563 research outputs found

    catena-Poly[[(2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)zinc(II)]-μ-2,2′-oxydibenzo­ato-κ2 O:O′]

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    In the title compound, [Zn(C14H8O5)(C15H11N3)]n, both the ZnII ion and the oxydibenzoate ligand are located on a twofold rotation axis. The ZnII centre is coordinated by three N atoms from a chelating 2,2′:6′,2′′-terpyridine ligand and two O atoms from two 2,2′-oxydibenzoate ligands, forming a distorted trigonal-bipyramidal coordination environment. Further coordination via the 2,2′-oxydibenzoate anions forms a one-dimensional coordination polymer extending parallel to [010]. Aromatic π–π stacking inter­actions are observed between adjacent terpyridine ligands with a centroid–centroid distance of 3.568 (2) Å

    Finite element analysis of porously punched prosthetic short stem virtually designed for simulative uncemented hip arthroplasty

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    Background: There is no universal hip implant suitably fills all femoral types, whether prostheses of porous short-stem suitable for Hip Arthroplasty is to be measured scientifically. Methods: Ten specimens of femurs scanned by CT were input onto Mimics to rebuild 3D models; their *stl format dataset were imported into Geomagic-Studio for simulative osteotomy; the generated *.igs dataset were interacted by UG to fit solid models; the prosthesis were obtained by the same way from patients, and bored by punching bears designed by Pro-E virtually; cements between femora and prosthesis were extracted by deleting prosthesis; in HyperMesh, all compartments were assembled onto four artificial joint style as: (a) cemented long-stem prosthesis; (b) porous long-stem prosthesis; (c) cemented short-stem prosthesis; (d) porous short-stem prosthesis. Then, these numerical models of Finite Element Analysis were exported to AnSys for numerical solution. Results: Observed whatever from femur or prosthesis or combinational femora-prostheses, “Kruskal-Wallis” value p > 0.05 demonstrates that displacement of (d) ≈ (a) ≈ (b) ≈ (c) shows nothing different significantly by comparison with 600 N load. If stresses are tested upon prosthesis, (d) ≈ (a) ≈ (b) ≈ (c) is also displayed; if upon femora, (d) ≈ (a) ≈ (b) < (c) is suggested; if upon integral joint, (d) ≈ (a) < (b) < (c) is presented. Conclusions: Mechanically, these four sorts of artificial joint replacement are stabilized in quantity. Cemented short-stem prostheses present the biggest stress, while porous short-stem & cemented long-stem designs are equivalently better than porous long-stem prostheses and alternatives for femoral-head replacement. The preferred design of those two depends on clinical conditions. The cemented long-stem is favorable for inactive elders with osteoporosis, and porously punched cementless short-stem design is suitable for patients with osteoporosis, while the porously punched cementless short-stem is favorable for those with a cement allergy. Clinically, the strength of this study is to enable preoperative strategy to provide acute correction and decrease procedure time

    Critical Ignition Temperature of Fuel-air Explosive

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    The charge of fuel-air explosive (FAE) warhead usually is solid-liquid mixed fuel. The solid component is aluminium powder. To meet the demand of FAE weapon usage and storage safety, in the mixed-fuel medium, there must be gaps where adiabatic compression occurs during launchin-e overloading- of warhead. Adiabatic compression makes the temperature of the mediumin the gaps to rise. High temperature can cause dxplosion of the mixed fuel during launching acceleration of the warhead, which is very dangerous. Because the fuel is a multicomponentmixture, the critical ignitioh temperature can't be determined only by one component. Through experiment, the critical ignition temperature of the mixed fuel is attained, and the changingregularity of the pressure following the temperature is shown in this paper

    Clinical study on the optic nerve protection of calcium dobesilate in treating glaucoma

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    AIM:To observe the protective effect of calcium dobesilate on optic nerve of glaucoma patients whose intraocular pressure has been under control through operation.<p>METHODS: A total of 78 inpatients(89 eyes)with glaucoma in this hospital from January, 2011 to February, 2012 were enrolled. All patients were randomly divided into treatment group and control group with 6 months in a course. The visual acuity, visual field(mean sensibility, MS), and intraocular pressure were measured at the experiment onset and 6 months later to evaluate the clinical effect.<p>RESULTS: There were no statistically significant differences in the visual acuity, intraocular pressure between the two groups neither at the experiment onset nor after 6 months(<i>P</i>>0.05). The mean sensibility(MS)of the treatment group was obviously improved(14.56±5.03 <i>vs </i>18.9±5.77, <i>P</i><0.05)with statistically significant differences before and after the treatment, while the MS remained unchanged in the control group(14.75±5.17 <i>vs </i>13.48±4.69). There are statistically significant difference between the treatment group and the control group. Compared to the ratio of improvement, stability, and deterioration in the control group(10.3%, 48.7%, 41.0%), the indexes were changed obviously in the treatment group(64.1%, 28.2%, 7.7%,<i>P</i><0.05)with statistically significant difference between the two groups.<p>CONCLUSION:Calcium dobesilate can improve mean retinal sensitivity and protect the optic nerve in glaucoma patients whose intraocular pressure has been controlled

    ηQ\eta_{Q} meson photoproduction in ultrarelativistic heavy ion collisions

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    The transverse momentum distributions for inclusive ηc,b\eta_{c,b} meson described by gluon-gluon interactions from photoproduction processes in relativistic heavy ion collisions are calculated. We considered the color singlet (CS) and color octet (CO) components with the framework of non-relativistic Quantum Chromodynamics (NRQCD) into the production of heavy quarkonium. The phenomenological values of the matrix elements for the color-singlet and color-octet components give the main contribution to the production of heavy quarkonium from the gluon-gluon interaction caused by the emission of additional gluon in the initial state. The numerical results indicate that the contribution of photoproduction processes cannot be negligible for mid-rapidity in p-p and Pb-Pb collisions at the Large Hadron Collider (LHC) energies.Comment: 11 pages, 2 figure

    iTRAQ Proteomic Analysis of Continuously Cropped Soybean Root Inoculated With Funneliformis mosseae

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    Soybean (Glycine max) is susceptible to root rot when subjected to continuous cropping, and this disease can seriously diminish the crop yield. Proteomics analyses can show the difference of protein expression in different treatment samples. Herein, isobaric tag for relative and absolute quantitation (iTRAQ) labeling and liquid chromatography-tandem mass spectrometry (LC-MS/MS) were employed for proteomic analysis of continuously cropped soybean inoculated with the arbuscular mycorrhizal fungus (AMF) Funneliformis mosseae. The AMF can reduce the incidence of root rot and increase plant height, biomass index in 1, 2, and 4 year of continuous cropping. Differential expression of proteins in soybean roots was determined following 1 year of continuous cropping. A total of 131 differentially expressed proteins (DEPs) were identified in F. mosseae-treated samples, of which 49 and 82 were up- and down-regulated, respectively. The DEPs were annotated with 117 gene ontology (GO) terms, with 48 involved in biological processes, 31 linked to molecular functions, and 39 associated with cell components. Kyoto Encyclopedia of Genes and Genomes (KEGG) pathway analysis mapped the DEPs to 113 mainly metabolic pathways including oxidative phosphorylation, glycolysis, and amino acid metabolism. Expression of glucan 1,3-beta-glucosidase, chalcone isomerase, calcium-dependent phospholipid binding and other defense-related proteins was up-regulated by F. mosseae, suggesting inoculation promotes the growth and development of soybean and increases disease resistance. The findings provide an experimental basis for further research on the molecular mechanisms of AMF in resolving problems associated with continuous soybean cropping

    N,N′-Bis(2-hydroxy­ethyl)-N,N′-[ethyl­ene­dioxy­bis(o-phenyl­enemethyl­ene)]­diammonium fumarate tetra­hydrate

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    The reaction of 1,2-bis­{2-[(2-hydroxy­ethyl)amino­methyl]­phen­oxy}ethane and fumaric acid in a mixed solution in ethanol–water (1:1 v/v) yields the title compound, C20H30N2O4 2+·C4H2O4 2−·4H2O. In the crystal structure, the anions, cations and water mol­ecules are connected via O—H⋯O and N—H⋯O hydrogen bonds into a three-dimensional network. The fumarate anion and the N,N′-bis­(2-hydroxy­ethyl)-N,N′-[ethyl­enedioxy­bis(o-phenyl­enemethylene)]diammonium cation are located on centers of inversion, whereas the two crystallographically independent water mol­ecules occupy general positions
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