Intercalant-Driven Superconductivity in YbC6_{6} and CaC6_{6}

Recently deiscovered superconductivity in YbC$_6$ and CaC$_6$ at temperatures substantially higher than previously known for intercalated graphites, raised several new questions: (1) Is the mechanism considerably different from the previously known intercalated graphites? (2) If superconductivity is conventional, what are the relevant phonons? (3) Given extreme similarity between YbC$_6$ and CaCa$_6$, why their critical temperatures are so different? We address these questions on the basis of first-principles calculations and conclude that coupling with intercalant phonons is likely to be the main force for superconductivity in YbC$_6$ and CaC$_6$, but not in alkaline-intercalated compounds, and explain the difference in $T_c$ by the ``isotope effect'' due to the difference in Yb and Ca atomic masses.Comment: 4 pages, embedded postscript figire

Detection of biomarkers in the organic matter of rocks from the romashkinskoe oil field using gas chromatography-mass spectrometry

Polycyclic hydrocarbons (biomarkers) were detected in the organic matter of Paleozoic and pre-Paleozoic rocks from the Romashkinskoe oil field in the Volga-Ural region using gas chromatography-mass spectrometry. Coefficients were calculated from the ratio between tetra- and pentacyclic hydrocarbons, and the facial genetic types, possible generation sources, and evolution transformation conditions of the initial organic matter were determined from the array of these coefficients. © Pleiades Publishing, Ltd., 2010

Applications of high repetition rate tabletop soft X-ray lasers become a reality in several fields

Includes bibliographical references (page 468).For many years researchers have envisioned the development of compact high repetition rate tabletop soft x-ray laser, that could be routinely used in application in numerous disciplines. With demonstrated average powers of several mW and millijoule-level pulse energy at 46.9nm, the Ne-like Ar capillary discharge-pumped laser is the first compact laser to reach this goal. In this paper we summarize the development status of high repetition rate tabletop soft x-ray lasers based on capillary discharge excitation, and give examples of their successful use in several applications. Results of the use of a caprllary discharge pumped 46.9nm laser m dense plasma interferometry, soft x-ray reflectometry for the determination of optical constants, characterization of diffraction gratings, laser ablation of materials, and plasma generation are described. The observation of lasing at 52.9nm line in Ne-like Cl with output pulse energy up to 10 μJ is also reported

Continuous selections of multivalued mappings

This survey covers in our opinion the most important results in the theory of continuous selections of multivalued mappings (approximately) from 2002 through 2012. It extends and continues our previous such survey which appeared in Recent Progress in General Topology, II, which was published in 2002. In comparison, our present survey considers more restricted and specific areas of mathematics. Note that we do not consider the theory of selectors (i.e. continuous choices of elements from subsets of topological spaces) since this topics is covered by another survey in this volume

Effects of Crystal Structure and the On-Site Coulomb Interactions on the Electronic and Magnetic Structure of Pyrochlores A2A_2Mo2_2O7_7 (A= Y, Gd, and Nd)

Being motivated by recent experimental studies, we investigate magnetic structures of the Mo pyrochlores $A_2$Mo$_2$O$_7$ ($A$= Y, Nd, and Gd) and their impact on the electronic properties. The latter are closely related with the behavior of twelve Mo($t_{2g}$) bands, located near the Fermi level and well separated from the rest of the spectrum. We use a mean-field Hartree-Fock approach, which combines fine details of the electronic structure for these bands, extracted from the conventional calculations in the local-density approximation, the spin-orbit interaction, and the on-site Coulomb interactions amongst the Mo(4d) electrons, treated in the most general rotationally invariant form. The Coulomb repulsion U plays a very important role in the problem, and the semi-empirical value U$\sim$1.5-2.5 eV accounts simultaneously for the metal-insulator (M-I) transition, the ferromagnetic (FM) - spin-glass (SG) transition, and for the observed enhancement of the anomalous Hall effect (AHE). The M-I transition is mainly controlled by $U$. The magnetic structure at the metallic side is nearly collinear FM, due to the double exchange mechanism. The transition into the insulating state is accompanied by the large canting of spin and orbital magnetic moments. The sign of exchange interactions in the insulating state is controlled by the Mo-Mo distances. Smaller distances favor the antiferromagnetic coupling, which preludes the SG behavior in the frustrated pyrochlore lattice. Large AHE is expected in the nearly collinear FM state, near the point of M-I transition, and is related with the unquenched orbital magnetization at the Mo sites. We also predict large magneto-optical effect in the same FM compounds.Comment: 26 pages, 17 figures (low resolution is used for Figs. 6, 8, and 9, please contact directly if you need the originals), 1 tabl

Detection of biomarkers in the organic matter of rocks from the romashkinskoe oil field using gas chromatography-mass spectrometry

Polycyclic hydrocarbons (biomarkers) were detected in the organic matter of Paleozoic and pre-Paleozoic rocks from the Romashkinskoe oil field in the Volga-Ural region using gas chromatography-mass spectrometry. Coefficients were calculated from the ratio between tetra- and pentacyclic hydrocarbons, and the facial genetic types, possible generation sources, and evolution transformation conditions of the initial organic matter were determined from the array of these coefficients. © Pleiades Publishing, Ltd., 2010

Detection of biomarkers in the organic matter of rocks from the romashkinskoe oil field using gas chromatography-mass spectrometry

Polycyclic hydrocarbons (biomarkers) were detected in the organic matter of Paleozoic and pre-Paleozoic rocks from the Romashkinskoe oil field in the Volga-Ural region using gas chromatography-mass spectrometry. Coefficients were calculated from the ratio between tetra- and pentacyclic hydrocarbons, and the facial genetic types, possible generation sources, and evolution transformation conditions of the initial organic matter were determined from the array of these coefficients. © Pleiades Publishing, Ltd., 2010