The Raman Spectra of CH3CF3 and CCl2CF2

Because of the interest attached to ethane and ethane-like molecules in connection with the question of free rotation of the CX3 groups with respect to each other, it was considered that the Raman spectrum of CH3CF3 might yield additional information on this point. Inasmuch as the spectrum of the liquid can be conveniently photographed only at low temperatures (b.p. about -40°), the determination of the polarization of the scattered light would be experimentally very difficult and was not attempted. The fact that the frequencies associated with the CF3 group will be considerably different in magnitude from those of the CH3 group may, in the analysis, compensate for the lack of data on polarization. Only the results of the experiments are presented here; the assignment of the frequencies will be given when completed. The Raman spectrum of the ethylene-like molecule CCl2=CF2 was photographed at room temperature with the substance in the liquid state, and the observed shifts are presented here

Identification Of Environmental Variables For Use In Monitoring For The Evaluation Of The Rural Environment Protection Scheme

Teagasc wishes to acknowledge the support of the Environmental RTDI Programme 2000–2006 in financing this research project.End of project reportThe aim of this study was to identify and select quantitative environmental attributes for a monitoring programme that may be integrated into an environmental evaluation of Ireland’s agri-environmental scheme. This was achieved primarily by reviewing a range of agri-environmental indicators and suggesting indicators that would be appropriate for monitoring the REPS. The study conducted a desk review to collate information on current best practice in monitoring for environmental quality. A Project Group (comprising representatives from the Environmental Protection Agency [EPA], Department of Agriculture and Food [DAF], Teagasc, and the project supervisors) advised on the ongoing development of the project. There was a consultation process with national experts, and with a selection of stakeholder organisations with an interest in monitoring the environmental impact of the REPS.Environmental Protection Agenc

The adenomatous polyposis coli protein unambiguously localizes to microtubule plus ends and is involved in establishing parallel arrays of microtubule bundles in highly polarized epithelial cells

Loss of full-length adenomatous polyposis coli (APC) protein correlates with the development of colon cancers in familial and sporadic cases. In addition to its role in regulating β-catenin levels in the Wnt signaling pathway, the APC protein is implicated in regulating cytoskeletal organization. APC stabilizes microtubules in vivo and in vitro, and this may play a role in cell migration (Näthke, I.S., C.L. Adams, P. Polakis, J.H. Sellin, and W.J. Nelson. 1996. J. Cell Biol. 134:165–179; Mimori-Kiyosue, Y., N. Shiina, and S. Tsukita. 2000. J. Cell Biol. 148:505–517; Zumbrunn, J., K. Inoshita, A.A. Hyman, and I.S. Näthke. 2001. Curr. Biol. 11:44–49) and in the attachment of microtubules to kinetochores during mitosis (Fodde, R., J. Kuipers, C. Rosenberg, R. Smits, M. Kielman, C. Gaspar, J.H. van Es, C. Breukel, J. Wiegant, R.H. Giles, and H. Clevers. 2001. Nat. Cell Biol. 3:433–438; Kaplan, K.B., A. Burds, J.R. Swedlow, S.S. Bekir, P.K. Sorger, and I.S. Näthke. 2001. Nat. Cell Biol. 3:429–432). The localization of endogenous APC protein is complex: actin- and microtubule-dependent pools of APC have been identified in cultured cells (Näthke et al., 1996; Mimori-Kiyosue et al., 2000; Reinacher-Schick, A., and B.M. Gumbiner. 2001. J. Cell Biol. 152:491–502; Rosin-Arbesfeld, R., G. Ihrke, and M. Bienz. 2001. EMBO J. 20:5929–5939). However, the localization of APC in tissues has not been identified at high resolution. Here, we show that in fully polarized epithelial cells from the inner ear, endogenous APC protein associates with the plus ends of microtubules located at the basal plasma membrane. Consistent with a role for APC in supporting the cytoskeletal organization of epithelial cells in vivo, the number of microtubules is significantly reduced in apico-basal arrays of microtubule bundles isolated from mice heterozygous for APC

Determinants Associated to Zeta Matrices of Posets

We consider the matrix ${\frak Z}_P=Z_P+Z_P^t$, where the entries of $Z_P$ are the values of the zeta function of the finite poset $P$. We give a combinatorial interpretation of the determinant of ${\frak Z}_P$ and establish a recursive formula for this determinant in the case in which $P$ is a boolean algebra.Comment: 14 pages, AMS-Te

Optimal provision of distributed reserves under dynamic energy service preferences

We propose and solve a stochastic dynamic programming (DP) problem addressing the optimal provision of regulation service reserves (RSR) by controlling dynamic demand preferences in smart buildings. A major contribution over past dynamic pricing work is that we pioneer the relaxation of static, uniformly distributed utility of demand. In this paper we model explicitly the dynamics of energy service preferences leading to a non-uniform and time varying probability distribution of demand utility. More explicitly, we model active and idle duty cycle appliances in a smart building as a closed queuing system with price-controlled arrival rates into the active appliance queue. Focusing on cooling appliances, we model the utility associated with the transition from idle to active as a non-uniform time varying function. We (i) derive an analytic characterization of the optimal policy and the differential cost function, and (ii) prove optimal policy monotonicity and value function convexity. These properties enable us to propose and implement a smart assisted value iteration (AVI) algorithm and an approximate DP (ADP) that exploits related functional approximations. Numerical results demonstrate the validity of the solution techniques and the computational advantage of the proposed ADP on realistic, large-state-space problems

Studies of Radiative Penguin B Decays at BaBar

We summarize results on a number of observations of penguin dominated radiative decays of the B meson. Such decays are forbidden at tree level and proceed via electroweak loops. As such they may be sensitive to physics beyond the standard model. The observations have been made at the BaBar experiment at PEP-II, the asymmetric B factory at SLAC.Comment: 3 pages, 5 figure