Analysis of Multiwalled Carbon Nanotubes Porosimetry And Their Thermal Conductivity with Ionic Liquid-Based Solvents

The suspension of nanoparticles with common heat transfer fluids like Ethylene glycol and water yields nanofluid exhibits superior thermal properties than their host fluids. Ionic liquids have the potential to demonstrate remarkable thermophysical properties (especially thermal conductivity) that ordinary nanofluids cannot achieve. On the other hand, the quantity and structure of nanoparticles porosity affects the nanofluid’s thermal conductivity considerably. Various investigations have revealed the improved thermophysical characteristicts of Multiwalled Carbon nanotubes (MWCNTs) nanofluids containing common solvents or base fluids. However, only limited studies are available on the impact of thermal conductivity in Ionic liquid-based nanofluids (Ionanofluids) owing to their high cost and viscosity. Ultrasonication technique is employed in preparing the three different Ionanofluids containing 0.5 Wt.% via the two-step method to achieve a greater stability and thermal conductivity without utilizing surfactants. Experimental investigations are performed to boost the thermal conductivity of MWCNT/Propylene glycol nanofluid using 1,3-dimethyl imidazolium dimethyl phosphate [Mmim][DMP], 1-ethyl-3-methyl imidazolium octyl sulfate [Emim][OSO4] and 1-ethyl-3-methyl imidazolium diethyl phosphate [Emim][DEP] at a temperature ranging from 295 K to 355 K. The acquired results illustrated that the thermal conductivity of MWCNT Ionanofluids incorporated with [Mmim][DMP], [Emim][OSO4] and [Emim][DEP] increased by 37.5%, 5% and 2% respectively. This unique class of Ionanofluids shows incredible capacity for use in high temperature applications as conventional heat transfer fluids

Cooling performance analysis of nanofluid assisted novel photovoltaic thermoelectric air conditioner for energy efficient buildings

Carbon emissions and excessive power usage are addressed by applying thermoelectric cooling, which benefits from its ability to be portable, economical, and reliable. However, a conventional thermoelectric air conditioner's coefficient of performance (COP) is much less due to the sustained heat generated on the thermoelectric module's hot side. This work presents a novel idea of utilizing a nanofluid cooled radiator as an external cooling jacket around the thermoelectric module's hot side to enhance the heat transfer rate of thermoelectric air conditioners. In this research, the performance of a newly designed thermoelectric air conditioner (TEAC) powered by photovoltaic systems (PV) installed in a residential building is analyzed using nanofluid as a coolant. Furthermore, by supplying different input currents (2-6A), the cooling characteristics and performance of the newly designed nanofluid assisted thermoelectric air conditioner (NTEAC) system were experimentally studied in a test room of 25.6 m3 volume in Malaysia's tropical climate. The system's best performance was at 6A, with a maximum temperature drop of 4.9 °C, a cooling capacity of 571 W, and a coefficient of performance of 1.27. In addition, the NTEAC system showed an energy saving of 67% and CO2 emission mitigation of 76% when compared with a conventional split air conditioner. Thus, an alternative to the traditional air conditioning system was developed from this research, which is Freon free. This system is expected to consume less energy and emit less CO2 for the tropical climatic conditions

Comprehensive study on nanofluid and ionanofluid for heat transfer enhancement:A review on current and future perspective

Researches on the improvement of heat transfer using nanofluids, ionanofluids, and nanofluid assisted devices have gained significant attention worldwide since the previous decade due to their remarkable properties. However, there are many difficulties in preparing a stable nanofluid and integrating it for practical applications to increase the dissipation of heat from any thermal systems. Even though there are some reviews on nanofluids and nanofluid assisted heat transfer devices separately, an attempt has been made to analyze the latest researches on nanofluids and ionanofluids that lead to an important discussion to enhance the thermal performance of a system. In this paper, we summarized the preparation, thermophysical and hydrothermal properties, mechanisms, factors responsible for obtaining stable and enhanced thermophysical properties furthermore and its benefits on integration with heat transfer applications. The present study compiles theoretical and experimental studies from researchers investigating on stable nanofluids and ionanofluids, incorporating their effects on heat transfer applications

Investigation of electrical conductivity, optical property, and stability of 2D MXene nanofluid containing ionic liquids

The addition of ionic liquids with MXene nanofluid has a substantial impact on the solar thermal collectors’ working fluid’s optical properties that effectively absorb and distribute solar radiation. Increased solar radiation absorption potential ensures that heats are transported more rapidly and effectively. This research endeavors to investigate the concept of accumulating solar energy via the usage of ionic liquid-based 2D MXene nanofluid (Ionanofluids) for solar applications. In this study, the optical potential of Diethylene Glycol/MXene nanofluid incorporated with 1-ethyl-3-methyl imidazolium octyl sulfate ([Emim][OSO4 ]) ionic liquid was extensively investigated with respect to MXene concentration (0.1 to 0.4 wt%) and time (first day and seventh day) through UV-Vis Spectroscopy. A two-step approach was employed to synthesize the proposed ionanofluids with nanoparticle concentrations from 0.1 to 0.4 wt%. In wavelengths between 240 to 790 nm, the effect of ionic liquids, MXene concentration, and dispersion stability played a significant part in enhancing the absorbance capacity of the formulated MXene based Ionanofluid. Furthermore, the increase in the concentration of MXene nanoparticles resulted in more absorbance peaks facilitating high light absorption. Finally, the electrical conductivity of the ionanofluids is also analyzed as MXene renders them promising for solar cell applications. The utmost electrical conductivity of the formulated fluids of 571 µS/cm (micro siemens per centimeter) was achieved at 0.4 wt% concentration

Optimization of thermophysical and rheological properties of mxene ionanofluids for hybrid solar photovoltaic/thermal systems

Since technology progresses, the need to optimize the thermal system’s heat transfer efficiency is continuously confronted by researchers. A primary constraint in the production of heat transfer fluids needed for ultra-high performance was its intrinsic poor heat transfer properties. MXene, a novel 2D nanoparticle possessing fascinating properties has emerged recently as a potential heat dissipative solute in nanofluids. In this research, 2D MXenes (Ti3C2) are synthesized via chemical etching and blended with a binary solution containing Diethylene Glycol (DEG) and ionic liquid (IL) to formulate stable nanofluids at concentrations of 0.1, 0.2, 0.3 and 0.4 wt%. Furthermore, the effect of different temperatures on the studied liquid’s thermophysical characteristics such as thermal conductivity, density, viscosity, specific heat capacity, thermal stability and the rheological property was experimentally conducted. A computational analysis was performed to evaluate the impact of ionic liquid-based 2D MXene nanofluid (Ti3C2/DEG+IL) in hybrid photovoltaic/thermal (PV/T) systems. A 3D numerical model is developed to evaluate the thermal efficiency, electrical efficiency, heat transfer coefficient, pumping power and temperature distribution. The simulations proved that the studied working fluid in the PV/T system results in an enhancement of thermal efficiency, electrical efficiency and heat transfer coefficient by 78.5%, 18.7% and 6%, respectively

Activity of cefepime/zidebactam against MDR Escherichia coli isolates harbouring a novel mechanism of resistance based on four-amino-acid inserts in PBP3

BACKGROUND: Recent reports reveal the emergence of Escherichia coli isolates harbouring a novel resistance mechanism based on four-amino-acid inserts in PBP3. These organisms concomitantly expressed ESBLs or/and serine-/metallo-carbapenemases and were phenotypically detected by elevated aztreonam/avibactam MICs. OBJECTIVES: The in vitro activities of the investigational antibiotic cefepime/zidebactam and approved antibiotics (ceftazidime/avibactam, ceftolozane/tazobactam, imipenem/relebactam and others) were determined against E. coli isolates harbouring four-amino-acid inserts in PBP3. METHODS: Whole-genome sequenced E. coli isolates (n = 89) collected from a large tertiary care hospital in Southern India (n = 64) and from 12 tertiary care hospitals located across India (n = 25) during 2016-18, showing aztreonam/avibactam MICs ≥1 mg/L (≥4 times the aztreonam epidemiological cut-off) were included in this study. The MICs of antibiotics were determined using the reference broth microdilution method. RESULTS: Four-amino-acid inserts [YRIK (n = 30) and YRIN (n = 53)] were found in 83/89 isolates. Among 83 isolates, 65 carried carbapenemase genes [blaNDM (n = 39), blaOXA-48-like (n = 11) and blaNDM + blaOXA-48-like (n = 15)] and 18 isolates produced ESBLs/class C β-lactamases only. At least 16 unique STs were noted. Cefepime/zidebactam demonstrated potent activity, with all isolates inhibited at ≤1 mg/L. Comparator antibiotics including ceftazidime/avibactam and imipenem/relebactam showed limited activities. CONCLUSIONS: E. coli isolates concurrently harbouring four-amino-acid inserts in PBP3 and NDM are an emerging therapeutic challenge. Assisted by the PBP2-binding action of zidebactam, the cefepime/zidebactam combination overcomes both target modification (PBP3 insert)- and carbapenemase (NDM)-mediated resistance mechanisms in E. coli