Development of lanthanum strontium cobalt ferrite composite cathodes for intermediate- to low-temperature solid oxide fuel cells

Solid oxide fuel cells (SOFCs) offer high energy conversion, low noise, low pollutant emission, and low processing cost. Despite many advantages, SOFCs face a major challenge in competing with other types of fuel cells because of their high operating temperature. The necessity to reduce the operational temperature of SOFCs has led to the development of research into the materials and fabrication technology of fuel cells. The use of composite cathodes significantly reduces the cathode polarization resistance and expands the triple phase boundary area available for oxygen reduction. Powder preparation and composite cathode fabrication also affect the overall performance of composite cathodes and fuel cells. Among many types of cathode materials, lanthanum-based materials such as lanthanum strontium cobalt ferrite (La1-xSrxCo1-yFeyO3-δ) have recently been discovered to offer great compatibility with ceria-based electrolytes in performing as composite cathode materials for intermediate- to low-temperature SOFCs (IT-LTSOFCs). This paper reviews various ceria-based composite cathodes for IT-LTSOFCs and focuses on the aspects of progress and challenges in materials technology

Removal of zinc and lead ions by polymer-enhanced ultrafiltration using unmodified starch as novel binding polymer

The removal of zinc and lead from aqueous dilute solutions by polymer-enhanced ultrafiltration process using unmodified starch as a new binding polymer was studied. Experiments were performed to determine the effects of transmembrane pressure, pH, concentration of metal ions on the retention and permeate flux. The performance of the proposed new binding polymer was compared to that of polyethyleneimine a conventional polymer frequently used in polymer-enhanced ultrafiltration. The retention of zinc and lead ions reached 96 and 66 , respectively, using 0.05 unmodified starch at pH 7. Overall unmodified starch showed better retention for zinc ions then polyethyleneimine, whereas polyethyleneimine retention for lead ions was higher. Solution pH was found to have little effect on flux