The influence of salinity on the solubility of Zn and Cd sulphides in the Scheldt estuary

In the estuary of the river Scheldt, where an oxygen gradient exists in addition to the salinity gradient, redox processes will be of major importance for trace metal mobilisation. In this study, the influence of salinity and pH on the redox processes of dissolved Zn and Cd sulphides is investigated together with the effects on the ratio of the dissolved Zn and Cd concentrations. The speciation of these metals is calculated with the chemical equilibrium programme MINEQL + .Zn sulphides are oxidised at lower oxygen concentrations than Cd sulphides, due to lower stability constants, causing a sudden increase or peak in the dissolved Zn/Cd ratio. The formation of dissolved Cd chloride complexes when oxidation occurs at high salinities (S = 15) increases the mobility of Cd, causing a decrease in the Zn/Cd peak of the total dissolved concentrations. The peak is three to four times smaller at S = 15 than when oxidation occurs at S = 2. The simple model calculations compare very well with field data. The Scheldt estuary is suitable to illustrate these calculations. In the, 1970s, the anoxic part of the estuary reached S = 15-20, but since the early 1980s it has dropped to S = 2-10. Historic data on metals in the estuary from 1978, 1987 and the 1990s were used to compare with the equilibrium calculations. The increase of the dissolved Zn/Cd peak at low salinity as a consequence, of the decreasing anoxic region is confirmed well by the data. The good agreement between model calculations and field data is a proof of the extreme importance of redox processes for the solubility of Zn and Cd sulphides in the estuary

Experimental stabilisation of 2D vortex patterns using time-dependent forcing

Experimental results of the effect of time-periodic and "chirped" (electro-magnetic) forcing on vortex patterns in shallow-water-layer flows are presented. Analogously to vibrational control, the use of a time-periodic forcing results in stabilisation of otherwise unstable vortex patterns. Chirped frequency forcing yields self-organising patterns that are different from those in stationary and periodically forced experiments. The results are shown to be consistent with theoretical analysis of 2D Taylor-Green vortices, i.e. unstable analytical solutions of the 2D Navier-Stokes equation. These results imply that, compared to the more often analysed stationary forced flows, time-varying forcing can stabilise different vortex patterns in shallow-water-layer flows

Evaluation of the Ontario Mediation Program (Rule 24.1) Final Report: The First 23 Months

https://digitalcommons.osgoode.yorku.ca/faculty_books/1142/thumbnail.jp

Evaluation of the Ontario Mediation Program (Rule 24.1) Final Report: The First 23 Months

https://digitalcommons.osgoode.yorku.ca/faculty_books/1142/thumbnail.jp