a particular disproportionate permeability reduction (DPR) effect. After gel injection, the channel permeability to water flow was reduced by more than 20 to 92 times of the permeability to oil flow. This work provides important support to understand the transport behavior of gel particles in super-K channels. The achievements are helpful for gel product selection and gel treatment design

Selective Penetration Behavior of Microgels in Superpermeable Channels and Reservoir Matrices

Gel treatment is an effective way to attack excessive water production in many mature oilfields around the world. Selective penetration is desired for successful gel treatments. That is, gel materials should easily penetrate the target zones (i.e., channeling features such as superpermeable channels) without entering/damaging the nontarget zones (i.e., reservoir matrices or oil zones). This study revealed that presence of threshold penetration pressure (ΔPth) was responsible for selective penetration behavior of tested microgels. The concept of ΔPth was utilized to figure out favorable working conditions for effective gel treatments. Microgel dispersions were injected into superpermeable (super-k) sandpacks (mimicking super-k channels in reservoirs, 60–221 darcies), heterogeneous models with super-k channels (79–230 darcies), and sandstone cores (mimicking reservoir matrices, 50–5000 md). The results demonstrated that a minimum differential driving pressure (i.e., threshold penetration pressure, ΔPth) was required to push microgel particles to penetrate channels or matrices. The critical penetration behavior was closely related to the particle/pore size ratio. Low ΔPth at smaller particle/pore ratios was beneficial to allow easy penetration of gel materials into the channeling zones. On the contrary, high ΔPth at larger particle/pore ratios was desirable to prevent gel materials from massively invading and damaging the matrices. Instead, the gel particles accumulated at the inlet surface, and a gel cake was gradually formed. The cake further prevented the invasion of the gels. The cake could be removed by chemical breakers to resume the injectivity/productivity of the matrices. Correlations were developed to describe the relationship between ΔPth and particle/pore ratio. A distinct transition was identified at the particle/pore ratio of about 3. This work could help identify the favorable conditions to achieve successful gel treatments. In an effective conformance treatment, the particle/pore ratio in the channel should be sufficiently low to allow easy penetration of gel materials into the channel (e.g., particle/pore ratiostudy). Meanwhile, the particle/pore ratio in the matrix should be large enough to support a high ΔPth and thus prevent massive gel invasion into the matrix. This study advances the current pore scale studies (a single particle passing through a single channel) to Darcy-scale characterization

Characterization and Oil Recovery Enhancement by a Polymeric Nanogel Combined with Surfactant for Sandstone Reservoirs

The characterization and enhanced oil recovery mechanisms of a nanosized polymeric cross-linked gel are presented herein. A negatively charged nanogel was synthesized using a typical free radical suspension polymerization process by employing 2-acrylamido 2-methyl propane sulfonic acid monomer. The synthesized nanogel showed a narrow size distribution with one peak pointing to a predominant homogeneous droplet size. The charged nanogels were also able to adsorb at the oil-water interfaces to reduce interfacial tension and stabilize oil-in-water emulsions, which ultimately improved the recovered oil from hydrocarbon reservoirs. In addition, a fixed concentration of negatively charged surfactant (sodium dodecyl sulfate or SDS) was combined with different concentrations of the nanogel. The effect of the nanogels combined with surfactant on sandstone core plugs was examined by running a series of core flooding experiments using multiple flow patterns. The results show that combining nanogel and SDS was able to reduce the interfacial tension to a value of 6 Nm/m. The core flooding experiments suggest the ability of the nanogel, both alone and combined with SDS, to improve the oil recovery by a factor of 15% after initial seawater flooding

A Systematic Design Approach For Bulk Gel Treatments Based On Gel Volume-concentration Ratio In Field Projects

Controlling excessive water production in mature oil fields has always been a desired objective of the oil and gas industry. This objective calls for planning of more effective water-control gel treatments with optimized designs to obtain more attractive outcomes. Unfortunately, planning such effective treatments remains a dilemma for reservoir engineers due to the lack of methodical design tools in the industry. This paper presents a novel systematic design approach for polyacrylamide-based bulk gel treatments by classifying their field projects according to the gel volume-concentration ratio (VCR) into three design types. In terms of one another, the approach estimates either the gel volume or the gel concentration based on the average gel VCR of each design and formation type. First, field data was collected from SPE papers and reports of US Department of Energy for 65 gel projects conducted between 1985 and 2020. Stacked histograms were then used to examine distributions of field projects according to the gel VCR and the formation type. A comprehensive review of channeling strength indicators in field gel projects was performed to identify the classification criterion and design types of gel treatments. Based on the mean-per-group concept, the average gel VCR was assessed for each design type and formation type to build the design approach. Approximations for the overall gel concentration and correlations for extremum designs were established and included in the approach. The study showed that the gel VCR is a superior design criterion for in-situ forming bulk gel treatments. It aggregates gel treatments into three project groups and ranks them according to the channeling strength. The three project groups have clear separating VCR intervals (3 bbl/ppm) and each of them is mostly dominated by one formation type. The VCR range of each project group represents one design type of the bulk gel treatments. The channeling type is the criterion of grouping and group-wise ranking of gel projects with respect to the gel VCR. In design type I, VCRs/ppm are used to treat pipe-like channeling usually exhibited by unconsolidated sandstones. More balanced VCRs of 1–3 bbl/ppm are designed for fracture-channeling frequently presented in naturally-fractured formations (design type II). Large gel treatments with VCR\u3e3 bbl/ppm are performed to address matrix-channeling often shown in matrix-rock formations (design type III). Prediction results demonstrated that the VCR approach reasonably estimates volumes and concentrations of both single gel treatments and averaged field projects in training and validation samples. Besides its novelty, the new approach is systematic, accurate, practical, and will facilitate the optimization of future gel treatments to improve their performances and success rate

Applied Technologies and Prospects of Conformance Control Treatments in China

China is the largest user of chemical-based conformance control treatments and a series of technologies have been successfully developed and deployed in recent years. This paper first shows the milestones of development and application of conformance control technologies in China. Then integrated conformance control technologies are reviewed followed by the lessons we have learned, and then a few major specific conformance control technologies are addressed, including tracer injection and channels explanation, potentiometric testing to identify areal sweep efficiency, Pressure Index (PI) decisionmaking technology to select well candidate, complementary decision-making technology to select well candidate and design application parameters, and major chemicals for in-depth fluid diversion technologies. In addition, this paper also describes the principles and applications of some promising technologies of combined chemical-based conformance treatment with other EOR/IOR process, including the combination technology of surfactant and water shutoff, profile control and mini-scale surfactant flooding, acid treatment and profile control treatment. Finally, this paper summarizes the problems and challenges faced by mature water flooded oilfields in China. Based on recent well tests, tracer testing and interpretation, and previous water control treatment experience, it appears that channels or high permeability streaks are common in mature water flooded oilfields. Some research directions and promising technologies are suggested

Numerical Simulation Study on Miscible EOR Techniques for Improving Oil Recovery in Shale Oil Reservoirs

Shale formations in North America such as Bakken, Niobrara, and Eagle Ford have huge oil in place, 100—900 billion barrels of oil in Bakken only. However, the predicted primary recovery is still below 10%. Therefore, seeking for techniques to enhance oil recovery in these complex plays is inevitable. Although most of the previous studies in this area recommended that CO2 would be the best EOR technique to improve oil recovery in these formations, pilot tests showed that natural gases performance clearly exceeds CO2 performance in the field scale. In this paper, two different approaches have been integrated to investigate the feasibility of three different miscible gases which are CO2, lean gases, and rich gases. Firstly, numerical simulation methods of compositional models have been incorporated with local grid refinement of hydraulic fractures to mimic the performance of these miscible gases in shale reservoirs conditions. Implementation of a molecular diffusion model in the LS-LR-DK (logarithmically spaced, locally refined, and dual permeability) model has been also conducted. Secondly, different molar-diffusivity rates for miscible gases have been simulated to find the diffusivity level in the field scale by matching the performance for some EOR pilot tests which were conducted in Bakken formation of North Dakota, Montana, and South Saskatchewan. The simulated shale reservoirs scenarios confirmed that diffusion is the dominated flow among all flow regimes in these unconventional formations. Furthermore, the incremental oil recovery due to lean gases, rich gases, and CO2 gas injection confirms the predicted flow regime. The effect of diffusion implementation has been verified with both of single porosity and dual-permeability model cases. However, some of CO2 pilot tests showed a good match with the simulated cases which have low molar-diffusivity between the injected CO2 and the formation oil. Accordingly, the rich and lean gases have shown a better performance to enhance oil recovery in these tight formations. However, rich gases need long soaking periods, and lean gases need large volumes to be injected for more successful results. Furthermore, the number of huff-n-puff cycles has a little effect on the all injected gases performance; however, the soaking period has a significant effect. This research project demonstrated how to select the best type of miscible gases to enhance oil recovery in unconventional reservoirs according to the field-candidate conditions and operating parameters. Finally, the reasons beyond the success of natural gases and failure of CO2 in the pilot tests have been physically and numerically discussed

Re-Crosslinking Particle Gel for Co₂ Conformance Control and CO₂ Leakage Blocking

The present invention generally relates to the composition of particle gels for CO2-EOR and CO2 storage. More particularly, CO2 resistant particle gels are provided that can re-crosslink at subterranean conditions. These particle gels can be deployed to improve the conformance of CO2 flooding, CO2 huff-puff, or Water-Alternative-Gas (WAG). The applications may also involve CO2 storage, such as the blocking of CO2 leakage and similar CO2 processing

Comprehensive Review of Polymer and Polymer Gel Treatments for Natural Gas-Related Conformance Control

Conformance problems often exist in natural gas-related activities, resulting in excessive water production from natural gas production wells and/or excessive natural gas production from oil production wells. Several mechanical and chemical solutions were reported in the literature to mitigate the conformance problems. Among the chemical solutions, two classes of materials, namely polymer gels and water-soluble polymers, have been mostly reported. These systems have been mainly reviewed in several studies for their applications as water shutoff treatments for oil production wells. Natural gas production wells exhibit different characteristics and have different properties which could impact the performance of the chemical solutions. However, there has not been any work done on reviewing the applications of these systems for the challenging natural gas-related shutoff treatments. This study provides a comprehensive review of the laboratory evaluation and field applications of these systems used for water control in natural gas production wells and gas shutoff in oil production wells, respectively. The first part of the paper reviews the in-situ polymer gel systems, where both organically and inorganically crosslinked systems are discussed. The second part presents the water-soluble polymers with a focus on their disproportionate permeability reduction feature for controlling water in gas production wells. The review paper provides insights into the reservoir conditions, treatment design and intervention, and the success rate of the systems applied. Furthermore, the outcomes of the paper will provide knowledge regarding the limitations of the existing technologies, current challenges, and potential paths forwards

Experimental Investigation of the Dynamics of Trapped Non-Wetting Droplets Subjected to the Seismic Stimulation in Constricted Tubes: Supporting Information

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