8,248 research outputs found

    Aircraft Observations of Dust and Pollutants over NE China: Insight into the Meteorological Mechanisms of Long-Range Transport

    Get PDF
    Substantial concentrations of trace gases and aerosols are lofted and carried from Asia over the Pacific producing an inter-hemispheric impact on atmospheric chemistry and climate. The meteorological mechanism leading to this large-scale transport of dust and pollutants remains a major uncertainty in quantifying the global effects of emissions from the developing world. Models and downwind measurements have identified isentropic advection associated with wave cyclones (warm conveyor belt circulation) as an important mechanism. We present data from a case study conducted over Shenyang in NE China as part of EAST-AIRE in April 2005 in which upstream convection, rather than WCB lofting appears to dominate. Observations from instrumented aircraft flights, back trajectories, and satellite images of clouds (GOES) and aerosols (MODIS) are analyzed. In this heavily industrialized and populated region, the warm-sector PBL air ahead of a cold front was highly polluted. In the free troposphere, between ~1000 and 4000 m altitude, concentrations of trace gases and aerosols were lower, but well above background; we measured ~70 ppb O3, ~300 ppb CO, ~2 ppb SO2, and ~ 8x10-5 m-1 aerosol scattering. These observations show that dry (non-precipitating) convection can be an important mechanism for converting local air pollution problems into regional or global atmospheric chemistry problems. Climatological data indicate that spring (MAM) precipitation over NE China is low, about 90 mm compared to 290 mm over the NE US. Cloud cover, however, is similar with cumulus clouds reported about 7% of the time over NE China and about 9% of the time over the NE US suggesting that lofting in dry convective events may be common over NE Asia. Evaluation of models’ convective schemes and further observations near the source regions are called for.NS

    Solution-processed perovskite light emitting diodes with efficiency exceeding 15% through additive-controlled nanostructure tailoring.

    Get PDF
    Organometal halide perovskites (OHP) are promising materials for low-cost, high-efficiency light-emitting diodes. In films with a distribution of two-dimensional OHP nanosheets and small three-dimensional nanocrystals, an energy funnel can be realized that concentrates the excitations in highly efficient radiative recombination centers. However, this energy funnel is likely to contain inefficient pathways as the size distribution of nanocrystals, the phase separation between the OHP and the organic phase. Here, we demonstrate that the OHP crystallite distribution and phase separation can be precisely controlled by adding a molecule that suppresses crystallization of the organic phase. We use these improved material properties to achieve OHP light-emitting diodes with an external quantum efficiency of 15.5%. Our results demonstrate that through the addition of judiciously selected molecular additives, sufficient carrier confinement with first-order recombination characteristics, and efficient suppression of non-radiative recombination can be achieved while retaining efficient charge transport characteristics

    Chemoenzymatic Synthesis of Glycosylated Macrolactam Analogues of the Macrolide Antibiotic YC‐17

    Full text link
    YC‐17 is a 12‐membered ring macrolide antibiotic produced from Streptomyces venezuelae ATCC 15439 and is composed of the polyketide macrolactone 10‐deoxymethynolide appended with D‐desosamine. In order to develop structurally diverse macrolactam analogues of YC‐17 with improved therapeutic potential, a combined approach involving chemical synthesis and engineered cell‐based biotransformation was employed. Eight new antibacterial macrolactam analogues of YC‐17 were generated by supplying a novel chemically synthesized macrolactam aglycone to S. venezuelae mutants harboring plasmids capable of synthesizing several unnatural sugars for subsequent glycosylation. Some YC‐17 macrolactam analogues were active against erythromycin‐resistant bacterial pathogens and displayed improved metabolic stability in vitro. The enhanced therapeutic potential demonstrated by these glycosylated macrolactam analogues reveals the unique potential of chemoenzymatic synthesis in antibiotic drug discovery and development.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/113147/1/adsc_201500250_sm_miscellaneous_information.pdfhttp://deepblue.lib.umich.edu/bitstream/2027.42/113147/2/2697_ftp.pd

    Dynamic Properties of a Sporadic Sodium Layer Revealed by Observations Over Zhongshan, Antarctica:A Case Study

    Get PDF
    A sodium Doppler lidar system with three-directional measurements of sodium density, atmospheric wind field, and temperature was established at Zhongshan (69.4°S, 76.4°E), Antarctica. On November 14, 2019, a sporadic sodium layer (SSL) was observed at an altitude range of 93–103 km. The temporal/spatial sodium density variations of this SSL are associated with a strong sporadic E (Es) layer at nearly the same height, which is modulated by the convective electric field. By considering the structures and the time lags of the SSL's growth at three positions, the SSL appears to have a horizontal advection in an approximately westward direction with a velocity of the order of 80 m/s. This is consistent with the zonal wind velocity derived from the lidar system itself. The temporal/spatial sodium density variations strongly indicate that the formation and perturbation of SSLs are related to the evolution of ES layers due to varied electric fields and atmospheric gravity waves, while it is advected by the horizontal wind

    Search for psi(3770)\ra\rho\pi at the BESII detector at the Beijing Electron-Positron Collider

    Full text link
    Non-DDˉD\bar{D} decay \psppto \rhopi is searched for using a data sample of (17.3±0.5)pb1(17.3\pm 0.5) pb^{-1} taken at the center-of-mass energy of 3.773 GeV by the BESII detector at the BEPC. No \rhopi signal is observed, and the upper limit of the cross section is measured to be \sigma(\EETO \rhopi)<6.0 pb at 90% C. L. Considering the interference between the continuum amplitude and the \pspp resonance amplitude, the branching fraction of \pspp decays to ρπ\rho\pi is determined to be \BR(\pspp\ra\rho\pi)\in(6.0\times10^{-6}, 2.4\times10^{-3}) at 90% C. L. This is in agreement with the prediction of the SS- and DD-wave mixing scheme of the charmonium states for solving the ``\rhopi puzzle'' between \jpsi and \psp decays.Comment: 15 pages, 5 figure

    Measurements of the Cross Section for e+e- -> hadrons at Center-of-Mass Energies from 2 to 5 GeV

    Get PDF
    We report values of R=σ(e+ehadrons)/σ(e+eμ+μ)R = \sigma(e^+e^-\to {hadrons})/\sigma(e^+e^-\to\mu^+\mu^-) for 85 center-of-mass energies between 2 and 5 GeV measured with the upgraded Beijing Spectrometer at the Beijing Electron-Positron Collider.Comment: 5 pages, 3 figure

    Partial Wave Analysis of χc0π+πK+K\chi_{c0}\to\pi^+\pi^-K^+K^-

    Full text link
    A partial wave analysis of χc0π+πK+K\chi_{c0}\to\pi^+\pi^-K^+K^- in ψ(2S)γχc0\psi(2S)\to\gamma\chi_{c0} decay is presented using a sample of 14 million ψ(2S)\psi(2S) events accumulated by the BES II detector. The data are fitted to the sum of relativistic covariant tensor amplitudes for intermediate resonant decay modes. From the fit, significant contributions to χc0\chi_{c0} decays from the channels f0(980)f0(980)f_0(980)f_0(980), f0(980)f0(2200)f_0(980)f_0(2200), f0(1370)f0(1710)f_0(1370)f_0(1710), K(892)0Kˉ(892)0K^*(892)^0\bar K^*(892)^0, K0(1430)Kˉ0(1430)K^*_0(1430)\bar K^*_0(1430), K0(1430)Kˉ2(1430)+c.c.K^*_0(1430)\bar K^*_2(1430) + c.c., and K1(1270)KK_1(1270)K are found. Flavor-SU(3)-violating K1(1270)K1(1400)K_1(1270)-K_1(1400) asymmetry is observed. Values obtained for the masses and widths of the resonances f0(1710)f_0(1710), f0(2200)f_0(2200), f0(1370)f_0(1370), and K0(1430)K^*_0(1430) are presented.Comment: 16 pages, 9 figures, and 4 table

    Measurements of the continuum RudsR_{\rm uds} and RR values in e+ee^+e^- annihilation in the energy region between 3.650 and 3.872 GeV

    Full text link
    We report measurents of the continuum RudsR_{\rm uds} near the center-of-mass energy of 3.70 GeV, the Ruds(c)+ψ(3770)(s)R_{{\rm uds(c)}+\psi(3770)}(s) and the Rhad(s)R_{\rm had}(s) values in e+ee^+e^- annihilation at 68 energy points in the energy region between 3.650 and 3.872 GeV with the BES-II detector at the BEPC Collodier. We obtain the RudsR_{\rm uds} for the continuum light hadron (containing u, d and s quarks) production near the DDˉD\bar D threshold to be Ruds=2.141±0.025±0.085R_{\rm uds}=2.141 \pm 0.025 \pm 0.085.Comment: 5 pages, 3 figure

    Measurement of the Inclusive Charm Cross Section at 4.03 GeV and 4.14 GeV

    Full text link
    The cross section for charmed meson production at s=4.03\sqrt{s} = 4.03 and 4.14 GeV has been measured with the Beijing Spectrometer. The measurement was made using 22.3 pb1pb^{-1} of e+ee^+e^- data collected at 4.03 GeV and 1.5 pb1pb^{-1} of e+ee^+e^- data collected at 4.14 GeV. Inclusive observed cross sections for the production of charged and neutral D mesons and momentum spectra are presented. Observed cross sections were radiatively corrected to obtain tree level cross sections. Measurements of the total hadronic cross section are obtained from the charmed meson cross section and an extrapolation of results from below the charm threshold.Comment: 11 pages, 13 figures. The top level tex file is paper.tex. It builds the paper from other tex files in this .tar and the .eps file
    corecore