Co-digestion of the mechanically recovered organic fraction of municipal solid waste with slaughterhouse wastes

The current work aimed to resolve some long-standing questions about the potential benefits and limitations of co-digestion of slaughterhouse wastes. To achieve this, a laboratory-scale trial was carried out using the mechanically recovered organic fraction of municipal solid waste mixed with either sheep blood or a mixture of pig intestines with flotation fat. Both of these co-substrates are difficult to digest in isolation because of their high nitrogen and lipid concentrations, and are regulated as Category 3 materials under the Animal By-Products Regulations (EC 1069/2009). The results showed that at an organic loading rate of 2 kg VS m?3 day?1 with the slaughterhouse material making up 20% of the load on a volatile solids basis the process could operate successfully. As the loading was increased to 4 kg VS m?3 day?1 signs of inhibition appeared with both co-substrates, however, and volumetric methane production was reduced to a point where co-digestion gave no process advantage. The main operational problem encountered was an increase in the concentration of volatile fatty acids in the digestate, particularly propionic acid: this was thought to be a result of ammonia toxicity. The concentration of potentially toxic elements in the digestate made it unsuitable for agricultural application for food production, although the increased nitrogen content made it more valuable as a fertiliser for non-food crop use

Seasonally loaded waste stabilisation ponds: a novel application for intermittent discharge

This research examined the use of a single facultative pond for treatment of an intermittent discharge from a UK campsite. The system was monitored over an 11-month period to determine the optimum time for discharge in terms of quality standards. The results showed that based on organic strength, discharge was possible in winter between November and March but February was the optimum to meet nutrient and suspended solids requirements. The pond showed rapid acclimatisation to the influent wastewater, with biochemical oxygen demand removal rates during the filling period of around 60 kg ha?1 day?1 and removal efficiencies of ?95% after maturation. The system proved simple to operate. A major design factor is the requirement for storage of net incoming precipitation, which may provide dilution of residual pollutants but requires additional system capacity.<br/

Operation and recovery of a seasonally-loaded UK waste stabilisation pond system

An intermittent discharge waste stabilisation pond system was trialled for treatment of a seasonal wastewater load from a campsite. The system showed rapid acclimatisation to incoming load, with chlorophyll-a exceeding 700 mg l?1 within 2 weeks and filtered and unfiltered effluent biochemical oxygen demand below 20 and 30 mg l?1 respectively. Good performance continued for some weeks, after which photosynthetic oxygenation capacity in the first pond was seriously impaired by a shock loading believed to include fatty material. Inflow to the system was suspended and a surface film was broken up, after which the pond recovered within an 8-day period. Laboratory experiments indicated that interventions such as artificial aeration and dilution with effluent had no beneficial effect although mixing may have increased the rate of recovery

Ammonia removal in anaerobic digestion by biogas stripping: an evaluation of process alternatives using a first order rate model based on experimental findings

The feasibility of biogas stripping to remove ammonia in the anaerobic digestion of source segregated food waste was investigated. It was found in batch experiments that ammonia could be removed from digestate and that the removal followed 1st order kinetics with respect to total ammonia nitrogen concentration. Increasing temperature, biogas flow rate and initial pH all increased removal rates. Using kinetic data gathered in these experiments allowed the integration of ammonia stripping with an anaerobic digestion plant to be modelled for different configurations. Four scenarios were identified: post digestion, in situ, side-stream and pre-digestion ammonia removal relating to where in the process the ammonia stripping was performed. The modelling showed that in situ ammonia removal may be best able to reduce in-digester ammonia concentrations over a wide range of organic loading rates whereas pre-digestion showed most promise in terms of application due to the flexibility to control each part of the process separately. Further experimental work is required into these scenarios to confirm their viability

Mass transfer and gas-liquid interface properties of single CO2 bubbles rising in tap water

To improve the mass transfer efficiency in many industrial applications better understanding of the mass transfer rate is required. High speed images of single CO2 bubbles rising in tap water were analysed to investigate the relationship between the mass transfer and properties of single bubbles. Transition to a lower mass transfer rate was shown to correspond with the transition from a mobile to an immobile bubble surface. This was indicated by the change in bubble rise velocity, bubble rise path and bubble shape. The presence of surfactants in untreated tap water appear to effect the transition point, particularly for bubbles with a smaller initial diameter and lower rise velocity

Effect of a trace element addition strategy on volatile fatty acid accumulation in thermophilic anaerobic digestion of food waste

PurposeA trace element (TE) supplementation strategy previously shown to be effective in mesophilic conditions was tested for thermophilic digestion of source segregated domestic food waste.MethodsInoculum from a mesophilic anaerobic digester treating municipal wastewater biosolids was successfully acclimated to thermophilic temperature (55 °C) with food waste as a substrate. Four laboratory-scale digesters were maintained at a loading of 2 g VS l?1 day?1 with one pair receiving TE supplementation. Two more pairs of digesters were incrementally loaded to 3 and 4 g VS l?1 day?1, respectively, and also received TE.ResultsAll digesters performed well for the first 3–4 months of operation, but volatile fatty acid (VFA) concentrations in those without TE showed no recovery from an initial small accumulation. On continued operation, VFA concentrations increased in all digesters, especially those at higher loading rates or without TE supplementation, reaching &gt;30 g l?1. Under these meta-stable conditions, a deliberate disturbance to daily feeding (cessation then resumption) led to acetic acid accumulation, a fall in pH and a sharp increase in the ratio of partial to intermediate alkalinity. Increases in VFA corresponded to an increasing total ammonia nitrogen concentration which appeared to become inhibitory at ~2,500 mg N l?1.ConclusionsWhile TE supplementation delayed the onset and reduced the rate of VFA accumulation, it was unable to sustain stable digestion of this substrate in thermophilic conditions.<br/

Cultivation and anaerobic digestion of Scenedesmus spp. grown in a pilot-scale open raceway

Digestibility of a micro-algal mixture was evaluated by mesophilic anaerobic digestion in continuously-stirred tank reactors. The culture consisted primarily of Scenedesmus spp. continuously cultivated over a 6-month period in a 100 m2 raceway reactor instrumented to record pH, dissolved oxygen and temperature. The raceway received supplementary carbon in the form of flue gas from a diesel boiler (10% CO2) injected into a 1-m deep sump to control pH in the range 7.8–8.0. Dilution was optimised to biomass productivity and gave values of 10–15 and 20–25 g total suspended solids (TSS) m? 2 day? 1 in winter (December–February) and spring (April–May), respectively. The culture for the anaerobic digestion trial was harvested in February by centrifugation to give an algal paste containing 4.3% volatile solids (VS). Semi-continuous digestion at organic loading rates of 2.00, 2.75 and 3.50 g VS l? 1 day? 1 gave volumetric biogas productions of ~ 0.66, ~ 0.83 and ~ 0.99 l l? 1 day? 1, respectively. Specific methane yield ranged from 0.13 to 0.14 l CH4 g? 1 VSadded with biogas methane content ~ 62%. Overall the digestion process was stable, but only ~ 30% VS destruction was achieved indicating low biodegradability, due to the short retention times and the recalcitrant nature of this type of biomas

Path Integral Monte Carlo Approach to the U(1) Lattice Gauge Theory in (2+1) Dimensions

Path Integral Monte Carlo simulations have been performed for U(1) lattice gauge theory in (2+1) dimensions on anisotropic lattices. We extractthe static quark potential, the string tension and the low-lying "glueball" spectrum.The Euclidean string tension and mass gap decrease exponentially at weakcoupling in excellent agreement with the predictions of Polyakov and G{\" o}pfert and Mack, but their magnitudes are five times bigger than predicted. Extrapolations are made to the extreme anisotropic or Hamiltonian limit, and comparisons are made with previous estimates obtained in the Hamiltonian formulation.Comment: 12 pages, 16 figure

An Application of Feynman-Kleinert Approximants to the Massive Schwinger Model on a Lattice

A trial application of the method of Feynman-Kleinert approximants is made to perturbation series arising in connection with the lattice Schwinger model. In extrapolating the lattice strong-coupling series to the weak-coupling continuum limit, the approximants do not converge well. In interpolating between the continuum perturbation series at large fermion mass and small fermion mass, however, the approximants do give good results. In the course of the calculations, we picked up and rectified an error in an earlier derivation of the continuum series coefficients.Comment: 16 pages, 4 figures, 5 table

Hamiltonian Study of Improved U(1U(1 Lattice Gauge Theory in Three Dimensions

A comprehensive analysis of the Symanzik improved anisotropic three-dimensional U(1) lattice gauge theory in the Hamiltonian limit is made. Monte Carlo techniques are used to obtain numerical results for the static potential, ratio of the renormalized and bare anisotropies, the string tension, lowest glueball masses and the mass ratio. Evidence that rotational symmetry is established more accurately for the Symanzik improved anisotropic action is presented. The discretization errors in the static potential and the renormalization of the bare anisotropy are found to be only a few percent compared to errors of about 20-25% for the unimproved gauge action. Evidence of scaling in the string tension, antisymmetric mass gap and the mass ratio is observed in the weak coupling region and the behaviour is tested against analytic and numerical results obtained in various other Hamiltonian studies of the theory. We find that more accurate determination of the scaling coefficients of the string tension and the antisymmetric mass gap has been achieved, and the agreement with various other Hamiltonian studies of the theory is excellent. The improved action is found to give faster convergence to the continuum limit. Very clear evidence is obtained that in the continuum limit the glueball ratio $M_{S}/M_{A}$ approaches exactly 2, as expected in a theory of free, massive bosons.Comment: 13 pages, 15 figures, submitted to Phys. Rev.