Investigation Of The Suitability Of Polyphosphoric Acid In Reducing The Degree Of Thermal Aging Of Agabu Natural Bitumen

Bitumen otherwise known as asphalt is a complex mixture of hydrocarbons which are naturally occurring or obtained from crude oil distillation. Bitumen when used as a binder in road pavement deteriorates with time as result of traffic load and contact of the pavement with environmental factors. The degradation of bitumen causes a rapid aging of the asphalt based pavement leading to road problems such as rutting, potholes etc. This deterioration is attributed to oxidative degradation of molecules of bitumen by factors such as heat, moisture and sunlight. This study investigates the viability of using polyphosphoric acid (PPA) to reduce the oxidative degradation effect of heat (at 60oC) on constituents of Agbabu Natural Bitumen (ANB) with a view to making it more durable when used for road pavement. Modification of ANB with PPA was carried out at 160oC using melt blend technique. Thereafter, the PPA modified and neat ANB samples were thermally aged in a hot air oven at 60oC. Fourier Transform Infrared (FTIR) Spectroscopy was used to validate the changes in the structure of ANB and aging indexes of neat and PPA modified samples of ANB calculated. The result showed that aging indexes of PPA modified samples of ANB were lower compared with that of the neat or unmodified samples of ANB. This implies that the rate of aging (at 60oC) of the unmodified ANB was faster than that of PPA modified ANB. Thus, a good potential for reducing thermal aging in ANB was found in PPA

Efficacy of Polyphosphoric Acid in Reducing the Degree of Thermal Aging of Agbabu Natural Bitumen

Bitumen is a complex mixture of hydrocarbons which occurred naturally or obtained from crude oil distillation. The degradation of bitumen causes its rapid aging leading to deterioration of asphalt based pavement readily induced by cracking, rutting, potholes etc. Aging in bitumen is attributed to chemical oxidation of its molecules and exposure to environmental factors, such as heat, moisture and sunlight. This study therefore investigates the viability of using polyphosphoric acid (PPA) to reduce the oxidative degradation effect of heat (60 o C) on constituents of Agbabu natural bitumen (ANB) with a view to making it more durable when used for road pavement. Modification of ANB with PPA was carried out at 150-55 o C using melt blend technique. Thereafter, the PPA modified and neat (unmodified) ANB samples were thermally aged in a hot air oven at 60 o C. Fourier Transform Infrared (FTIR) Spectroscopy was used to evaluate the changes in the structure of ANB and aging indexes of neat and PPA modified samples of ANB were calculated. The neat and PPA modified ANB samples aged as a result of their exposure to temperature at 60 o C. However, the aging indexes of PPA modified samples of ANB were found to be lower compared with that of the neat sample of ANB. This implies that the rate of aging (60 o C) of the neat ANB was faster than that of PPA modified ANB samples. Thus, a good potential for reducing thermal aging in ANB was found in PPA

Characterisation of Agbabu Natural Bitumen and Its Fractions Using Fourier Transform Infrared Spectrometry

Physico-chemical characterization of bitumen is very germane to its applications. There have been many physico-chemical investigations on Agbabu natural bitumen (ANB), but there appears to be some discrepancies in the results of some of the findings. Thus, the need to re-examine some of the physico-chemical parameters of the ANB. Raw sample of ANB was obtained from one of the observatory wells in Agbabu, Ondo State, Nigeria. The sample was dehydrated, purified and asphaltene component precipitated through addition of n-pentane to the sample. The maltene component was fractionated into saturate, aromatics and resin using column chromatographic method. The purified ANB sample and its fractions were each subjected to infrared analysis. In addition, the elemental composition and trace metals in the whole purified ANB were quantified using CHNS-O Analyzer (FlashEA® 1112) and Atomic Absorption Spectrometer (AAS) respectively. Infrared spectral features obtained for the whole bitumen and its fractions bear a good degree of resemblance to the results of earlier workers on the subject with some minor differences. The values obtained for structural indexes from Infrared (IR) spectra showed that all the fractions contained branch and straight chain hydrocarbons. The structural indexes also showed that asphaltenes and resin fractions are strongly polar, both of which contain hetero–atomic compounds. Results of compositional analysis are: C (86.62%), H(10.98%), S (0.92%) N (0.48%), O (0.83%), Maltene (78.34%) aand Asphaltene (21.67%). The concentrations of the trace metals are: Mg (792.00 ppm), Mn (28.40 ppm), Fe (3633.10 ppm), Ca (1082.10 ppm), Zn (17.50 ppm), Cu (17.90 ppm), Cr (153.90 ppm), Pb (93.78 ppm), Ni (103.65 ppm), V (156.53 ppm) and Na (3740.00 ppm). Results of compositional and trace metals analyses of this study are at variance with the earlier results on characterization of ANB in the literatures. The differences in the results might be attributed to variation in the method of sample preparation especially the inclusion of dehydration of the raw ANB in the purification step prior to characterization as introduced in this study. Keywords: Aromatics, Asphaltenes, Agbabu Natural Bitumen, IR, Resins, Saturate

Efficacy of Polyphosphoric Acid in Reducing the Degree of Thermal Aging of Agbabu Natural Bitumen

Bitumen is a complex mixture of hydrocarbons which occurred naturally or obtained from crude oil distillation. The degradation of bitumen causes its rapid aging leading to deterioration of asphalt based pavement readily induced by cracking, rutting, potholes etc. Aging in bitumen is attributed to chemical oxidation of its molecules and exposure to environmental factors, such as heat, moisture and sunlight. This study therefore investigates the viability of using polyphosphoric acid (PPA) to reduce the oxidative degradation effect of heat (60 o C) on constituents of Agbabu natural bitumen (ANB) with a view to making it more durable when used for road pavement. Modification of ANB with PPA was carried out at 150-55 o C using melt blend technique. Thereafter, the PPA modified and neat (unmodified) ANB samples were thermally aged in a hot air oven at 60 o C. Fourier Transform Infrared (FTIR) Spectroscopy was used to evaluate the changes in the structure of ANB and aging indexes of neat and PPA modified samples of ANB were calculated. The neat and PPA modified ANB samples aged as a result of their exposure to temperature at 60 o C. However, the aging indexes of PPA modified samples of ANB were found to be lower compared with that of the neat sample of ANB. This implies that the rate of aging (60 o C) of the neat ANB was faster than that of PPA modified ANB samples. Thus, a good potential for reducing thermal aging in ANB was found in PPA

The performance of Agbabu natural bitumen modified with polyphosphoric acid through fundamental and Fourier transform infrared spectroscopic investigations

Nigeria is greatly endowed with large deposit of natural bitumen at Agbabu, Ondo State. The country was reported to have a proven reserve of about 42.47 billion tonnes of bitumen, a quantity which is estimated to be second largest in the world but yet to be explored for economic purposes. However, literature has shown paucity of research work on its modification. This study is therefore carried out to investigate the suitability of polyphosphoric acid (PPA) as a modifier in Agbabu natural bitumen (ANB). The performance of unmodified and PPA modified ANB has been comparatively studied with specific emphasis on Fourier Transform Infrared investigation and fundamental physical tests like penetration, softening point, fire and flash point and specific gravity. Kinematic viscosity (flow) test was also investigated. Penetration indexes of ANB samples were calculated from the penetration values for softening points. The comparative study of FTIR spectra of both base ANB and PPA modified ANB samples showed appearance of some few new peaks in the infrared spectra of PPA modified ANB samples confirming that the structure of the neat ANB had been modified. On the basis of our experimental results, incorporation of PPA up to 6% into ANB structure greatly enhances the fundamental physical and flow properties of ANB. This showed that PPA has the potential of improving the service life of ANB

Harmonic measurements and analyses in distribution infrastructure feeding selected institutions in Malaysia and Nigeria

Potential of harmonic generations by research institutes and universities have not been exhaustively investigated in some developing Countries. This paper therefore presents measurements and analyses of harmonic distortions in distribution infrastructure feeding selected institutions in Malaysia and Nigeria. Harmonic data were collected over extended periods using a power quality analyzer (Fluke 435) for selected time intervals in two different universities, one each from Southern Malaysia and Northern Nigeria. The acquired data were preprocessed using inbuilt Discrete Fourier Transform (DFT) and further statistically analyzed in Excel and MATLAB environments. The main results respectively, revealed a maximum total harmonic distortion in voltage and current of 1.62% and 17.14% in a Malaysian university as against 1.3% and 14% in Nigerian university. Statistical analyses based on time stamped THDV and THDI have clearly demonstrated the extent of harmonic generations in the two institutions which even though are within recommended IEEE standard, exhibited distinctive diurnal variation patterns