Measurements and modeling of snow albedo at Alerce Glacier, Argentina: effects of volcanic ash, snow grain size and cloudiness

The relevance of light absorbing impurities in snow albedo (and its effects in seasonal snow or glacier mass balance) have been under study for several decades. However, the effect of volcanic ash has been much less studied, and most articles studied only the effect of thick layers after direct deposition. There is also a knowledge gap in field measurements of seasonal snow and glaciers of the southern Andes, that only recently has started to be filled.We present here the first field measurements on Argentinian Andes, combined with albedo and mass balance modeling activities.Measured impurities content (1.1mgkg−1 to 30000 mgkg−1) varied abruptly in snow pits and snow/firn cores, due to high surface enrichment during ablation season and possibly local/regional wind driven resuspension and redeposition of dust and volcanic ash. In addition, we observed a high spatial hetereogeneity, due to seasonality, glacier topography and prevailing wind direction. Microscopical characterization showed that the major component was ash from recent Calbuco (2015) and Cordón Caulle (2011) volcanic eruption, with 10 minor presence of mineral dust and Black Carbon. We also found a wide range of measured snow albedo (0.26 to 0.81), whichreflected mainly the impurities content and the snow/firn grain size (due to aging). SNICAR model has been updated to model snow albedo taking into account the effect of cloudiness on incident radiation spectra, improving the match of modeled and measured values. We also ran sensitivity studies on the main measured parameters (impurities content and composition, snow grain size, layer thickness, etc) to assess which field measurements precision can improve the uncertainty of albedo modeling. Finally, we studied the impact of these albedo reductions in Alerce glacier using a spatially distributed surface mass-balance model. We found a large impact of albedo changes in glacier mass balance, and we estimated that the effect of observed ash concentrations can be as high as a 1.25mwe decrease in the glacier-wide annual mass balance (due to a 34 % of increase inthe melt during the ablation season).Fil: Gelman Constantin, Julián. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); ArgentinaFil: Ruiz, Lucas Ernesto. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales. Provincia de Mendoza. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales. Universidad Nacional de Cuyo. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales; ArgentinaFil: Villarosa, Gustavo. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto Andino Patagónico de Tecnologías Biológicas y Geoambientales. Universidad Nacional del Comahue. Instituto Andino Patagónico de Tecnologías Biológicas y Geoambientales; Argentina. Universidad Nacional del Comahue. Centro Regional Universitario Bariloche; ArgentinaFil: Outes, Ana Valeria. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - Patagonia Norte. Instituto Andino Patagónico de Tecnologías Biológicas y Geoambientales. Universidad Nacional del Comahue. Instituto Andino Patagónico de Tecnologías Biológicas y Geoambientales; ArgentinaFil: Bajano, Facundo N.. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); ArgentinaFil: He, Cenlin. National Center for Atmospheric Research; Estados UnidosFil: Bajano, Héctor. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); ArgentinaFil: Dawidowski, Laura Elena. Comisión Nacional de Energía Atómica. Gerencia del Área de Seguridad Nuclear y Ambiente. Gerencia de Química (CAC); Argentin

Chemical markers of biomass burning: Determination of levoglucosan, and potassium in size-classified atmospheric aerosols collected in Buenos Aires, Argentina by different analytical techniques

A study concerning the identification and quantification of key chemical markers of biomass burning namely, levoglucosan and potassium in size-fractionated airborne particulate matter was conducted. To perform a complete characterization of PM2.5 and PM10 samples collected in Buenos Aires, Argentina black carbon, metals and metalloids were also determined. Due to the particularly complex chemical composition of atmospheric aerosols several analytical techniques were employed. Levoglucosan was extracted from filters and determined by gas chromatography–mass spectrometry (GC–MS). It was detected in a wide range of concentrations, from 2.0 ng m−3 to 4.90 μg m−3 (PM2.5) and 6.0 ng m−3 to 1.86 μg m−3 (PM10). Equivalent black carbon concentrations were determined by reflectromety and varied between 3.3 and 8.9 μg m−3. Other tracer of biomass burning such as Potassium was determined by flame atomic absorption spectrometry (FAAS). Potassium was mainly detected in the coarse fraction varying from <0.56 to 3.51 μg m−3. In addition, 17 minor, major and trace elements (Al, As, Ba, Cr, Cu, Fe, Hg, Mg, Mn, Ni, Pb, Sb, Se, Sn, Ti, V and Zn) were determined by plasma-based techniques namely, inductively coupled plasma optical emission spectrometry (ICP OES) and inductively coupled plasma-mass spectrometry (ICP-MS). Mean concentrations (in ng m−3) of metals and metalloids varied from 1.57 (Hg) to 1688 (Al) for PM2.5 and 1.5 (Al) to 1502 (Hg) for PM10.Fil: Achad, Mariana. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; ArgentinaFil: Caumo, Sofía. Universidade de Sao Paulo; BrasilFil: de Castro Vasconcellos, Pérola. Universidade de Sao Paulo; BrasilFil: Bajano, Héctor. Comisión Nacional de Energía Atómica; ArgentinaFil: Gómez, Darío. Comisión Nacional de Energía Atómica; ArgentinaFil: Smichowski, Patricia Nora. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Comisión Nacional de Energía Atómica; Argentin