Iron oxidation state effect on the Mg-Al- Si-O glassy system

Mg-Al-Si-O glassy systems have a great importance in a wide range of industrial applications, specifically as an electrolyte for molten oxide electrolysis processes in steelmaking. Understanding how the iron oxidation state of the raw material (Fe2+/Fe3+) and its corresponding amount influence this glassy system's properties will be the aim of the current work. Iron oxides (as Fe2O3 or Fe3O4) were used to dope Mg-Al-Si-O system obtaining amorphous materials through an unconventional method: Laser Floating Zone (LFZ). Above 8% mol of Fe formation of magnetic phases or iron clusters, were observed in the glass matrix. Samples with Fe2O3 showed a higher crystal concentration, when compared with Fe3O4. The electron paramagnetic resonance measurements show a strong dependence on the iron source (Fe3O4 or Fe2O3). In addition, the magnetization decreases linearly with iron content, independently of iron oxidation state, except for samples with a higher concentration of Fe2O3(15% mol), due to sample crystallization. Moreover, with Fe3O4 as raw material there is an improvement (~250 times) of the electrical conductivity when compared with Fe2O3. The results show that the presence of Fe2+ on the glass influences the electrical conductivity, which could have impact in the efficiency of molten oxide electrolysis process.publishe

MIP-soja: uma tecnologia eficiente e sustentável no manejo dos percevejos no atual sistema produtivo da soja.

Frente às mudanças ocorridas no cenário produtivo da soja no Brasil e os questionamentos que surgem em relação aos critérios adotados pelo Manejo Integrado de Pragas (MIP), numa parceria entre a Coamo e a Embrapa Soja, avaliou-se o manejo dos percevejos em 108 unidades de MIP com os seguintes tratamentos: 1. MIP: controle de percevejos conforme o nível de ação e produtos indicados pela pesquisa; 2. Sistema do produtor (SP): controle segundo os critérios do produtor e 3. Testemunha: área sem controle dos percevejos. A densidade populacional de percevejos foi monitorada através de amostragens semanais, foram registradas as aplicações realizadas e foi avaliada a produtividade e a qualidade da soja colhida. Os resultados obtidos indicaram que os critérios adotados pelo MIP-Soja são viáveis no atual sistema produtivo, destacando os seguintes resultados em relação ao manejo dos percevejos: o monitoramento dos percevejos foi fundamental na tomada de decisão e deve continuar até a fase de maturação da soja, a densidade populacional e os danos de percevejos causados à soja foram regionalizados; não foram constatadas diferenças na produtividade e na qualidade da soja entre os tratamentos MIP e SP; os produtores realizaram, em média, 2,06 vezes mais aplicações que o tratamento MIP e a redução na eficiência de controle ocorreu quando as aplicações foram realizadas com densidades elevadas de percevejos. Os resultados ratificaram que o controle dos percevejos antes do estádio R3 é desnecessário e, a análise da flutuação populacional indicou que a intensidade de ataque dos percevejos foi maior nas semeaduras realizadas antes de 16/10

Prioritizing Complex Issues of Hydrographic Basin Committees by Group Decision Approach

In Brazil, the hydrographic basin committees are the centre of decision for water resource management in their respective basins. The committee members, who represent the public sector, water users and civil society, must decide about complex issues, requesting the consideration of multiple aspects: economic, social and environmental. Given the complexity of the decision-making process, it is advantageous to have a decision support system that guarantees transparency, rapidness and, specially, a structured analysis of the problem, incorporating all aspects of the situation. This paper presents a group decision making model based on multicriteria analyses to support the members of a hydrographic basin committee to prioritize complex issues, in special activities to control the environmental degradation The proposed model works through two steps: firstly is used the PROMETHEE II method to achieve the individual rankings of alternatives, and secondly, the individual rankings of alternatives are aggregated to attain the global ranking, applying the ELECTRE IV method, reflecting the preference of the group

Interaction of Hawking radiation with static sources in deSitter and Schwarzschild-deSitter spacetimes

We study and look for similarities between the response rates $R^{\rm dS}(a_0, \Lambda)$ and $R^{\rm SdS}(a_0, \Lambda, M)$ of a static scalar source with constant proper acceleration $a_0$ interacting with a massless, conformally coupled Klein-Gordon field in (i) deSitter spacetime, in the Euclidean vacuum, which describes a thermal flux of radiation emanating from the deSitter cosmological horizon, and in (ii) Schwarzschild-deSitter spacetime, in the Gibbons-Hawking vacuum, which describes thermal fluxes of radiation emanating from both the hole and the cosmological horizons, respectively, where $\Lambda$ is the cosmological constant and $M$ is the black hole mass. After performing the field quantization in each of the above spacetimes, we obtain the response rates at the tree level in terms of an infinite sum of zero-energy field modes possessing all possible angular momentum quantum numbers. In the case of deSitter spacetime, this formula is worked out and a closed, analytical form is obtained. In the case of Schwarzschild-deSitter spacetime such a closed formula could not be obtained, and a numerical analysis is performed. We conclude, in particular, that $R^{\rm dS}(a_0, \Lambda)$ and $R^{\rm SdS}(a_0, \Lambda, M)$ do not coincide in general, but tend to each other when $\Lambda \to 0$ or $a_0 \to \infty$. Our results are also contrasted and shown to agree (in the proper limits) with related ones in the literature.Comment: ReVTeX4 file, 9 pages, 5 figure

Large-scale collective motion of RFGC galaxies

We processed the data about radial velocities and HI linewidths for 1678 flat edge-on spirals from the Revised Flat Galaxy Catalogue. We obtained the parameters of the multipole components of large-scale velocity field of collective non-Hubble galaxy motion as well as the parameters of the generalized Tully-Fisher relationship in the "HI line width - linear diameter" version. All the calculations were performed independently in the framework of three models, where the multipole decomposition of the galaxy velocity field was limited to a dipole, quadrupole and octopole terms respectively. We showed that both the quadrupole and the octopole components are statistically significant. On the basis of the compiled list of peculiar velocities of 1623 galaxies we obtained the estimations of cosmological parameters Omega_m and sigma_8. This estimation is obtained in both graphical form and as a constraint of the value S_8=sigma_8(Omega_m/0.3)^0.35 = 0.91 +/- 0.05.Comment: Accepted for publication in Astrophysics and Space Scienc

On-ground performance tests of the SAX/PDS detector

The Phoswich Detection System (PDS) is one of the four narrow field experiments on board the SAX satellite. The PDS will be dedicated to deep temporal and spectral studies of celestial X-ray sources in the 15–300 keV energy band. It also includes a gamma-ray burst monitor. The PDS detector is composed of 4 actively shielded NaI(Tl)/CsI(Na) phoswich scintillators with a total geometric area of 795 cm2 and a field of view of 1:4 (FWHM). The performance of the detector, before its integration with its flight electronic, was tested using standard instrumentation. Here we present results of these tests. The measured energy resolution of the phoswich units is better than 15% at 60 keV, confirming the expectations. Also test results of the anticoincidence shield of CsI(Na) and collimator are discussed