Evaluation of Some Properties of Soils Affected by Diesel Oil Pollution in Uyo, Niger Delta Area, Nigeria

Soil pollution due to oil spill is a common problem in the Niger Delta region of Nigeria. This necessitated the experiment to determine the effect of diesel oil pollution on some soil properties in Uyo within the Niger Delta region of Nigeria.  The experiment was conducted at the University of Uyo Teaching and Research Farm in 2009. It was laid out in a completely randomized design (CRD) in triplicates.  The size of the experimental plot was 60.7m2, sub-divided into three sub-plots each measuring 20.24m2. Each sub-plot was divided into five experimental units receiving the following treatments: 0 (control), 8, 11.5, 14.5 and 22.0 litres of diesel oil, which was converted into 0.0%, 1.39%, 2.50%, 3.45% and 5.06%. The results at two weeks after oil application (2WAOA) showed significant decrease in soil pH from  4.90 in the control  to 4.35 in 5.06% pollution levels resulting in soil reaction being rated as extremely acid in oil polluted soils compared to the control with soil/reaction being rated as very strongly acid. There was depletion in total nitrogen and basic cations such as Ca2+, Mg2+, Na+ and K+. at 2WAOA. Carbon/nitrogen ratio increased in all the treatments, with the highest pollution level (5.06%) having 114.33±1.41. Percent base saturation increased inconsistently across the treatments with the highest being 56.96±0.003% (for 2.50% pollution) and the lowest being 44.24±0.008% (for 5.06% pollution level). The results at 18WAOA showed varying degrees of increase in the soil pH. The control plot had the pH of 6.39±0.002 and the highest pollution level of 5.06% had the pH of 6.05±0.2. The soil reaction at 18 WAOA was rated slightly acid compared to extremely acid in 2WAOA. There were varying degrees of increase in organic carbon in all the treatments. Total nitrogen also increased at 18WAOA, the increase ranged from 50-80%. Carbon/Nitrogen ratio was significantly reduced (? < 0.05) across the treatments.  Basic cations and percent base saturation increased across the treatments at 18WAOA. Correlation between concentrations of diesel oil in the soil and some soil properties at 2WAOA and 18 WAOA showed that at 2 WAOA soil pH, total N and percent base saturation showed negative correlation, while organic carbon and carbon/nitrogen ratio showed positive correlation. At 18 WAOA, organic carbon and total N, showed positive correlation, while soil pH, carbon/nitrogen ratio and percent base saturation showed negative correlation. Keywords: Evaluation, Soil Properties, Oil polluted, Niger Delta Area, Nigeri

Credit Risk Management in Nigerian Banks (2005 – 2015)

This study examines credit risk management in Nigerian banks. Content analysis approach was used to examine 15 banks over a ten years period. Findings from the study revealed that credit risk architecture significantly affects loan recovery of selected banks in Nigeria. Also GDP, NPL, interest rate and unemployment significantly affects the credit risk structure of banks in Nigeria. However inflation had insignificant effect on the credit risk structure of banks in Nigeria. We recommend that banks should enhance their credit risk architecture to always include collateral review and management, facility performance monitoring, quality reviews classification and risk portfolio reporting. Again, banks credit granting decision should be based on the result of risk assessment client’s solvency, available collateral, and transaction compliance with policies. Keywords: Credit risk, Credit structure, and Content analysis, Credit Risk Architecture

Effect of Branched and Straight Chained Alcohols on Performance of Crude oil Demulsifiers

Unwanted crude oil emulsions occur in many stages of oil production,  transportation, and processing. The huge cost resulting from corrosion of transport system and production facilities, because of the presence of water is a major challenge to the oil industry and the global economy. However, the addition of alcohols to demulsifiers has been reported to enhance their efficiency in removing water from emulsions. There is therefore the need to identify the best type of alcohols and optimize this process of addition.  Consequently in this work, the effect of different straight and branched chain alcohols on the performance enhancement of demulsifiers was investigated using four different crude oil emulsion samples. The results showed that straight alcohols performed better when compared to branched chain alcohols under all conditions of temperature. This may be due to their slow mobility particularly in stable emulsions.Keywords: Crude Oil, Emulsion, Emulsifiers, Demulsifiers, Alcohols

The value of serum C reactive protein in the assessment of severity of HIV infection among children in a resource limited setting

Background: Human immuno-deficiency virus (HIV) infection has devastating impact especially on well-being of children. Management of HIV infected children in resource-limited countries poses significant difficulties. The role of C-reactive protein as a potentially useful/cost-effective tool for assessing severity of HIV infection is yet to be established. The relationship between serum C-reactive protein and severity of HIV infection among children aged 6 months to 12 years was evaluated.Methods: Authors recruited 85 children each on combined antiretrovirals for ≥3 months, and apparently healthy HIV-negative controls. Severity of HIV infection was assessed by classification into immunologic categories 1, 2, 3 and clinical categories N, A, B, C according to the Centre for Disease Control revised classification system. Enzyme linked immunosorbent assay (ELISA) was used for serum CRP estimation. CD4 count was estimated by flow cytometry. Data analysis was with Statistical Package for Social Sciences version 20.Results: Response rate was 160 (94.1%) with mean age of participants being 8.50±3.36 years. Male to female ratio was 1.35:1. Lymphadenopathy was the commonest clinical feature in 26 (32.50%) participants, 59 (73.75%) participants were asymptomatic, and 52 (65.00%) were immunologic stage 1. Median serum CRP of HIV infected group and controls were 4.2 (1-13.9) mg/l and 0.5 (0.2-1.9) mg/l respectively. There was an association between Clinical and immunolological stages of infection and levels of serum CRP, p values = 0.001 and 0.002 respectively.Conclusions: The serum level of CRP may predict the severity of HIV infection among children

Neurobehavioral and Immunohistochemical Assessment of the Cerebellum in Adult Male Albino Wistar Rats Following Cannabis Sativa Administration

Reports abound on the use and effects of Cannabis sativa. High consumption may result in schizophrenia. It put some consumers in a state of coma, while some become unconscious after its consumption. Besides, it restores emotional stability in others and fills some consumers with a sense of wellbeing. Epidemiologic data suggest that Cannabis sativa use is a serious public health problem because it is highly addictive and is associated with a variety of neurological complications. The cerebellum is implicated in locomotor  activity and is richly endowed with cannabinoid-1, CB1 receptors; there was the need to assess the microstructure of the cerebellum and to evaluate locomotor activity on an animal model  following consumption of Cannabis sativa via various routes of administration. Graded doses of various preparations of Cannabis sativa were administered daily for 28 days as follows: Group B: 0.41 mg/kg, 0.2 mg/kg, and 0.13 mg/kg body weight of soxtlet extract of Cannabis sativa via oral ingestion. Group C: 4grams, 2grams and 1grams of grounded dried leaves of Cannabis sativa via inhalation.  Group D: A mixture of 8grams, 4grams and 2 grams of grounded dried leaves of Cannabis sativa and 90grams of animal feed in each case. Group A served as the control while rats in Group E were given 1gm of 10% Tween 80 via oral ingestion. Before and after 28 days of administration of Cannabis sativa, the  open field maze and Morris water maze experiments on neurobehavioral were carried out. Data were expressed as means ± standard error of the mean (M±SEM) and subjected to one way analysis of variance (ANOVA) using PRIMER, EXE, version 3.01. Significant difference between means was assessed by Student-Newman-Keuls post hoc test. 95% level of significance (P = .05) was used for the statistical analysis; while Microsoft excel 2010 package was used for graphs and error bars.  The findings of this study thus suggest that the extract of Cannabis sativa obtained via soxtlet extraction technique has a mild and lesser psychoactive effect compared to other preparations of Cannabis sativa, thus presents a better method to be adopted in preparation of medical Cannabis. Keywords: Cannabis sativa. Cerebellum.  Albino  Wistar rat

Occurrence and Sources of Triterpenoid Methyl Ethers and Acetates in Sediments of the Cross-River System, Southeast Nigeria

Pentacyclic triterpenol methyl ethers (PTMEs), germanicol methyl ether (miliacin), 3-methoxyfern-9(11)-ene (arundoin), β-amyrin methyl ether (iso-sawamilletin), and 3-methoxytaraxer-14-ene (sawamilletin or crusgallin) were characterized in surface sediments of the Cross-River system using gas chromatography-mass spectrometry (GC-MS). Triterpenol esters (mainly α- and β-amyrinyl acetates and hexanoates, and lupeyl acetate and hexanoate) were also found. These distinct compounds are useful for assessing diagenesis that can occur during river transport of organic detritus. Poaceae, mainly Gramineae and Elaeis guineensis higher plant species, are proposed as primary sources for the PTMEs and esters in the sediments. PTMEs are biomarkers of specific higher plant subspecies, while the triterpenol esters are indicators of early diagenetic alteration of higher plant detritus

Sustainable use of seashells as binder in concrete production: Prospect and challenges

Cement production has a lot of adverse effects on the environment and the globe at large. With all these negativities, it becomes imperative to find alternative materials that are sustainable and environmentally friendly to reduce some of these adverse effects. Seashells are one of the numerous wastes that are quickly accumulating onshore coasts. Using seashells in cement aids in ridding seashells from seashores and landfills, and transforming these wastes to viable cementitious materials. This review paper summarizes past studies on using seashell ash powder as a partial replacement for cement in several proportions. The workability of concrete reduces with the addition of seashell ash. It also indicates a reduction in compressive strength of concrete whose cement content is partially replaced with seashells as compared to those of ordinary Portland cement (OPC). Also, at low percentages of 5%–15% ranges, the concrete absorption and porosity are less compared to standard. Though, with greater replacement levels of up to 25%–50%, these values are enhanced. The workability of concrete is reduced with the addition of higher percentage of seashell ash. After long curing periods, concrete permeability is also reduced, and the mechanical performance is enhanced

Cold water and harmful algal blooms linked to coral reef collapse in the Eastern Tropical Pacific

Background: With conventional coral reef conservation methods proving ineffective against intensifying climate change, efforts have focussed on augmenting coral tolerance to warmer water—the primary driver of coral declines. We document coral cover and composition in relation to sea surface temperature (SST) over 25-years, of six marginal reefs in an upwelling area of Costa Rica’s Eastern Tropical Pacific. Methods: Using reef survey data and sea surface temperature (SST) dating back over 25-years, we document coral cover and composition of six marginal reefs in an upwelling area of Costa Rica’s Eastern Tropical Pacific in relation to thermal highs and lows. Results.: A ubiquitous and catastrophic coral die-off event occurred in 2009, driven by SST minima and likely by the presence of extreme harmful algal blooms. Coral cover was dramatically reduced and coral composition shifted from dominant branching Pocillopora to massive Pavona, Porites, and Gardineroseris. The lack of coral recovery in the decade since indicates a breach in ecosystem tipping-point and highlights a need for resilience-based management (RBM) and restoration. We propose a locally tailored and globally scalable approach to coral reef declines that is founded in RBM and informed by coral health dynamics

Mechanical and durability assessment of concrete containing seashells: A review

This study reviews recent literature on the mechanical and durability properties of concrete incorporating seashells as partial or full substitutes for conventional materials. The study summarizes various contributions elucidating the various waste seashells utilized, the growing worldwide aquaculture production, seashell material preparation and treatment, chemical composition, physical properties, and different mechanical and durability test methods adopted by previous studies such as compressive strength, split tensile strength, flexural strength, modulus of elasticity, freeze-thaw resistance, water permeability, air content, chemical attack, carbonation, and weight loss. The study showed that mechanical properties indicate reductions of different percentages with increases in substitution ratio at 5% to 75%, compared to control mixes. However, relative increases in mechanical strength were recorded with the increase in curing age up to 90 days. Influence of seashells on durability properties varied across various durability tests at different seashell percentages. In a nutshell, the use of seashells in concreteproduction has a good effect, and further innovative research can solidify its utilization in the drive towards sustainable development

The Hidden Cost of Cancer: The Siblings’ Story, A Mother’s Narrative on How Three of Her Children Journeyed Through Their 14-Year-Old Sister’s 9-Month Journey From Ill Heath to Death and Beyond

The siblings of children diagnosed with cancer can get lost in the cancer journey. Through a mother’s eyes, this paper examines the issues faced by three siblings when their teenage sister is diagnosed with and dies of cancer. It focusses on the impact their sister’s illness has on their educational, social, emotional and communication skills. Each sibling not only had their own unique set of needs but this paper argues that the term ‘cancer survivor’ should also be extended to the siblings as they comprise an intrinsic part of the family’s cancer journey. The paper calls on professionals to adopt a holistic approach to reduce the impact that childhood cancer has on the siblings and it highlights the far-reaching consequences of not properly supporting the siblings during this time